Table of Contents
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FOREWORD
PREFACE
List of Contributors
Role of Plasmonic Metal-semiconductor Hetero-structure in Photo Catalytic Hydrolysis and Degradation of Toxic Dyes
Abstract
Introduction
Plasmonic Dynamics
Synthesis process of metal-semiconductor plasmonic photocatalyst
Factors Affecting Plasmonic Nanostructure
Geometrical Shape
Size of the Plasmonic Nanocrystal
Material Composition
Ratio of Noble Metal to the Semiconductor
Plasmonic metal-semiconductor heterostructure for photocatalytic hydrolysis of ammonium borane
Plasmonic metal-semiconductor heterostructure for dye water treatment
Proposed Mechanism
Schottky Barrier
Direct Electron Transfer
Enhanced Local Electric Field
Plasmon Resonant Energy Transfer
Prospects and Future
Plasmonic as Energy Inputs
Quantum Dots and Quantum Dots
Communication with Plasmonic
Plasmonic Nanoparticles in the Treatment of Cancer
Plasmonic in Desalination of Water
Plasmonic Invisible Photodetector
Electrochromic Smart Window
Plasmonic Sensing
Antimicrobial Coating
Limitations and Challenges
Conclusion
ACKNOWLEDGMENTS
References
BaZrO3-Based Ceramics and Ceramic Composites as Smart Materials for Advanced Applications
Abstract
Introduction
Synthesis Strategy of Ceramics
Ceramics and Ceramic Composites in PC-SOFC Technology
Grotthuss Mechanism in Proton Conductors
BaZrO3 Based Proton Conductors (PCs) for Fuel Cells
BaZrO3-based Thin Film Composites for Fuel Cell Technology
Advanced Ceramic Composites in Defence
Mechanism of Course-Changing Bullets
BaZrO3 Based Ceramic Composites in Defence
Ceramic Composites as Photocatalysts for Hydrogen Production
Photocatalytic Mechanism for Hydrogen Production
BaZrO3 Based Ceramic Composites for Hydrogen Production
Ceramic Phosphors for Medical Applications
Optical Activity of Ceramic Phosphors
BaZrO3-based Ceramic Phosphor for Radiation Shielding
Ceramic Materials for Microwave Dielectric Resonators
Functioning of Microwave Dielectric Resonator
BaZrO3-Based Ceramic Materials as Microwave Dielectric Resonators
Critical Shortcomings and Future Scope
Conclusion
ACKNOWLEDGMENT
References
A High-capacity Anode Material for Lithium-ion Batteries is Sili-graphene Type SiC3
Abstract
Introduction
Computational Details
RESULTS AND DISCUSSION
Electronic Properties of Li Adsorption on the Siligraphene
Li Adsorption and Diffusion on the Siligraphene
Li Diffusion Process
Voltage Profiles as a Function of Capacity for Siligraphene LixSiC3
Conclusion
References
An Introduction to the Fabrication of White Light-emitting Diodes
Abstract
Introduction
Types of LEDs and Their Applications
Characteristics of a Lighting Source
Color Rendering Index (CRI)
CIE Color Co-ordinates
Color Co-related Temperature (CCT)
Luminous Efficacy (K)
Fabrications of White Light-emitting Diode
Mixing of Multiple LEDs Emitting Different Monochromatic Color
Advantages and Disadvantages
Mixing of an LED Chip with a Phosphor
Luminescence
Phosphor
Different Synthetic Methods of Phosphor
Co-Precipitation Method
Hydrothermal/Solvothermal Method
Sol-gel Method
Combustion Method
Sonochemical Route
Microwave-assisted Synthesis
Solid State Method
Energy Transfer
Quenching of Luminescence
Thermal Quenching
Combination of Blue Emitting LED with a Phosphor Emitting Yellow Light
Advantages and Disadvantages
Combination of UV/NUV Emitting LED with Multiple Phosphors Emitting Red, Green and Blue Color
Advantages and Disadvantages
Combination of UV/NUV Emitting LED With a Single Phosphor Emitting Blue and Yellow Lights or Blue, Green and Red Lights
Doping of a Single Activator Ion into the Host Material
Doping of Multiple Activator Ions into the Host Material
Controlling the Concentrations of Defect and Reaction Conditions of the Defect-related Luminescent Material
Advantages and Disadvantages
Current Limitations and Challenging
