Functional Supramolecular Architectures E-Book

• Herausgeber: Wiley-VCH
• Kategorie: Fachliteratur
• Sprache: Englisch

Seitenzahl: 1922

Veröffentlichungsjahr: 2014

Beschreibung

A comprehensive overview of functional nanosystems based on organic and polymeric materials and their impact on current and future research and technology in the highly interdisciplinary field of materials science. As such, this handbook covers synthesis and fabrication methods, as well as properties and characterization of supramolecular architectures. Much of the contents are devoted to existing and emerging applications, such as organic solar cells, transistors, diodes, nanowires and molecular switches. The result is an indispensable resource for materials scientists, organic chemists, molecular physicists and electrochemists looking for a reliable reference on this hot topic.

Leseprobe

CONTENTS

Cover

Series Page

Title Page

Copyright

Dedication

Preface

List of Contributors

Volume 1

Part One: Modeling and Theory

Chapter 1: Charge Transport in Organic Semiconductors: A Multiscale Modeling

1.1 Introduction

1.2 Organic Single Crystals

1.3 Tetrathiafulvalene Derivatives

1.4 Polythiophene Derivatives

1.5 Phthalocyanine Stacks

1.6 Polymer Dielectrics

1.7 Outlook

References

Chapter 2: Monte Carlo Studies of Phase Transitions and Cooperative Motion in Langmuir Monolayers with Internal Dipoles

2.1 Introduction

2.2 Computational Details

2.3 Results and Discussion

2.4 Summary

References

Chapter 3: Molecules on Gold Surfaces: What They Do and How They Go Around to Do It

3.1 Introduction

3.2 A Simple Description of the Geometrical Structure of Metals

3.3 A Simple Description of the Geometrical Structure of Molecules

3.4 Electronegativity Governs Chemical Interactions: Charge Equilibration, QEq, Models

3.5 A Simple Description of the Interaction between Metal Surfaces and Molecules

3.6 Presence of an External Electric Potential or Field

3.7 Generality of the Model and Its Transferability

3.8 Thiolates on Gold

3.9 Adsorption of a Large Molecule: C60

3.10 Simple Packing Problems

3.11 The Presence of an Electrostatic Potential

3.12 Challenges and Conclusion

References

Part Two: Supramolecular Synthetic Chemistry

Chapter 4: Conjugated Polymer Sensors: Design, Principles, and Biological Applications

4.1 Introduction

4.2 Water Solubility

4.3 Protein Detection

4.4 DNA Detection

4.5 Bacteria Detection

4.6 Electron-Deficient Polymers

4.7 Aggregation-Based Detection

4.8 Temperature-Responsive Fluorescent Polymers

4.9 Nonhomogeneous Detection Schemes

4.10 Mechanism of Energy Transfer

4.11 Conclusions and Future Directions

References

Chapter 5: Chromophoric Polyisocyanide Materials

5.1 Introduction

5.2 Polyisocyanide Materials

5.3 Perylene Polyisocyanides in Devices

5.4 TFT Devices

5.5 Morphology Control in Perylene/Crystal Systems

5.6 Postmodification of Polyisocyanopeptides

5.7 Toward Larger Length Scales: Polyisocyanopeptide Brushes

5.8 Summary and Outlook

References

Chapter 6: Functional Polyphenylenes for Supramolecular Ordering and Application in Organic Electronics

6.1 Introduction

6.2 Conjugated Polymers

6.3 Graphene Molecules and their Alignment

6.4 Rylenes Dyes

6.5 Dendritic Polyphenylenes: The Three-Dimensional Case

6.6 Conclusion and Outlook

References

Chapter 7: Molecular Tectonics: Design of Hybrid Networks and Crystals Based on Charge-Assisted Hydrogen Bonds

7.1 Introduction

7.2 Examples of Robust Charge-Assisted H-Bonded (CAHB) Networks

7.4 Charge-Assisted H-Bonded Networks Based on Amidinium Tectons

7.4 Charge-Assisted H-Bonded Networks Based on Amidinium and Polycyanometallate Tectons

7.5 Properties of Charge-Assisted H-Bonded Networks Based on Amidinium Tectons

7.6 Design of Crystals Based on CAHB Networks

7.7 Conclusion

References

Chapter 8: Synthesis and Design of π-Conjugated Organic Architectures Doped with Heteroatoms

8.1 Introduction

8.2 Boron

8.3.1 Sulfur, Selenium, and Tellurium

8.4 Miscellaneous

8.5 Conclusions

References

Part Three: Nanopatterning and Processing

Chapter 9: Functionalization and Assembling of Inorganic Nanocontainers for Optical and Biomedical Applications

9.1 Introduction

9.2 Zeolite L as Inorganic Nanocontainers

9.3 Functionalization of Zeolites: Host–Guest Chemistry and Surface and Channel Functionalizations

9.4 Photoinduced Processes in Zeolites

9.5 Self-Assembly in Solution and on Surfaces

9.6 Possible Optical and Biomedical Applications of Nanocontainers

References

Chapter 10: Soft Lithography for Patterning Self-Assembling Systems

10.1 Introduction

10.2 Self-Assembling Systems

10.3 Soft Lithography

10.4 Contact Printing of SAMs with High Resolution

10.5 Soft Lithography to Pattern Assemblies of Nanoparticles

10.6 Soft Lithography Pattern Supramolecular Assembly

10.7 Concluding Remarks

References

Chapter 11: Colloidal Self-Assembly of Semiconducting Polymer Nanospheres: A Novel Route to Functional Architectures for Organic Electronic Devices

