Grafted Biopolymers as Corrosion Inhibitors E-Book
173,99 €
Mehr erfahren.
- Herausgeber: John Wiley & Sons
- Kategorie: Fachliteratur
- Serie: Wiley Series in Corrosion
- Sprache: Englisch
GRAFTED BIOPOLYMERS AS CORROSION INHIBITORS Comprehensive resource explaining the synthesis, characterization, and anticorrosive applications of green and environmentally benign grafted biopolymers and their derivatives Grafted Biopolymers as Corrosion Inhibitors highlight research and technology on sustainable grafted biopolymers as corrosion inhibitors and detail their rapidly emerging features and future research prospects. The many forms of grafted biopolymers and techniques for preventing corrosion are explored in relation to their macromolecular weights, chemical makeup, and distinctive molecular and electronic structures. The book covers state-of-the-art corrosion science and engineering as well as an in-depth, step-by-step exposition of knowledge on numerous corrosion systems and their role in contemporary industry. Each chapter include an introduction, isolation and purification, synthesis methods, worked examples, current applications, and future predictions. Edited and contributed to by well-known researchers, scientists and experts from academia and industry, Grafted Biopolymers as Corrosion Inhibitors includes information on: * Basics of corrosion, economic adverse effects and its mitigation, and past and present developments and future directions of corrosion inhibition * Corrosion inhibitor classification and selection criteria, chemical, electrochemical, and surface characterization, and computational techniques for corrosion monitoring * Sustainable grafted biopolymers, covering synthesis and characterizations, properties and applications, and factors affecting biopolymers grafting * Grafted natural exudates gums, pectin, chitosan, starch, cellulose, alginates, dextrin, and biopolymer composites and nanocomposites as sustainable corrosion inhibitors Delivering the recent advancements in sustainable grafted biopolymer for the anticorrosive applications arena, Grafted Biopolymers as Corrosion Inhibitors is an essential resource for scholars in academia and industry, working corrosion engineers, and materials science, engineering, and chemistry students.
Sie lesen das E-Book in den Legimi-Apps auf:
Seitenzahl: 783
Veröffentlichungsjahr: 2023
Ähnliche
WILEY SERIES IN CORROSION
R. Winston Revie, Series Editor
Corrosion Inspection and Monitoring ⋅ Pierre R. Roberge
Microbiologically Influenced Corrosion ⋅ Brenda J. Little and Jason S. Lee
Corrosion Resistance of Aluminum and Magnesium Alloys: Understanding, Performance, and Testing ⋅ Edward Ghali
Metallurgy and Corrosion Control in Oil and Gas Production ⋅ Robert Heidersbach
Green Corrosion Inhibitors: Theory and Practice ⋅ V. S. Sastri
Heterogeneous Electrode Processes and Localized Corrosion ⋅ Yongjun Tan
Stress Corrosion Cracking of Pipelines ⋅ Y. Frank Cheng
Corrosion Failures: Theory, Case Studies, and Solutions ⋅ K. Elayaperumal and V. S. Raja
Challenges in Corrosion: Costs, Causes, Consequences and Control ⋅ V. S. Sastri
Metallurgy and Corrosion Control in Oil and Gas Production, Second Edition ⋅ Robert Heidersbach
High Temperature Corrosion: Fundamentals and Engineering ⋅ César A. C. Sequeira
Grafted Biopolymers as Corrosion Inhibitors: Safety, Sustainability, and Efficiency ⋅ Jeenat Aslam, Chandrabhan Verma and Ruby Aslam
Grafted Biopolymers as Corrosion Inhibitors
Safety, Sustainability, and Efficiency
Edited by Jeenat Aslam, Chandrabhan Verma, and Ruby Aslam
This edition first published 2023
© 2023 John Wiley & Sons, Inc.
All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, except as permitted by law. Advice on how to obtain permission to reuse material from this title is available at http://www.wiley.com/go/permissions.
The right of Jeenat Aslam, Chandrabhan Verma and Ruby Aslam to be identified as the authors of the editorial material in this work has been asserted in accordance with law.
Registered Office
John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, USA
For details of our global editorial offices, customer services, and more information about Wiley products visit us at www.wiley.com.
Wiley also publishes its books in a variety of electronic formats and by print-on-demand. Some content that appears in standard print versions of this book may not be available in other formats.
