Conjugated Polymer Synthesis E-Book

• Herausgeber: Wiley-VCH
• Kategorie: Wissenschaft und neue Technologien
• Sprache: Englisch

Seitenzahl: 470

Veröffentlichungsjahr: 2011

Beschreibung

Edited and authored by top international experts, this first book on conjugated polymers with a focus on synthesis provides a detailed overview of all modern synthetic methods for these highly interesting compounds. As such, it describes every important compound class, including polysilanes, organoboron compounds, and ferrocene-containing conjugated polymers. An indispensable source for every synthetic polymer chemist.

Leseprobe

Contents

Preface

List of Contributors

1 Organometallic polycondensation for Conjugated polymers

1.1 Basic Organometallic C–C Coupling

1.2 Syntheses of π-Conjugated polymers

1.3 Optical properties

1.4 Redox Behavior and Electrical Conductivity

1.5 Linear Structure and Alignment on the Surface of Substrates

1.6 Stacking in the Solid and Colloid

1.7 Chemical Reactivity and Catalysis

1.8 Electronic and Optical Devices (ECD, Battery, EL, Diode, Transistor, Nonlinear Optical Device, etc.)

1.9 Conclusions

References

2 Catalyst-Transfer Condensation polymerization for precision Synthesis of π-Conjugated polymers

2.1 Introduction

2.2 Kumada–Tamao Coupling polymerization with Ni Catalyst

2.3 Suzuki–Miyaura Coupling polymerization with pd Catalyst

2.4 Conclusion

References

3 Regioregular and Regiosymmetric polythiophenes

3.1 Introduction

3.2 Synthesis of polythiophene and Regioirregular polythiophenes

3.3 Head-to-Tail Coupled Regioregular poly(3-Alkylthiophene)s

3.4 Side Chain Functionalized HT Regioregular polythiophenes

3.5 End Group Functionalized HT Regioregular polythiophenes

3.6 Block Copolymers Derived from HT Regioregular polythiophenes

3.7 Universal Use of the GRIM Method

3.8 Regiosymmetric polythiophenes

3.9 Summary

References

4 Functional Hyperbranched polymers Constructed from Acetylenic An-Type Building Blocks

4.1 Introduction

4.2 Hyperbranched polymers Constructed from Acetylenic An-Type Building Blocks

4.3 Conclusions

References

5 Through-Space Conjugated polymers

5.1 Introduction

5.2 Through-Space Conjugated polymers with the Layered π-Electron Systems in the Side Chain

5.3 Through-Space Conjugated polymers with the Layered p-Electron Systems in the Main Chain

5.4 Conclusion

References

6 Fully Conjugated Nano-Sized Macrocycles: Syntheses and Versatile properties

6.1 Introduction

6.2 Synthesis of π-Conjugated Macrocycles

6.3 Isolation and Self-Association in Solution and in the Solid State

6.4 Versatile properties of Giant π-Conjugated Macrocycles

6.5 Conclusion

References

7 Organoboron Conjugated polymers

7.1 Introduction

7.2 Tricoordinate Boron π-Conjugated polymers

7.3 Tetracoordinate Boron π-Conjugated polymers

7.4 π-Conjugated Carborane-Based polymers

7.5 Conclusions

References

8 Recent Developments in π-Conjugated Macromolecules with phosphorus Atoms in the Main Chain

8.1 Introduction

8.2 poly(phosphole) and Related polymers

8.3 poly(p-phenylenephosphine) and Related polymers

8.4 poly(Vinylenephosphine)s and Related polymers

8.5 poly(p-phenylenephosphaalkene)s and Related polymers

8.6 poly(p-phenylenediphosphene)s and Related polymers

8.7 Summary

References

9 Organo-Arsenic, phosphorus, and Antimony Conjugated polymers

9.1 Introduction

9.2 Survey of Group 15 Element-Containing polymers

9.3 Carbon–Main Group Element Bond Formation Via Bismetallation

9.4 Homocyclic Compounds of Group 15 Elements

9.5 poly(Vinylene-Arsine)s

9.6 poly(Vinylene-phosphine)s

9.7 poly(Vinylene-Stibine)s

9.8 periodic Terpolymerization of Cyclooligoarsine, Cyclooligostibine, and an Acetylenic Compound

9.9 Stability

9.10 Optical properties

9.11 Coordination Ability of poly(Vinylene-Arsine)s Towards Transition Metal Ions

9.12 Cross-Linked poly(Vinylene-Arsine)s

9.13 Conclusion

References

10 Synthetic Strategies to Conjugated Main-Chain Metallopolymers

10.1 Introduction

10.2 π-Conjugated polymers with Terpyridine Units and Other Tridentate Ligands as part of the Main Chain

10.3 π-Conjugated polymers with porphyrin Units as part of the Main Chain

10.4 Rigid-Rod polymetallaynes

10.5 Conclusion and Outlook

References

11 Helical polyacetylene prepared in a Liquid Crystal Field

11.1 Introduction

11.2 Chiral Dopants and Chiral Nematic LCs

11.3 Acetylene polymerization in Chiral Nematic LC

11.4 Characterization of Helical polyacetylene Film

11.5 Summary

References

Index

The Editor

Prof. Yoshiki Chujo

Kyoto University

Graduate School of Engineering

Department of Polymer Chemistry

Katsura Nishikyo-ku

Kyoto 615-8510

Japan

All books published by Wiley-VCH are carefully produced. Nevertheless, authors, editors, and publisher do not warrant the information contained in these books, including this book, to be free of errors. Readers are advised to keep in mind that statements, data, illustrations, procedural details or other items may inadvertently be inaccurate.

