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Interdisciplinary approach to sustainability, illustrating current catalytic approaches in applied chemistry, chemical engineering, and materials science Catalysis for a Sustainable Environment covers the use of catalysis in its various approaches, including homogeneous, supported, and heterogeneous catalysis, and photo- and electrocatalysis, towards sustainable environmental benefits. The text fosters interdisciplinarity in sustainability by illustrating modern perspectives in catalysis, from fields including inorganic, organic, organometallic, bioinorganic, pharmacological, and analytical chemistry, along with chemical engineering and materials science. The chapters are grouped in seven sections on (i) Carbon Dioxide Utilization, (ii) Volatile Organic Compounds (VOCs) Transformation, (iii) Carbon-based Catalysis, (iv) Coordination, Inorganic, and Bioinspired Catalysis, (v) Organocatalysis, (vi) Catalysis for Water and Liquid Fuels Purification, and (vii) Hydrogen Formation/Storage. Sample topics covered in Catalysis for a Sustainable Environment include: * Activation of relevant small molecules with strong environmental impact and carbon-based catalysts for sustainable chemical processes * Catalytic synthesis of important added value organic compounds, in both commodity and fine chemistries (large and small scale productions, respectively) * Development of catalytic systems operating under environmentally benign and mild conditions towards the establishment of sustainable energy processes * Catalysis by coordination, metal and metal-free compounds, MOFs (metal-organic frameworks) and nanoparticles, and their contribution to environmental and sustainable processes Employing the latest approaches that impact global and circular economies, Catalysis for a Sustainable Environment serves as an excellent starting point for innovative catalytic approaches, and will appeal to professionals in engineering, academia, and industry who wish to improve existing processes and materials.
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Seitenzahl: 2052
Veröffentlichungsjahr: 2024
Edited by
Professor Armando J. L. Pombeiro
Instituto Superior técnicoLisboa, Portugal
Dr. Manas Sutradhar
Universidade Lusófona de Humanidades e TecnologiasFaculdade de EngenhariaLisboa, Portugal
Professor Elisabete C. B. A. Alegria
Instituto Politécnico de LisboaDepartamento de Engenharia QuímicaLisboa, Portugal
This edition first published 2024
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Armando Pombeiro is a Full Professor Jubilado at Instituto Superior Técnico, Universidade de Lisboa (ULisboa), former Distant Director at the People’s Friendship University of Russia (RUDN University), a Full Member of the Academy of Sciences of Lisbon (ASL), the President of the Scientific Council of the ASL, a Fellow of the European Academy of Sciences (EURASC), a Member of the Academia Europaea, founding President of the College of Chemistry of ULisboa, a former Coordinator of the Centro de Química Estrutural at ULisboa, Coordinator of the Coordination Chemistry and Catalysis group at ULisboa, and the founding Director of the doctoral Program in Catalysis and Sustainability at ULisboa. He has chaired major international conferences. His research addresses the activation of small molecules with industrial, environmental, or biological significance (including alkane functionalization, oxidation catalysis, and catalysis in unconventional conditions) as well as crystal engineering of coordination compounds, polynuclear and supramolecular structures (including MOFs), non-covalent interactions in synthesis, coordination compounds with bioactivity, molecular electrochemistry, and theoretical studies.
He has authored or edited 10 books, (co-)authored ca. 1000 research publications, and registered ca. 40 patents. His work received over. 30,000 citations (over 12,000 citing articles), h-index ca. 80 (Web of Science).
Among his honors, he was awarded an Honorary Professorship by St. Petersburg State University (Institute of Chemistry), an Invited Chair Professorship by National Taiwan University of Science & Technology, the inaugural SCF French-Portuguese Prize by the French Chemical Society, the Madinabeitia-Lourenço Prize by the Spanish Royal Chemical Society, and the Prizes of the Portuguese Chemical and Electrochemical Societies, the Scientific Prizes of ULisboa and Technical ULisboa, and the Vanadis Prize. Special issues of Coordination Chemistry Reviews and the Journal of Organometallic Chemistry were published in his honor.
https://fenix.tecnico.ulisboa.pt/homepage/ist10897
Manas Sutradhar is an Assistant Professor at the Universidade Lusófona, Lisbon, Portugal and an integrated member at the Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Portugal. He was a post‐doctoral fellow at the Institute of Inorganic and Analytical Chemistry of Johannes Gutenberg University of Mainz, Germany and a researcher at the Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa. He has published 72 papers in international peer review journals (including three reviews + 1 reference module), giving him an h-index 28 (ISI Web of Knowledge) and more than 2250 citations. In addition, he has 11 book chapters in books with international circulation and one patent. He is one of the editors of the book Vanadium Catalysis, published by the Royal Society of Chemistry. His main areas of work include metal complexes with aroylhydrazones, oxidation catalysis of industrial importance and sustainable environmental significance, magnetic properties of metal complexes, and bio-active molecules. The major contributions of his research work are in the areas of vanadium chemistry and oxidation catalysis. He received the 2006 Young Scientist Award from the Indian Chemical Society, India and the Sir P. C. Ray Research Award (2006) from the University of Calcutta, India.