Trademarks: Wiley and the Wiley logo are trademarks or registered trademarks of John Wiley & Sons, Inc. and/or its affiliates in the United States and other countries and may not be used without written permission. All other trademarks are the property of their respective owners. John Wiley & Sons, Inc. is not associated with any product or vendor mentioned in this book.
Limit of Liability/Disclaimer of Warranty
In view of ongoing research, equipment modifications, changes in governmental regulations, and the constant flow of information relating to the use of experimental reagents, equipment, and devices, the reader is urged to review and evaluate the information provided in the package insert or instructions for each chemical, piece of equipment, reagent, or device for, among other things, any changes in the instructions or indication of usage and for added warnings and precautions. While the publisher and authors have used their best efforts in preparing this work, they make no representations or warranties with respect to the accuracy or completeness of the contents of this work and specifically disclaim all warranties, including without limitation any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives, written sales materials or promotional statements for this work. The fact that an organization, website, or product is referred to in this work as a citation and/or potential source of further information does not mean that the publisher and authors endorse the information or services the organization, website, or product may provide or recommendations it may make. This work is sold with the understanding that the publisher is not engaged in rendering professional services. The advice and strategies contained herein may not be suitable for your situation. You should consult with a specialist where appropriate. Further, readers should be aware that websites listed in this work may have changed or disappeared between when this work was written and when it is read. Neither the publisher nor authors shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages.
Library of Congress Cataloging-in-Publication Data
Hardback ISBN: 9781119881360; ePub ISBN: 9781119881384; ePDF ISBN: 9781119881377; oBook ISBN: 9781119881391
Cover Image: © Vink Fan/Shutterstock
Cover Design: Wiley
Set in 9.5/12.5pt STIXTwoText by Integra Software Services Pvt. Ltd, Pondicherry, India
Contents
Cover
Series Page
Title Page
Copyright Page
About the Editors
List of Contributors
Preface
Part 1 Economic and Legal Issue of Corrosion
1 Corrosion: Basics, Economic Adverse Effects, and its Mitigation
2 Corrosion Inhibition: Past and Present Developments and Future Directions
3 Biopolymers as Corrosion Inhibitors: Relative Inhibition Potential of Biopolymers and Grafted Biopolymers
4 Biopolymers vs. Grafted Biopolymers: Challenges and Opportunities
Part 2 Overview of Sustainable Grafted Biopolymers
5 Sustainable Grafted Biopolymers: Synthesis and Characterizations
6 Sustainable Grafted Biopolymers: Properties and Applications
7 Factors Affecting Biopolymers Grafting
Part 3 Sustainable Grafted Biopolymers as Corrosion Inhibitors
8 Corrosion Inhibitors: Introduction, Classification and Selection Criteria
9 Methods of Corrosion Measurement: Chemical, Electrochemical, Surface, and Computational
10 Experimental and Computational Methods of Corrosion Assessment: Recent Updates on Concluding Remarks
11 Grafted Natural Gums Used as Sustainable Corrosion Inhibitors
12 Grafted Pectin as Sustainable Corrosion Inhibitors
13 Grafted Chitosan as Sustainable Corrosion Inhibitors
14 Grafted Starch Used as Sustainable Corrosion Inhibitors
15 Grafted Cellulose as Sustainable Corrosion Inhibitors
16 Sodium Alginate: Grafted Alginates as Sustainable Corrosion Inhibitors
17 Grafted Dextrin as a Corrosion Inhibitor
18 Grafted Biopolymer Composites and Nanocomposites as Sustainable Corrosion Inhibitors
19 Industrially Useful Corrosion Inhibitors: Grafted Biopolymers as Ideal Substitutes
Index
End User License Agreement
List of Tables
CHAPTER 03
Table 3.1 Table 3.1 represents...
Table 3.2 Table 3.2 represents...
CHAPTER 06
Table 6.1 Grafted Biopolymers with...
CHAPTER 09
Table 9.1 Different electrochemical method...
CHAPTER 11
Table 11.1 Examples of gums...
CHAPTER 13
Table 13.1 Main characteristics of...
Table 13.2 Main characteristics of...
Table 13.3 Main characteristics of...
CHAPTER 14
Table 14.1 A summary of...
CHAPTER 16
Table 16.1 Biopolymers with antifouling...