Conclusion
REFERENCES
Electronic and Piezoelectric Properties of Non-metal Doped II-VI Monolayer Compounds
Abstract
Introduction
Computational Methods
Results and Discussion
Pristine Properties
Non-metal Doping
Conclusion
Acknowledgements
References
A Theoretical Investigation on the New Quaternary MAX-phase Compounds (Zr1-xTix)3AlC2 (where x= 0-1)
Abstract
Introduction
Generalities on the MAX-phases
Chemical Elements
Crystal Structure
MAX Phases Properties
Mechanical Properties
Electrical Properties
Thermal Properties
Synthesis of MAX Phases
Synthesis of Massive Samples
Synthesis of Thin Film
Applications
Results and discussion of the first-principle investigations of (Zr1-xTix)3AlC2 MAX-phase compounds (x=0-1)
Details of the Employed First-principle Method
Structural Properties
Mechanical Behavior
Electronic Properties
Thermodynamic Properties
Conclusion
References
Surface Segregation in Pt3Nb and Pt3Ti using Density Functional Theory-based Methods
Abstract
INTRODUCTION
COMPUTATIONAL METHOD
RESULTS AND DISCUSSION
Surface Segregation in Pt3X (111) Surface
Direct Exchange and Antisite Migration
Oxygen Adsorption on Pristine Pt (111) Surface
Oxygen Adsorption Energy on Pt3X (111) Surface
CONCLUSION
ACKNOWLEDGEMENT
REFERENCES
Nanoparticles and Environmental Health
Abstract
Introduction
Natural NPs
Engineered NPs
THE FATE OF NPs IN THE ENVIRONMENT
Physiochemical Transformation
Biological Transformation of sNPs
NPs in Soil
Source of Soil NPs
Effect on Soil
Soil Remediation with NPs
NPs in the Aquatic Environment
Source
Effect of NPs in Water
Remediation of Contaminants in Water
NPs in Air
Source
Effect of NPs in the Air
Remediation of Pollutants in the Air by NPs
Limitations and Future Perspectives
Conclusion
ACKNOWLEDGMENTS
References
Investigation for Optimum Site for Adsorption and Population Effect of Lithium on Silicene Monolayer
Abstract
INTRODUCTION
Computational Details
Results and Discussions
Conclusion
References
Strategies for Synthesizing Metal Oxide Nanoparticles and the Challenges
Abstract
INTRODUCTION
Nanoscience and Nanotechnology
Nanotechnology in the 20th Century
Nanomaterials Classification
Different Methods Of Generation Of Nps
Bottom-up Approaches
Sol-gel Method
Advantage
Disadvantage
Hydrothermal Method
Advantages
Disadvantage
Chemical Vapour Deposition Method
Advantages
Disadvantages
Top-down Approaches to the Synthesis of NPS
Ball Milling Method
Advantage
Disadvantage
Laser Ablation Method
Advantages
Disadvantages
Electrochemical Discharge Methods
Influencing Process Parameter of ECDP for NPs Synthesis
Advantage
Disadvantage
CONCLUSION
ACKNOWLEDGMENTS
REFERENCES
Heterogeneous Semiconductor Photocatalysis for Water Purification: Basic Mechanism and Advanced Strategies
Abstract
Introduction
Photocatalysis and its Basic Mechanism
Strategies to Improve the Catalytic Efficiency and Light Absorption
Doping of Metal or Non-metal
Metal Ion Doping
Non-metal Doping
Surface Plasmon Resonance
Construction of Semiconductor Heterostructure
Z-scheme Heterostructure Formation
Factors Affecting the Catalytic Efficiency
Effects of Particle Size, Morphology and Crystal Structure
Effect of pH
Effect of Catalyst Concentration
Effect of Pollutant Concentration
Effect of Light Intensity
Effect of Temperature
Effect of O2 Concentration
CONCLUSION
REFERENCES
Advanced Materials and Nano Systems: Theory and Experiment
(Part 3)
Edited by
Dibya Prakash Rai
Department of Physics
Mizoram University
Aizawl, India
Kingsley O. ObodoI
CTP-East African Institute for Fundamental
Research, Kigali, Rwanda
Center for Space Research, North-West University
Potchefstroom, South Africa
National Institute of Theoretical and Computational
Sciences, Johannesburg, South Africa
&
Jitendra Pal Singh
Department of Sciences (Physics)
Manav Rachna University
Faridabad, India
BENTHAM SCIENCE PUBLISHERS LTD.
