Ceramics Science and Technology, Volume 2 -  - E-Book

Ceramics Science and Technology, Volume 2 E-Book

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Beschreibung

Although ceramics have been known to mankind literally for millennia, research has never ceased. Apart from the classic uses as a bulk material in pottery, construction, and decoration, the latter half of the twentieth century saw an explosive growth of application fields, such as electrical and thermal insulators, wear-resistant bearings, surface coatings, lightweight armour, or aerospace materials. In addition to plain, hard solids, modern ceramics come in many new guises such as fabrics, ultrathin films, microstructures and hybrid composites.
Built on the solid foundations laid down by the 20-volume series Materials Science and Technology, Ceramics Science and Technology picks out this exciting material class and illuminates it from all sides.
Materials scientists, engineers, chemists, biochemists, physicists and medical researchers alike will find this work a treasure trove for a wide range of ceramics knowledge from theory and fundamentals to practical approaches and problem solutions.

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Seitenzahl: 1791

Veröffentlichungsjahr: 2015

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Table of Contents

Cover

Series

Title

Copyright

Preface

List of Contributors

I: Ceramic Material Classes

1: Ceramic Oxides

1.1 Introduction

1.2 Aluminum Oxide

1.3 Magnesium Oxide

1.4 Zinc Oxide

1.5 Titanium Dioxide

1.6 Zirconium Oxide

1.7 Cerium Oxide

1.8 Yttrium Oxide

References

2: Nitrides

2.1 Silicon Nitride

2.2 Boron Nitride

2.3 Aluminum Nitride

2.4 Titanium Nitride

2.5 Tantalum Nitride

2.6 Chromium Nitride

2.7 Ternary Nitrides

2.8 Light-Emitting Nitride and Oxynitride Phosphors

References

3: Gallium Nitride and Oxonitrides

3.1 Introduction

3.2 Gallium Nitrides

3.3 Gallium Oxides

3.4 Gallium Oxonitrides

3.5 Outlook

References

4: Silicon Carbide- and Boron Carbide-Based Hard Materials

4.1 Introduction

4.2 Structure and Chemistry

4.3 Production ofParticles and Fibers

4.4 Dense Ceramic Shapes

4.5 Properties of Silicon Carbide- and Boron Carbide-Based Materials

4.6 Application of Carbides

References

5: Complex Oxynitrides

5.1 Introduction

5.2 Principles of Silicon-Based Oxynitride Structures

5.3 Complex Si–Al–O–N Phases

5.4 M–Si–Al–O–N Oxynitrides

5.5 Oxynitride Glasses

5.6 Oxynitride Glass Ceramics

5.7 Conclusions

References

6: Perovskites

6.1 Introduction

6.2 Crystal Structure

6.3 Physical Properties

6.4 Chemical and Catalytic Properties

6.5 Summary

References

7: The M

n

+1

AX

n

Phases and their Properties

7.1 Introduction

7.2 Bonding and Structure

7.3 Elastic Properties

7.4 Electronic Transport

7.5 Thermal Properties

7.6 Mechanical Properties

7.7 Tribological Properties and Machinability

7.8 Concluding Remarks

References

II: Structures and Properties

8: Structure–Property Relations

8.1 Introduction

8.2 Self-Reinforced Silicon Nitrides

8.3 Fibrous Grain-Aligned Silicon Nitrides (Large Grains)

8.4 Fibrous Grain-Aligned Silicon Nitrides (Small Grains)

8.5 Grain Boundary Phase Control

8.6 Fibrous Grain-Aligned Porous Silicon Nitrides

References

9: Dislocations in Ceramics

9.1 Introduction

9.2 The Critical Resolved Shear Stress

9.3 Crystallography of Slip

9.4 Dislocations in Particular Oxides

9.5 Work Hardening

9.6 Solution Hardening

9.7 Closing Remarks

References

10: Defect Structure, Nonstoichiometry, and Nonstoichiometry Relaxation of Complex Oxides

10.1 Introduction

10.2 Defect Structure

10.3 Oxygen Nonstoichiometry

10.4 Nonstoichiometry Re-Equilibration

References

11: Interfaces and Microstructures in Materials

11.1 Introduction

11.2 Interfaces in Materials

11.3 Practical Implications

11.4 Summary and Outlook

References

III: Mechanical Properties

12: Fracture of Ceramics

12.1 Introduction

12.2 Appearance of Failure and Typical Failure Modes

12.3 A Short Overview of Damage Mechanisms

12.4 Brittle Fracture

12.5 Probabilistic Aspects of Brittle Fracture

12.6 Delayed Fracture

12.7 Concluding Remarks

References

13: Creep Mechanisms in Commercial Grades of Silicon Nitride

13.1 Introduction

13.2 Material Characterization

13.3 Discussion of Experimental Data

13.4 Models of Creep in Silicon Nitride

13.5 Conclusions

References

14: Fracture Resistance of Ceramics

14.1 Introduction

14.2 Theory of Fracture

14.3 Toughened Ceramics

14.4 Influence of Crack Growth Resistance Curve Upon Failure by Fracture

14.5 Determination of Fracture Resistance

14.6 Fatigue

14.7 Concluding Remarks

References

15: Superplasticity in Ceramics: Accommodation-Controlling Mechanisms Revisited

15.1 Introduction

15.2 Macroscopic and Microscopic Features of Superplasticity

15.3 Nature of the Grain Boundaries

15.4 Accommodation Processes in Superplasticity

15.5 Applications of Superplasticity

15.6 Future Prospective in the Field

References

IV: Thermal, Electrical, and Magnetic Properties

16: Thermal Conductivity

16.1 Introduction

16.2 Thermal Conductivity of Dielectric Ceramics

16.3 High-Thermal Conductivity Nonoxide Ceramics

16.4 Mechanical Properties of High-Thermal Conductivity Si

3

N

4

Ceramics

16.5 Concluding Remarks

References

17: Electrical Conduction in Nanostructured Ceramics

17.1 Introduction

17.2 Space Charge Layers in Semiconducting Ceramic Materials

17.3 Effect of Space Charge Profiles on the Observed Conductivity

17.4 Influence of Nanostructure on Charge Carrier Distributions

17.5 Case Studies

17.6 Conclusions and Observations

References

18: Ferroelectric Properties

18.1 Introduction

18.2 Intrinsic Properties: The Anisotropy of Properties

18.3 Extrinsic Properties: Hard and Soft Ferroelectrics

18.4 Textured Ferroelectric Materials

18.5 Ferroelectricity and Magnetism

18.6 Fatigue in Ferroelectric Materials

References

19: Magnetic Properties of Transition-Metal Oxides: From Bulk to Nano

19.1 Introduction

19.2 Properties of Transition Metal 3d Orbitals

19.3 Iron Oxides

19.4 Ferrites

19.5 Chromium Dioxide

19.6 Manganese Oxide Phases

19.7 Concluding Remarks

References

Index

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