Table 16.2 Uses of sodium...
CHAPTER 17
Table 17.1 Shows a few...
CHAPTER 19
Table 19.1 Chitosan and grafted...
Table 19.2 Pectin and grafted...
Table 19.3 Grafted exudate gum...
List of Illustrations
CHAPTER 01
Figure 1.1 An image comparing...
Figure 1.2 The above image...
Figure 1.3 Images of a...
CHAPTER 03
Figure 3.1 Above is a...
Figure 3.2 Steps of the...
Figure 3.3 Above is a...
CHAPTER 04
Figure 4.1 Schematic diagram for...
Figure 4.2 Structure of cellulose...
Figure 4.3 Structure of Amylose...
Figure 4.4 Structure of Amylopectin...
Figure 4.5 Structure of Chitin...
Figure 4.6 Structure of a...
Figure 4.7 Structure of grafting...
CHAPTER 05
Figure 5.1 Preparation methods of...
Figure 5.2 Structures of some...
Figure 5.3 Phosphorylation of chitosan...
Figure 5.4 A Phosphorylation of...
Figure 5.5 Phosphorylation of chitosan...
Figure 5.6 A functionalization of...
Figure 5.7 A diagram of...
Figure 5.8 An image of...
Figure 5.9 A diagram of...
Figure 5.10 A diagram of...
Figure 5.11 A representation of...
Figure 5.12 The rafting of...
Figure 5.13 Grafting of β...
CHAPTER 06
Figure 6.1 The formation of...
Figure 6.2 The different roles...
Figure 6.6 The Synthesis of...
Figure 6.3 The use of...
Figure 6.4 An image of...
Figure 6.5 A Cysteamine modified...
Figure 6.7 The synthesis of...
Figure 6.8 Synthesis of a...
Figure 6.9 Polyacrylamide-grafted copolymer...
CHAPTER 07
Figure 7.1 Tertiary (I) polymer...
Figure 7.2 Structure of the...
Figure 7.3 H-bonded complex...
Figure 7.4 Structure of ethanolamine...
CHAPTER 08
Figure 8.1 Classification of corrosion...
Figure 8.2 Adsorption mechanism of...
Figure 8.3 Schematic representation of...
Figure 8.4 Mechanism of corrosion...
CHAPTER 09
Figure 9.1 Schematic of corrosion...
Figure 9.2 Number of published...
Figure 9.3 OCP measurement of...
Figure 9.4 LPR measurement methods...
Figure 9.5 Potentiodynamic polarization curve...
Figure 9.6 Potentiodymic polarization curve...
Figure 9.7 Potential and current...
Figure 9.8 Nyquist plot with...
Figure 9.9 Bode and phase...
Figure 9.10 Typical Nyquist plots...
Figure 9.11 Types of corrosion...
Figure 9.12 “X-ray...
Figure 9.13 “X-ray...
Figure 9.14 “XPS results...
Figure 9.15 “The high...
Figure 9.16 “XRD patterns...
Figure 9.17 “Surface morphology...
Figure 9.18 “3D and...
Figure 9.19 “The optimized...
Figure 9.20 “Skeletal formulas...
Figure 9.21 “The most...
Figure 9.22 “Bond-strengths...
Figure 9.23 “Side and...
CHAPTER 10
Figure 10.1 Representation of corrosion...
Figure 10.2 Representation of the...
Figure 10.3 Arrhenius plots and...
Figure 10.4 Transition state plots...
Figure 10.5 Langmuir adsorption isotherm...
Figure 10.6 Temkin adsorption isotherm...
Figure 10.7 Freundlich adsorption isotherm...
Figure 10.8 Frumkin adsorption isotherm...
Figure 10.9 Flory-Huggins adsorption...
Figure 10.10 OCP Vs Time...
Figure 10.11 Representation of Randel...
Figure 10.12 Representation of depressed...
Figure 10.13 The representation of...
Figure 10.14 Representation of potentiodynamic...
Figure 10.15 Potentiodynamic polarization curves...
Figure 10.16 SEM images of...
Figure 10.17 AFM image of...
Figure 10.18 EDX image of...
Figure 10.19 XPS spectra of...
Figure 10.20 Frontier orbitals...
Figure 10.22 MDS simulation for...
CHAPTER 11
Figure 11.1 Reaction scheme of...