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FOREWORD
First of all, I would like to congratulate Dr. Dibya Prakash Rai for successfully publishing a series of two books, Part 1 & 2, entitled “Advanced Materials and Nano Systems: Theory and Experiment”. Following the success of the previous two books, the editor is motivated for the third edition. I believe this third edition of the book will receive grand success with the support of two dynamic researchers Dr. Kingsley O. Obodo and Dr. Jitendra Pal Singh. The subjects covered in this book range from bulk to nanoscale materials at all applied levels, including some of the most significant and current issues in materials science and nanosystems. It includes introductory chapters, discussions of fundamentals, and problems with in-depth solutions. It covers practically all of the subject matter in the concerned discipline. This book walks readers through using the most basic features or utilities of a program or method. I have had the pleasure of reading several extremely fascinating chapters on the creation of nanoparticles. These chapters concentrate on the potential for reducing environmental pollution and the application of nanosystems for energy harvesting. This book also addresses the existing constraints and difficulties in the development of nanotechnology. It offers a perspective on its potential future development and application in overcoming the current energy crisis, in medicine, and the evolution of digital technology, etc. Over the past 20 years, there has been a tremendous increase in nanotechnology research, which focuses on the science, technology and engineering of nanoscale materials. Nanotechnology has seen a rise in global investment from all sectors, including the public, businesses, governments, institutes, etc. Developed nations, including the United States, Germany, the United Kingdom, France, and others, are working to advance research and development in this crucial sector and creating the scientific understanding required to address queries and worries about the potential effects of this nanotechnology on the environment, health, and safety. In both clinical care and biological research, nanotechnology is gaining importance and prominence. Nanotechnology is anticipated to have a bright future in many facets of medicine, much like other sciences. Nanoparticles can deliver medications into cells to reach illness areas because of their tiny size, which raises local drug concentrations and lowers systemic toxicities. The diversity and promise of nanotechnology products thrill me. Still, I am also conscious of the challenging research required to provide solid answers to important queries regarding their potential effects on human health and the environment. To consider the possible influence on human health that this new and promising kind of material science represents, many of the established assumptions of safety and health must be re-examined, if not modified. Technological advancements have made it possible for humans to view atoms, manipulate them individually, alter their positions one at a time, and utilize them to generate new codes. The challenge was and continues to be, how to handle the system at an atomic scale. This is a challenging undertaking, but it is still feasible. Electronics experts who work with integrated circuits participated in the race for shrinking as well as moving circuitry from micro to submicron levels and reaching ever-closer to the nanoscale. The concept of electronics will need to be completely rethought if researchers ultimately get to the point where a single electron serves as the foundation for electronics (nano-transistor). Since other scientific disciplines like mechanics, optics, chemistry, and biology have also begun to create their nanoworlds, which we now refer to as nanosystems, this evolution is not simply affecting electronics. The silicon airbag's accelerometer in automobiles refers to the example of a mass-produced nanosystem. As far as I am concerned, the application of nanosystems as nanomotors, nanorobots or nano-transistor has not been realized yet. This is because development from lab-scale to commercial-scale will take some time. In actuality, the energy situation is what is most concerning. Rapid energy use eventually threatens the viability of life and may even bring about the end of the contemporary planet one day. As a result, one should seek renewable energy sources or locations where energy may be produced without harming the environment. We may find various promising energy harvesting technologies in the field of materials science, such as thermoelectricity, piezoelectricity, solid-state batteries, etc. Since revolutions and technological advancement do not come naturally to people or communities, it is to be expected that certain worries will accompany these developments. We must be cognizant of the current difficulties and the issues at hand. I want to invite the readers to continue reading this book. Let's explore this new universe in all the forms of materials science while maintaining the realism of an engineer and the creative progress.