11.1 Introduction

11.2 Formation of Semiconducting Polymer Nanospheres

11.3 Driving Forces behind Nanoparticle Self-Assembly Processes

11.4 Deposition Methods for Aqueous Dispersions of Semiconducting Polymer Nanospheres

11.5 Organic Electronic Devices from Semiconducting Polymer Nanospheres

11.6 Conclusions

Acknowledgment

References

Chapter 12: Photolithographic Patterning of Organic Electronic Materials

12.1 Introduction

12.2 Photolithographic Methods for Patterning Organic Materials

12.3 Conclusions and General Considerations

References

Part Four: Scanning Probe Microscopies

Chapter 13: Toward Supramolecular Engineering of Functional Nanomaterials: Preprogramming Multicomponent 2D Self-Assembly at Solid–Liquid Interfaces

13.1 Introduction

13.2 van der Waals Interactions

13.3 Hydrogen–Bonding Interactions

13.4 Metal–Ligand Interactions

13.5 Conclusions and Outlook

References

Chapter 14: STM Characterization of Supramolecular Materials with Potential for Organic Electronics and Nanotechnology

14.1 Introduction

14.2 Characterization Using STM and Related Technologies

14.3 Molecular Systems with Applications in Electronics

14.4 Optically Active Molecules

14.5 Magnetic Systems

14.6 STM Characterization and Biological Surface Science

14.7 Using the STM to Initiate Chemical Reactions

14.8 Conclusions and Perspective

List of Acronyms

References

Chapter 15: Scanning Probe Microscopy Insights into Supramolecular π-Conjugated Nanostructures for Optoelectronic Devices

15.1 Introduction: SPM Techniques for the Nanoscale Characterization of Organic Thin Films

15.2 Controlling the Supramolecular Assembly and Nanoscale Morphology of π-Conjugated (Macro)Molecules

15.3 Effect of the Nanoscale Morphology on the Optoelectronic Properties and Device Performances

15.4 Conclusions and Perspectives

References

Chapter 16: Single-Molecule Organic Electronics: Toward Functional Structures

16.1 Introduction

16.2 Techniques

16.3 Summary and Outlook

References

Volume 2

Part Five: Electronic and Optical Properties

Chapter 17: Charge Transfer Excitons in Supramolecular Semiconductor Nanostructures

17.1 Introduction

17.2 Experimental Methodologies

17.3 Delayed PL Decay Dynamics: Evidence of Charge Transfer Exciton Recombination in T6

17.4 Distribution of Charge Transfer Exciton Radii

17.5 Conclusions

References

Chapter 18: Optical Properties and Electronic States in Anisotropic Conjugated Polymers: Intra- and Interchain Effects

18.1 Introduction

18.2 Polymer Properties and Orientation

18.3 Intrachain Effects

18.4 Interchain Effects

18.5 Conclusions

References

Chapter 19: Nanoscale Shape of Conjugated Polymer Chains Revealed by Single-Molecule Spectroscopy

19.1 Introduction

19.2 The Single-Molecule Approach

19.3 Chain Shape

19.4 Conclusions

References

Chapter 20: Electronic Structure Engineering Through Intramolecular Polar Bonds

20.1 Introduction

20.2 Electrostatic Considerations

20.3 Introducing Energy Levels

20.4 Intrinsic Intramolecular Surface Dipoles

20.5 Implications for Materials and Devices

20.6 Conclusions

References

Part Six: Field-Effect Transistors

Chapter 21: Crystal Structure Performance Relationship in OFETs

21.1 Introduction

21.2 Single-Crystal OFETs

21.3 Crystal Packing Motifs

21.4 Polymorphism

21.5 Summary

References

Chapter 22: Bioactive Supramolecular Architectures in Electronic Sensing Devices

22.1 Introduction

22.2 Supramolecular Architectures for Organic Thin-Film Field-Effect Sensing Transistors

22.3 Bioactive Sensing Layer

22.4 Sensing Devices with Polyelectrolyte Multilayer Architectures

22.5 Electronic Sensing Devices with Phospholipid Layer Architectures

22.6 Conclusions and Perspectives

References

Chapter 23: Field-Effect Devices Based on Organic Semiconductor Heterojunctions

23.1 Introduction

23.2 Field-Effect Devices

23.3 Conclusions

References

Chapter 24: Functional Semiconducting Blends

24.1 Introduction

24.2 Processing Aids

24.3 Mechanically Tough Semiconducting Blends

24.4 Ferroelectric Semiconducting Blends

24.5 Photovoltaic Blends

24.6 Conclusions

References

Part Seven: Solar Cells

Chapter 25: Hybrid Organic–Inorganic Photovoltaic Diodes: Photoaction at the Heterojunction and Charge Collection Through Mesostructured Composites

25.1 Introduction

25.2 Basic Operating Principles of Hybrid Solar Cells

25.3 Photoaction at the Heterojunction: Light Harvesting, Charge Generation, and Recombination