Figure 11.2 Mechanistic pathway for...
Figure 11.3 Molecular structure of...
Figure 11.4 (a) Synthesis rout...
Figure 11.5 Synthesis rout and...
Figure 11.6 Synthetic route of...
Figure 11.7 Synthetic route for...
Figure 11.8 SEM images of...
CHAPTER 12
Figure 12.1 Diagrammatic representation of...
Figure 12.2 Chemical structure of...
Figure 12.3 Schematic representation for...
Figure 12.4 Alkylation of pectin...
Figure 12.5 Amidation of pectin...
Figure 12.6 Reaction scheme for...
Figure 12.7 Mechanism of graft...
Figure 12.8 Structure of O...
CHAPTER 13
Figure 13.1 Schematic illustrations of...
Figure 13.2 Tafel curves for...
Figure 13.3 Obtained OCP for...
Figure 13.4 Optimized molecular structure...
Figure 13.5 MD simulation results...
Scheme 13.1 Reaction procedure of grafted chitosan with the benzotriazole (BTA).
Figure 13.6 Results in surface...
CHAPTER 14
Figure 14.1 Chemical structures of...
Figure 14.2 Factors responsible for...
Figure 14.3 SEM and EDX...
Figure 14.4 Optimized structures of...
Figure 14.5 Synthetic procedure and...
Figure 14.6 Optimized molecular structures...
Figure 14.7 FTIR plots for...
Figure 14.8 (a) OCP-time...
Figure 14.9 Impedance spectra for...
Figure 14.10 SEM (a, d...
CHAPTER 15
Figure 15.1 A schematic of...
Figure 15.2 A schematic of...
Figure 15.3 A schematic of...
Figure 15.4 The reactions that...
Figure 15.5 A monomeric structure...
Figure 15.6 The inhibition efficiency...
Figure 15.8 Synthesis of AHEC...
Figure 15.9 A schematic of...
Figure 15.10 (a) Polarization and...
Figure 15.11 The scale inhibition...
Figure 15.13 SEM micrographs of...
Figure 15.14 The inhibition efficiency...
Figure 15.15 Schematic depiction of...
CHAPTER 16
Figure 16.1 Production and development...
Figure 16.2 Classification of bio...
Figure 16.3 Characterization techniques for...
Figure 16.4 Biomaterials prepared from...
Figure 16.5 Types of polymer...
CHAPTER 17
Figure 17.1 Types of biopolymers...
Figure 17.2 Methods of grafting...
Figure 17.3 Molecular structure of...
Figure 17.4 Variations of the...
Figure 17.5 SEM images and...
Figure 17.6 CR and η...
Figure 17.7 The synthesis of...
Figure 17.8 Analysis of scale...
CHAPTER 18
Figure 18.1 Mechanism of corrosion...
Figure 18.2 Role of ceramic...
CHAPTER 19
Figure 19.1 Molecular structure of...
Figure 19.2 Types of green...
Figure 19.3 Application and industrial...
Figure 19.4 Classification of biopolymers...
Figure 19.5 Industrial application of...
Figure 19.6 The mechanism of...
Figure 19.7 Structure of dextrin...
Figure 19.8 Structure of carrageenan...