Victor Sunday Aigbodion
Department of Metallurgy and Materials Engineering
Faculty of Engineering, University of Nigeria
Nsukka, Nigeria
PREFACE
List of Contributors
A. El KenzLaboratory of Condensed Matter and Interdisciplinary Sciences (LaMScI), Faculty of Science, Mohammed V University of Rabat, Rabat, MoroccoA. BenyoussefLaboratory of Condensed Matter and Interdisciplinary Sciences (LaMScI), Faculty of Science, Mohammed V University of Rabat, Rabat, MoroccoAlok Kumar DasIndian Institute of Technology, Indian School of Mines, Dhanbad, IndiaAdedapo S. AdeyinkaResearch Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg, Johannesburg, South AfricaAparna RoyDepartment of Zoology , University of Calcutta, Kolkata, West Bengal, IndiaBiswajit RoyCSIR-Centre for Cellular and Molecular Biology, Hyderabad, Telangana, IndiaDibya Prakash RaiDepartment of Physics, Mizoram University, Aizawl, IndiaDivya RaiDepartment of Zoology , University of Calcutta, Kolkata, West Bengal, IndiaD. VigneshBirla Institute of Technology, Mesra, Ranchi, Jharkhand, IndiaEla RoutBirla Institute of Technology, Mesra, Ranchi, Jharkhand, IndiaHarish BishwakarmaIndian Institute of Technology, Indian School of Mines, Dhanbad, IndiaHabib RachedMagnetic Materials Laboratory, Faculty of Exact-Sciences, Djillali-Liabès University of Sidi-Bel-Abbès, Sidi-Bel-Abbès, AlgeriaIsmail OuadhaMagnetic Materials Laboratory, Faculty of Exact-Sciences, Djillali-Liabès University of Sidi-Bel-Abbès, Sidi-Bel-Abbès, AlgeriaKumaresh MandalDepartment of Zoology , University of Calcutta, Kolkata, West Bengal, IndiaKingsley O. ObodoICTP-East African Institute for Fundamental Research, Kigali, Rwanda
Center for Space Research, North-West University Potchefstroom, South Africa
National Institute of Theoretical and Computational Sciences, Johannesburg, South AfricaLalrinthara PachuauDepartment of Physics, Physical Sciences Research Centre (PSRC), Pachhunga University College, Aizawl, Mizoram, IndiaLalmuanpuia VanchhawngDepartment of Physics, Physical Sciences Research Centre (PSRC), Pachhunga University College, Aizawl, Mizoram, IndiaLalmuan ChhanaDepartment of Physics, School of Physical Sciences, Mizoram University, Aizawl, Mizoram, India
Physical Sciences Research Centre (PSRC), Department of Physics, Pachhunga University College, Mizoram University, Aizawl, Mizoram, IndiaLalhriat ZualaPhysical Sciences Research Centre (PSRC), Department of Physics, Pachhunga University College, Mizoram University, Aizawl, Mizoram, IndiaLalrin KimaDepartment of Physics, Mizoram University, Aizawl, India
Department of Physics, Pachhunga University College, Mizoram University, Aizawl, IndiaLalhumhimaDepartment of Physics, Physical Sciences Research Centre (PSRC), Pachhunga University College, Aizawl, Mizoram, India
Department of Physics, Mizoram University, Aizawl, Mizoram, IndiaLalmuanchhanaDepartment of Physics, Physical Sciences Research Centre (PSRC), Pachhunga University College, Aizawl, Mizoram, India