https://orcid.org/0000-0003-3349-9154
Elisabete C.B.A. Alegria is an Adjunct Professor at the Chemical Engineering Department of the Instituto Superior de Engenharia de Lisboa (ISEL) of the Polytechnic Institute of Lisbon, Portugal. She is a researcher (Core Member) at the Centro de Química Estrutural (Coordination Chemistry and Catalysis Group). She has authored 86 papers in international peered review journals and has an h-index of 23 with over 1600 citations, four patents, five book chapters, and over 180 presentations at national and international scientific meetings. She was awarded an Honorary Distinction (2017–2020) for the Areas of Technology and Engineering (Scientific Prize IPL-CGD). She is an editorial board member, and has acted as a guest editor and reviewer for several scientific journals. Her main research interests include coordination and sustainable chemistry, homogeneous and supported catalysis, stimuli‐responsive catalytic systems, green synthesis of metallic nanoparticles for catalysis, and biomedical applications. She is also interested in mechanochemistry (synthesis and catalysis) and molecular electrochemistry.
https://orcid.org/0000-0003-4060-1057
Aiming to change the world for the better, 17 Sustainable Development Goals (SDGs) were adopted by the United Nations (UN) Member States in 2015, as part of the UN 2030 Agenda for Sustainable Development that concerns social, economic, and environmental sustainability. Hence, a 15-year plan was set up to achieve these Goals and it is already into its second half.
However, the world does not seem to be on a good track to reach those aims as it is immersed in the Covid-19 pandemic crisis and climate emergency, as well as economic and political uncertainties. Enormous efforts must be pursued to overcome these obstacles and chemical sciences should play a pivotal role. Catalysis is of particular importance as it constitutes the most relevant contribution of chemistry towards sustainable development. This is true even though the SDGs are integrated and action in one can affect others.
For example, the importance of chemistry and particularly catalysis is evident in several SDGs. Goal 12, addresses “Responsible Consumption and Production Patterns” and is aligned with the circularity concept with sustainable loops or cycles (e.g., in recycle and reuse processes that are relevant within the UN Environmental Program). Goal 7 addresses “Affordable and Clean Energy” and relates to efforts to improve energy conversion processes, such as hydrogen evolution and oxygen evolution from water, that have a high environmental impact. Other SDGs in which chemistry and catalysis play an evident role with environmental significance include Goal 6 (“Clean Water and Sanitation”), Goal 9 (“Industry, Innovation and Infrastructure” 13 (“Climate Action”), Goal 14 (“Life Below Water”), and Goal 15 (“Life on Land”).
The book is aligned with these SDGs by covering recent developments in various catalytic processes that are designed for a sustainable environment. It gathers skilful researchers from around the world to address the use of catalysis in various approaches, including homogeneous, supported, and heterogeneous catalyses as well as photo- and electrocatalysis by searching for innovative green chemistry routes from a sustainable environmental angle. It illustrates, in an authoritative way, state-of-the-art knowledge in relevant areas, presented from modern perspectives and viewpoints topics in coordination, inorganic, organic, organometallic, bioinorganic, pharmacological, and analytical chemistries as well as chemical engineering and materials science.
The chapters are spread over seven main sections focused on Carbon Dioxide Utilization, Transformation of Volatile Organic Compound (VOCs), Carbon-based Catalysts, Coordination, Inorganic, and Bioinspired Catalysis, Organocatalysis, Catalysis for the Purification of Water and Liquid Fuels,and Hydrogen Formation, Storage, and Utilization. These sections are gathered together as a contribution towards the development of the challenging topic.
The book addresses topics in (i) activation of relevant small molecules with strong environmental impacts, (ii) catalytic synthesis of important added value organic compounds, and (iii) development of systems operating under environmentally benign and mild conditions toward the establishment of sustainable energy processes.
This work is expected to be a reference for academic and research staff of universities and research institutions, including industrial laboratories. It is also addressed to post-doctoral, postgraduate, and undergraduate students (in the latter case as a supplemental text) working in chemical, chemical engineering, and related sciences. It should also provide inspiration for research topics for PhD and MSc theses, projects, and research lines, in addition to acting as an encouragement for the development of the overall field.