Guide
Cover
Series Page
Title Page
Copyright Page
Table of Contents
About the Editors
List of Contributors
Preface
Begin Reading
Index
End User License Agreement
Pages
i
ii
iii
iv
v
vi
vii
viii
ix
x
xi
xii
xiii
xiv
xv
xvi
xvii
xviii
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
232
233
234
235
236
237
238
239
240
241
242
243
244
245
246
247
248
249
250
251
252
253
254
255
256
257
258
259
260
261
262
263
264
265
266
267
268
269
270
271
272
273
274
275
276
277
278
279
280
281
282
283
284
285
286
287
288
289
290
291
292
293
294
295
296
297
298
299
300
301
302
303
304
305
306
307
308
309
310
311
312
313
314
315
316
317
318
319
320
321
322
323
324
325
326
327
328
329
330
331
332
333
334
335
336
337
338
339
340
341
342
343
344
345
346
347
348
349
350
351
352
353
354
355
356
357
358
359
360
361
362
363
364
365
366
367
368
369
370
371
372
373
374
375
376
377
378
379
380
381
382
383
384
385
386
387
388
389
390
391
392
393
394
395
396
397
398
399
400
401
402
403
404
405
406
407
408
409
410
411
412
413
414
415
416
417
418
419
420
421
422
423
424
425
426
427
428
429
430
431
432
433
434
435
436
437
438
439
440
441
442
443
444
445
446
447
448
449
450
451
452
453
454
455
456
457
458
459
460
461
462
463
464
465
466
467
468
469
470
471
472
473
474
475
476
About the Editors
Jeenat Aslam, Ph.D., is currently working as an Associate Professor at the Department of Chemistry, College of Science, Taibah University, Yanbu, Al-Madina, Saudi Arabia. She earned her Ph.D. degree in Surface Science/Chemistry from the Aligarh Muslim University, Aligarh, India. Materials & corrosion, nanotechnology, and surface chemistry are the primary areas of her research. Dr. Jeenat has published a number of research and review articles in peer-reviewed international journals like ACS, Wiley, Elsevier, Springer, Taylor & Francis, Bentham Science, and others. She has authored over thirty book chapters and edited more than twenty books for the American Chemical Society, Elsevier, Springer, Wiley, De-Gruyter, and Taylor & Francis.
Chandrabhan Verma, Ph.D., works at the Department of Chemical Engineering, Khalifa University of Science and Technology, P.O. Box 127788, Abu Dhabi, United Arab Emirates. He obtained his Ph.D. in Material Science/Chemistry at the Indian Institute of Technology (Banaras Hindu University) Varanasi, India. He is an American Chemical Society (ACS) member and serves as a reviewer and editorial board member for various internationally recognized ACS, RSC, Elsevier, Wiley, and Springer platforms. Dr. Verma is the Associate Editor-in-Chief of the Organic Chemistry Plus Journal. He is the author of several research and review articles published in ACS, Elsevier, RSC, Wiley, Springer, etc. He has a total citation of more than 9065 with an H-index of 53 and an i-10 index of 142. Dr. Verma has edited many books for the ACS, Elsevier, RSC, and Wiley. Dr. Verma received several awards for his academic achievements.
Ruby Aslam, PhD., is currently a Research Associate fellow under CSIR-HRDG, New Delhi in the Department of Applied Chemistry, Aligarh Muslim University, Aligarh, India. She received her M.Sc., M. Phil., and Ph.D. degrees from the same university. Her main areas of interest in research include the development of stimuli-responsive smart coatings for corrosion detection and protection as well as the assessment of environmentally friendly corrosion inhibitors. She has authored/co-authored several research papers in international peer-reviewed journals of wide readership, including critical reviews and book chapters. She has edited many books for American Chemical Society, Elsevier, Springer, Wiley, De-Gruyter and Taylor & Francis.
List of Contributors
Khamdam Akbarov
Faculty of Chemistry, National University of Uzbekistan, Tashkent Uzbekistan
Ekemini D. Akpan
Centre for Materials ScienceCollege of Science, Engineering,and Technology, University of South Africa, Johannesburg, South Africa
Farhat A. Ansari
Faculty of Pharmaceutical ChemistryHygia Institute of PharmaceuticalEducation and Research, Uttar Pradesh, India
J. Arun
Centre for waste management –“International Research Centre”Sathyabama Institute of Science andTechnology, Tamil Nadu, India