Department of Physics, Mizoram University, Aizawl, Mizoram, IndiaMukul AnandIndian Institute of Technology, Indian School of Mines, Dhanbad, IndiaM. HoumadLaboratory of Condensed Matter and Interdisciplinary Sciences (LaMScI), Faculty of Science, Mohammed V University of Rabat, Rabat, MoroccoM. KhuiliSuperior School of Technology (EST-Khenifra), University of Sultan Moulay Slimane, Khenifra, 54000, MoroccoNaorem Premjit SinghA. R. S. D. College, University of Delhi, Dhaula Kuan, New Delhi, IndiaRakesh TamangDepartment of Zoology , University of Calcutta, Kolkata, West Bengal, IndiaRamesh Chandra TiwariDepartment of Physics, School of Physical Sciences, Mizoram University, Aizawl, Mizoram, IndiaShivraj GurungPhysical Sciences Research Centre (PSRC), Department of Physics, Pachhunga University College, Mizoram University, Aizawl, Mizoram, IndiaShishir TamangDepartment of Zoology , University of Calcutta, Kolkata, West Bengal, India
Department of Zoology, Darjeeling Government College, Darjeeling, West Bengal, IndiaSoni SubbaDepartment of Zoology , University of Calcutta, Kolkata, West Bengal, IndiaSaptaparni DeDepartment of Zoology , University of Calcutta, Kolkata, West Bengal, IndiaShomaila KhanamDepartment of Physics, Birla Institute of Technology, Mesra, Ranchi, Jharkhand, IndiaSanjeeb Kumar RoutDepartment of Physics, Birla Institute of Technology, Mesra, Ranchi, Jharkhand, IndiaYengkhom Rangeela DeviDepartment of Physics, Pachhunga University College (PUC), Aizawl, Mizoram, IndiaZodinmawiaDepartment of Physics, Mizoram University, Aizawl, Mizoram, IndiaZodinmawiaDepartment of Physics, School of Physical Sciences, Mizoram University, Aizawl, Mizoram, India
Role of Plasmonic Metal-semiconductor Hetero-structure in Photo Catalytic Hydrolysis and Degradation of Toxic Dyes
Shomaila Khanam1,Sanjeeb Kumar Rout1,*
1 Department of Physics, Birla Institute of Technology, Mesra, Ranchi, Jharkhand, India
Abstract
Plasmonic metal-semiconductor heterostructure has become the most prominent content for water splitting by photocatalytic means. It is thought to be an effective, clean, and affordable energy source. Hydrolysis, water splitting, and destruction of organic dyes have all demonstrated the high efficiency of LSPR formation by these materials. A noble metal combined with a low bandgap semiconductor makes for the perfect photocatalyst. In this case, both semiconductors and noble metals can absorb visible light. They are prone to producing positive and negative pairs and inhibit their recombination, causing the resulting electron-hole pairs to interact with the chemicals in the immediate environment, thereby increasing photocatalytic activity. The strong SPR's combined effect with the efficient separation of photogenerated electrons and holes supported by noble metal particles can be credited with the increased photocatalytic activity. It has become a useful method for overcoming the limitations of conventional photocatalysts and promoting photocatalytic mechanisms.
This book chapter has three main goals: briefly describing plasmonic dynamics, explaining the preparation techniques, analyzing the key characteristics of the plasmonic metal nanostructure that influence photocatalysis, summarizing the reported literature, and offering an in-depth explanation of the four fundamental plasmonic energy transfer process.
Keywords: Ammonia borane, Localized surface, Plasmon resonance effect, Photocatalytic degradation, Plasmonic, Photocatalytic hydrolysis.
*Corresponding author Sanjeeb Kumar Rout: Department of Physics, Birla Institute of Technology, Mesra, Ranchi, Jharkhand, India; E-mail:
[email protected]