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Bibliographic information publishd by the Deutsche Nationalbibliothek

The Deutsche Nationalbibliothek lists this publication in the Deutsche Nationalbibliografie; detailed bibliographic data are available on the Internet at http://dnb.d-nb.de.

© 2010 WILEY-VCH Verlag & Co. KGaA, Boschstr. 12, 69469 Weinheim, Germany

All rights reserved (including those of translation into other languages). No part of this book may be reproduced in any form–by photoprinting, microfilm, or any other means–nor transmitted or translated into a machine language without written permission from the publishers. Registered names, trademarks, etc. used in this book, even when not specifically marked as such, are not to be considered unprotected by law.

ISBN: 978-3-527-32267-1

Preface

This book “Conjugated Polymer Synthesis–Methods and Reactions“ aims to summarize the major developments in the topics of synthesis of new conjugated polymers, novel methodologies for the preparation of conjugated polymers, and inorganic-elements containing mainchain-type conjugated polymers. These new compounds and materials are all set to be very important in the fields of electrical, optical, and magnetic applications.

Much effort has been devoted to the design and synthesis of a wide variety of conjugated polymers such as polyacetylene, polythiophene, polypyrrole, poly(p-phenylene), poly(p-phenylenevinylene), poly(p-phenylene-ethynylene), polyfluorene and their derivatives. This is not only due to an academic interest in their particular characteristic properties, but also owing to various industrial utilizations. Potential applications here include organic light-emitting diodes, flat panel displays, sensory materials, semiconductors, field-effect transistors, photovoltaic cells, and so on. To achieve high performance in these applications, it is now necessary to explore new, more conjugated polymers. These new conjugated systems might be expected to show high emission efficiency, fine-tunability of their band-gaps, processability, dramatic improvements in durability, thermal-, air- and photo-stabilities, and other important characteristic properties.

In each of the chapters, all of them written by internationally acclaimed experts, the book covers the whole spectrum of the synthesis of new conjugated polymers from fundamentals to material science applications. I hope that the readers will enjoy this new chemistry and methodology developed throughout the book.

August 2010

Yoshiki Chujo

List of Contributors

Kazuo Akagi

Kyoto University

Department of Polymer Chemistry

Katsura

Kyoto 615-8510

Japan

Yoshiki Chujo

Kyoto University

Graduate School of Engineering

Department of Polymer Chemistry

Katsura, Nishikyo-ku

Kyoto 615-8510

Japan

Derek P. Gates

University of British Columbia

Department of Chemistry

2036 Main Mall

Vancouver, British Columbia

Canada V6T 1Z1

Martin D. Hager

Friedrich-Schiller-University Jena

Laboratory of Organic and

Macromolecular Chemistry

Humboldtstr. 10

07743 Jena

Germany

Masahiko Iyoda

Department of Chemistry

Graduate School of Science

Tokyo Metropolitan University

Hachioji

Tokyo 192-0397

Japan

Jacky W.Y. Lam

The Hong Kong University of

Science & Technology

Department of Chemistry

Clear Water Bay

Kowloon, Hong Kong

China

Jianzhao Liu

The Hong Kong University of

Science & Technology

Department of Chemistry

Clear Water Bay

Kowloon, Hong Kong

China

Richard D. McCullough

Carnegie Mellon University

Department of Chemistry

4400 Fifth Ave.

Pittsburgh, PA 15213

USA

Yasuhiro Morisaki

Kyoto University

Graduate School of Engineering

Department of Polymer Chemistry

Katsura, Nishikyo-ku

Kyoto 615-8510

Japan

Atsushi Nagai

Kyoto University

Graduate School of Engineering

Department of Polymer Chemistry

Katsura, Nishikyo-ku

Kyoto 615-8510

Japan

Kensuke Naka

Kyoto Institute of Technology

Graduate School of Science and

Technology

Department of Chemistry and Materials

Technology

Goshokaido-cho, Matsugasaki, Sakyo-ku

Kyoto 606-8585

Japan

Itaru Osaka

Graduate School of Engineering

Department of Applied Chemistry

1-4-1 Kagamiyama, Higashi-hiroshima

Hiroshima 739-8527

Japan

Ulrich S. Schubert

Friedrich-Schiller-University Jena

Laboratory of Organic and

Macromolecular Chemistry

Humboldtstr. 10

07743 Jena

Germany

Paul W. Siu

University of British Columbia

Department of Chemistry

2036 Main Mall

Vancouver, British Columbia

Canada V6T 1Z1

Masayoshi Takase

Tokyo Metropolitan University

Graduate School of Science

Department of Chemistry

Hachioji

Tokyo 192-0397

Japan

Ben Zhong Tang

The Hong Kong University of Science & Technology

Department of Chemistry

Clear Water Bay

Kowloon, Hong Kong

China

and

Zhejiang University

Department of Polymer Science & Engineering

Hangzhou 310027

China

Andreas Wild

Friedrich-Schiller-University Jena

Laboratory of Organic and

Macromolecular Chemistry

Humboldtstr. 10

07743 Jena

Germany

Andreas Winter

Friedrich-Schiller-University Jena

Laboratory of Organic and

Macromolecular Chemistry

Humboldtstr. 10

07743 Jena

Germany

Takakazu Yamamoto

Tokyo Institute of Technology

Chemical Resources Laboratory

4259 Nagatsuta, Midori-ku

Yokohama 226-8503

Japan

Tsutomu Yokozawa

Kanagawa University

Department of Material and Life

Chemistry

Rokkakubashi, Kanagawa-ku

Yokohama 221-8686

Japan