Jeenat Aslam
Department of Chemistry, Collegeof Science, Taibah UniversityAl-Madina, Saudi Arabia
Ruby AslamCorrosion Research LaboratoryDepartment of Applied ChemistryAligarh Muslim UniversityUttar Pradesh, India
Humira Assad
Department of ChemistryFaculty of Technology and ScienceLovely Professional UniversityPunjab, India
Rajeshwari Athavale
Department of Chemistry, K.E. T’sV. G. Vaze College (Autonomous) Maharashtra, India
Khasan BerdimuradovFaculty of industrial Viticultureand Food Production TechnologyShahrisabz branch of TashkentInstitute of Chemical TechnologyShahrisabz, Uzbekistan
Elyor Berdimurodov
Faculty of Chemistry, NationalUniversity of Uzbekistan, TashkentUzbekistan
K. Cial
Corrosion Research LaboratoryDepartment of Applied ChemistryAligarh Muslim UniversityUttar Pradesh, India
Lakha V. Chopda
Government Engineering CollegeBhuj (Gujarat), India
Fatima Choudhary
Department of Chemistry, K.E. T’sV. G. Vaze College (Autonomous)Maharashtra, India
Omar Dagdag
Centre for Materials ScienceCollege of Science, Engineeringand TechnologyUniversity of South AfricaJohannesburg, South Africa
Walid Daoudi
Laboratory of Molecular ChemistryMaterials and Environment(LCM2E), Department of ChemistryMultidisciplinary Faculty of NadorUniversity Mohamed I, Nador Morocco
Pragnesh N. Dave
Department of Chemistry, SardarPatel University, Vallabh Vidynagar(Gujarat), India
R. V. Deeksha
Centre for waste management –“International Research Centre”Sathyabama Institute of Science andTechnology, Tamil Nadu, India
Manoj Dhameja
Department of Chemistry, BabasahebBhimrao Ambedkar UniversityUttar Pradesh, India
Eno E. Ebenso
Centre for Materials Science College of Science, Engineeringand Technology, University of SouthAfrica, Johannesburg, South Africa
Abdolreza Farhadian
Department of Polymer & MaterialsChemistry, Faculty of Chemistry and Petroleum Science, Shahid Beheshti University, Tehran, Iran
Department of Petroleum EngineeringKazan Federal University, KazanRussian Federation
Omolola E. Fayemi
Department of Chemistry, Schoolof Chemical and Physical Sciencesand Material Science Innovation& Modelling (MaSIM) ResearchFocus Area, Faculty of Natural and Agricultural Sciences, North-WestUniversity, Mmabatho, South Africa
Luana Barros Furtado
Federal University of Rio de JaneiroSchool of Chemistry, Rio de JaneiroAthos da Silveira Ramos AvenueBrazil
Richika Ganjoo
Department of Chemistry, Facultyof Technology and Science, LovelyProfessional University, Punjab, India
Sailee Gardi
Department of Chemistry, K.E. T’sV. G. Vaze College (Autonomous)Maharashtra, India
Husnu Gerengi
Corrosion Research LaboratoryDepartment of MechanicalEngineering, Duzce UniversityDuzce, Turkey
Maria José O. C. Guimarães
Federal University of Rio de JaneiroSchool of Chemistry, Rio de JaneiroAthos da Silveira Ramos AvenueBrazil
Lei Guo
School of Material and ChemicalEngineering, Tongren UniversityTongren, P. R. China
Preeti Gupta
Department of Chemistry, BabasahebBhimrao Ambedkar University, UttarPradesh, India
Nellaiah Hariharan
Bangalore Biotech Labs PrivateLimited (BiOZEEN), Bangalore, India
Rajesh Haldhar
School of Chemical Engineering,Yeungnam University, GyeongsanRepublic of Korea
Brahim El Ibrahimi
Department of Applied Chemistry,Faculty of Applied Sciences, Ibn ZohrUniversity, Aït Melloul, Morocco
Kundan Jangam
Department of Chemistry, K.E. T’s, V. G. Vaze College (Autonomous)Maharashtra, India
Ali Asghar Javidparvar
School of Metallurgy and MaterialsEngineering, College of Engineering,University of Tehran, Tehran, Iran
Abduvali Kholikov
Faculty of Chemistry, NationalUniversity of Uzbekistan, TashkentUzbekistan
Seong-Cheol Kim
School of Chemical EngineeringYeungnam University, GyeongsanRepublic of Korea
Ashish Kumar
Department of Chemistry, Facultyof Technology and Science, LovelyProfessional University, Punjab, India
NCE, Bihar Engineering UniversityDepartment of Scienceand Technology, Government of BiharIndia
Hariom Kumar
Department of Chemistry, BabasahebBhimrao Ambedkar UniversityUttar Pradesh, India
Han-Seung Lee
Department of ArchitecturalEngineering, Hanyang University-ERICA, Gyeonggi-do, Republic ofKorea
Hassane Lgaz
Innovative Durable Building andInfrastructure Research CenterCenter for Creative ConvergenceEducation
Hanyang University ERICAGyeonggi-do, Korea
Hui-Jing Li
Weihai Marine Organism & MedicalTechnology Research InstituteHarbin Institute of TechnologyWeihai, P. R. China
Sheerin Masroor
Department of Chemistry, A.N.College, Patliputra UniversityBihar, India
M. Mobin
Corrosion Research LaboratoryDepartment of Applied ChemistryAligarh Muslim UniversityUttar Pradesh, India
Shalini Mohan
Department of BiotechnologyKalasalingam Academy of Researchand Education, Tamil Nadu, India
Paresh More
Department of Chemistry, K.E. T’sV. G. Vaze College (Autonomous)Maharashtra, India
N. Mujafarkani
PG and Research Department ofChemistry, Jamal Mohamed College(Autonomous), TiruchirappalliTamil Nadu, India
Lakshmanan Muthulakshmi
Department of BiotechnologyKalasalingam Academy of Researchand Education, Tamil Nadu, India
Rafaela C. Nascimento
LAQV-REQUIMTE, Instituto deInvestigação e Formação AvançadaUniversidade de Évora, Évora, ColégioLuís António Verney, Portugal
Lukman O. Olasunkanmi
Department of Chemistry, Faculty ofScience, Obafemi Awolowo UniversityIle Ife, Nigeria
Department of Chemical ScienceUniversity of JohannesburgJohannesburg, South Africa
Tae Joon Park
Department of Robotics EngineeringHanyang University, Gyeonggi-doKorea
M. Parveen
Corrosion Research Laboratory Department of Applied ChemistryAligarh Muslim UniversityUttar Pradesh, India
Dwarika Prasad
Department of ChemistryShri Guru Ram Rai UniversityDehradun, India
P. Priyadharsini
Centre for waste management –“International Research Centre”Sathyabama Institute of Science andTechnology, Tamil Nadu, India
Taiwo W. Quadri
Centre for Material Science, College ofScience, Engineering and TechnologyUniversity of South AfricaJohannesburg, South Africa
Syed Ali Abdur Rahman
Department of BiotechnologySathyabama Institute of Science andTechnology, Tamil Nadu, India
Mohamed Rbaa
Laboratory of Organic ChemistryCatalysis and EnvironmentFaculty of Sciences, Ibn TofailUniversity, Kenitra, Morocco
Marziya Rizvi
Department of ChemistryBabasaheb Bhimrao AmbedkarUniversity, Uttar Pradesh, India
Vandana Saraswat
Department of ChemistryUniversity Institute of SciencesChandigarh UniversityMohali, India
Tarun K. Sarkar
Department of Chemistry, IFTMUniversity, MoradabadUttar Pradesh, India
Ali Reza Shahmoradi
Department of Chemical EngineeringShahreza Branch, Islamic AzadUniversity, Shahreza, Iran
Hariom K. Sharma
Engineering DepartmentUniversity of Technology and AppliedSciences (UTAS)Dhofar, Sultanate of Oman
Praveen Kumar Sharma
Department of Chemistry, Facultyof Technology and Science, LovelyProfessional University, Punjab, India
Rahul Singh
Department of Chemistry, Shri GuruRam Rai University, Dehradun, India
Karthick Subbiah
Department of Architectural Engineering, Hanyang University-ERICA, Gyeonggi-doRepublic of Korea
Nilufar Tursunova
Faculty of Chemistry, NationalUniversity of Uzbekistan Tashkent, Uzbekistan
Dakeshwar Kumar Verma
Department of ChemistryGovernment Digvijay AutonomousPostgraduate CollegeChhattisgarh, India
Dan-Yang Wang
Weihai Marine Organism & MedicalTechnology Research InstituteHarbin Institute of TechnologyWeihai, P. R. China
Yan-Chao Wu
Weihai Marine Organism & MedicalTechnology Research InstituteHarbin Institute of TechnologyWeihai, P. R. China
Mahendra Yadav
Indian Institute of technology (Indian School of Mines), Dhanbad, India
Ramesh Yamgar
Department of Chemistry C. S.’s Patkar-Varde CollegeMaharashtra, India
Preface
Corrosion of metal is a destructive phenomenon that has a significant impact on the anticipated lifetime and use of materials made of metals. Use of corrosion inhibitors is thought to be the most efficient and cost-effective method to block metals against corrosion, especially in acidic conditions, to resolve this type of issue. Studies on “sustainable(green)” corrosion inhibitors, which don’t have the negative health effects associated with the organic compounds employed in the past, have been conducted over the past ten years.
In recent times, polymeric biomaterials have received the most important attention in corrosion science. Biomaterials such as natural biopolymers (polysaccharides) and their derivatives are attractive due their affordability, intrinsic non-toxicity, biodegradability, and availability of numerous adsorption sites. These unexpected benefits have led to widespread usage of biopolymers (polysaccharides) and their derivatives for medication delivery, corrosion inhibitors, coating materials, and the removal of hazardous chemicals through adsorption. Though there are various reports on natural biopolymers and their derivatives as corrosion inhibitors. For instance, gums from natural exudates, chitosan, cellulose derivatives, starch and its derivatives, pectin, carrageenan, and alginate. However in order to prevent valuable metals from being damaged by acid solutions, it is still essential to design efficient corrosion inhibitors. Biopolymers (polysaccharides) have been generally studied as corrosion inhibitors because of the presence of a variety of polar functional groups for example OH, COOH, and NH2 in their arrangement and capability to complex with metals on surfaces. In corrosion inhibition, biopolymers (polysaccharides) characterize a set of chemically stable, biodegradable, and environment-friendly macromolecules with distinctive inhibitory strengths and binding to metal surfaces.
The present book is a collection of major advancements in the field of polymer for the design and testing of the corrosion inhibition effect of sustainable grafted biopolymer corrosion inhibitors. This book explains the synthesis, characterization, and anticorrosive application of some green and environmentally friendly sustainable grafted biopolymers and their derivatives for inhibition of metal corrosion. It has also been explored how their distinct molecular and electrical structures, chemical makeup, and macromolecular weights all have a role in the sorts and ways of protection they offer.
The book is written for scholars in academia and industry, working corrosion engineers and materials science students, and applied and engineering chemistry.
The book is structured into three parts, each of which contains several chapters, in order to condense the detailed explanation of anticorrosive applications of sustainable grafted biopolymer and to offer the reader a sensible and expressive design of the issue.
PART 1 explores the economic and legal issues of corrosion. Topics covered in chapters 1 to 4 are corrosion: basics, economic adverse effects, and its mitigation, corrosion inhibition: past and present developments and future directions, biopolymers as corrosion inhibitors: relative inhibition potential of biopolymers and grafted biopolymers and biopolymers vs. grafted biopolymers: challenges and opportunities
PART 2 discusses an overview of sustainable grafted biopolymers. Topics covered in chapters 5 to 7 are sustainable grafted biopolymers: synthesis and characterizations, sustainable grafted biopolymers: properties and applications, and factors affecting biopolymers grafting.
PART 3 debates sustainable grafted biopolymers as corrosion inhibitors. Topics covered in chapters 8 to 19 are corrosion inhibitors: introduction, classification and selection criteria, chemical, electrochemical, surface characterization, computational techniques for corrosion monitoring, methods of corrosion measurements: chemical, electrochemical, surface and computational, grafted natural exudates gums used as sustainable corrosion inhibitors, grafted pectin as sustainable corrosion inhibitors, grafted chitosan as sustainable corrosion inhibitors, grafted starch used as sustainable corrosion inhibitors, grafted cellulose as sustainable corrosion inhibitors, grafted alginates as sustainable corrosion inhibitors, grafted dextrin as sustainable corrosion inhibitors, grafted biopolymer composites and nanocomposites as sustainable corrosion inhibitors, industrially useful corrosion inhibitors: grafted biopolymers as ideal substitutes.
The goal of this book is to provide the most recent developments in grafted biopolymers for anticorrosive applications. This book is written for a highly diverse group of people who work in chemical engineering, advanced materials research, and other related subjects. Libraries in academic and professional settings, independent research organizations, government agencies, and scientists will all find this book to be an invaluable source of reference information. The chapters’ authors and book editors are renowned academic and professional researchers, scientists, and subject matter specialists.
On behalf of John Wiley & Sons, Inc., we thank all contributors for their exceptional and whole-hearted contribution. Invaluable thanks to Mr. Michael Leventhal (Acquisitions Editor), Miss Kelly Labrum (Associate Managing Editor), Miss Elizabeth (Managing Editor), and the Editorial Team at John Wiley & Sons, Inc. for their wholehearted support and help during this project. In the end, all appreciation to John Wiley & Sons, Inc. for publishing the book.
Jeenat Aslam, Chandrabhan Verma & Ruby Aslam
(Editors)
