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An essential companion for catalysis researchers and professionals studying economically viable and eco-friendly catalytic strategies for energy conversion In the two-volume Heterogeneous Nanocatalysis for Energy and Environmental Sustainability, a team of distinguished researchers deliver a comprehensive discussion of fundamental concepts in, and practical applications of, heterogeneous nanocatalysis for alternative energy production, biomass conversion, solar energy, green fuels, H2 production, fuel cells, electrochemical energy conversion processes, CO2 conversion, clean water, and environmental protection. The volumes cover the design and catalytic performance of various nanocatalysts, including nanosized metals and metal oxides, supported metal nanoparticles, inverse oxide-metal nanocatalysts, core-shell nanocatalysts, nanoporous zeolites, nanocarbon composites, and metal oxides in confined spaces. Each chapter contains a critical discussion of the opportunities and challenges posed by the use of nanosized catalysts for practical applications. Volume 1 - Energy Applications focuses on the conversion of renewable energy (biomass/solar) into green fuels and chemicals, ammonia synthesis, clean hydrogen production, and electrochemical energy conversion processes using a variety of nanosized catalysts. It also offers: * A thorough introduction to heterogeneous catalysis and nanocatalysis, as well as a discussion of catalytic active sites at nano-scale range * Comprehensive explorations of the methods for control and activation of nanosized catalysts * Practical discussions of C3N4-based nanohybrid catalysts for solar hydrogen production via water splitting * Nanosized catalysts in visible light photocatalysis for sustainable organic synthesis * Applications of MXenes in electrocatalysis Perfect for researchers, postgraduate students, chemists, and engineers interested in heterogeneous catalysis and nanocatalysis, Heterogeneous Nanocatalysis for Energy and Environmental Sustainability will also earn a place in the libraries of professionals working in alternative energy production, biomass conversion, solar energy, green fuels, H2 production, fuel cells, electrochemical energy conversion processes, CO2 conversion, clean water, and environmental protection. Explore the environmental applications of heterogeneous nanocatalysis in the field of alternative energy production In Volume 2: Environmental Applications of Heterogeneous Nanocatalysis for Energy and Environmental Sustainability, a team of distinguished researchers discusses the foundational concepts and practical applications of heterogeneous nanocatalysis for alternative energy production. Volume 2 focuses on the purification of auto exhaust pollutants and volatile organic compounds, as well as CO2 conversion and wastewater treatment over a range of nano-sized catalysts.

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Heterogeneous Nanocatalysis for Energy and Environmental Sustainability

Volume 2 ‐ Environmental Applications

Edited by

Putla Sudarsanam

Department of Chemistry

Indian Institute of Technology Hyderabad

Kandi, Telangana, India

Yusuke Yamauchi

Australian Institute for Bioengineering and Nanotechnology (AIBN)

School of Chemical Engineering

The University of Queensland

Brisbane, Queensland, Australia

Pankaj Bharali

Department of Chemical Sciences

Tezpur University

Nappam, Assam, India

This edition first published 2023© 2023 John Wiley & Sons Ltd

All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, except as permitted by law. Advice on how to obtain permission to reuse material from this title is available at http://www.wiley.com/go/permissions.

The right of Putla Sudarsanam, Yusuke Yamauchi, and Pankaj Bharali to be identified as the authors of the editorial material in this work has been asserted in accordance with law.

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Library of Congress Cataloging‐in‐Publication DataNames: Sudarsanam, Putla, editor. | Yamauchi, Yusuke, editor. | Bharali, Pankaj, editor.Title: Heterogeneous nanocatalysis for energy and environmental sustainability / Putla Sudarsanam, Yusuke Yamauchi, Pankaj Bharali. Description: First edition. | Chichester, West Sussex, UK ; Hoboken, NJ, USA : Wiley, 2023. | Includes bibliographical references and index. | Contents: volume 1. Energy applications – volume 2. Environmental applications.Identifiers: LCCN 2022032470 (print) | LCCN 2022032471 (ebook) | ISBN 9781119771999 (cloth ; volume 1) | ISBN 9781119772026 (cloth ; volume 2) | ISBN 9781119772002 (adobe pdf ; volume 1) | ISBN 9781119772019 (epub ; volume 1) | ISBN 9781119772033 (adobe pdf ; volume 2) | ISBN 9781119772040 (epub ; volume 2)Subjects: LCSH: Catalysts. | Heterogeneous catalysis. |Nanochemistry–Industrial applications. | Green chemistry. | Electric power production from chemical action. | Biomass energy. | Environmental protection. | Pollution prevention.Classification: LCC TP159.C3 H48 2023 (print) | LCC TP159.C3 (ebook) |DDC 660/.2995–dc23/eng/20220720LC record available at https://lccn.loc.gov/2022032470LC ebook record available at https://lccn.loc.gov/2022032471

Cover Design: WileyCover Images: © ejaugsburg/Pixabay, Ractapopulous/Pixabay

Preface

Heterogeneous Nanocatalysis for Energy and Environmental Sustainability, Volume 2: Environmental Applications

Heterogeneous catalysis plays a key role in tackling environmental pollution and related areas. Some of the important applications of heterogeneous catalysts in environmental catalysis are CO2 reduction into valuable fuels and chemicals, valorization of greenhouse gases, water purification, degradation of toxic pollutants, and VOC oxidation. Compared with bulk solid catalysts, nanosized catalysts can exhibit superior catalytic efficiency because of their size‐dependent catalytic properties, such as higher BET surface area, more active sites and defects, and improved acid‐base and redox nature. Besides, the shape of the catalyst’s particles can control the crystal facets, edge and corner atoms, and low‐coordinated metal sites, which are believed to have abundant catalytic acid and redox sites. Consequently, tremendous efforts have been made in controlling the particle size and shape of the catalysts to develop advanced nanosized catalysts with tunable catalytic properties for environmental catalysis.

The book introduces the concepts and applications of a wide range of novel heterogeneous nanosized catalytic materials for various environmental applications. It covers various emerging topics including VOC oxidation using supported Pt and bimetallic Pt—Cu nanoparticles (Chapter 14) and water purification using nanocarbon composites and Fenton‐like catalysts in Chapters 15 and 16, respectively. Chapters 17 and 18 discuss the role of photocatalysis in the degradation of toxic pollutants using various nanostructured catalysts. The role of photo‐, electro‐, and thermochemical routes for CO2 reduction to various value‐added chemicals, fuels, and materials are elucidated in Chapters 19–26. Especially, the significance of metal‐organic frameworks, Cu‐based catalysts, and SnO2 clusters in CO2 valorization are critically discussed. The application of in situ characterization techniques to understand the mechanisms and active intermediates during catalytic CO2 reduction reactions is reported in Chapter 22. The perspectives and the challenges associated with the practical applications of nanosized catalysts for environmental sustainability are critically discussed in this book.

The book covers various aspects of nanocatalysis and nanosized catalysts, including synthesis, characterization, and their role in achieving environmental sustainability. Thus, the book will be of great interest to researchers/students and industrial chemists familiar with the fields of heterogeneous catalysis and nanocatalysis. We hope that catalysis researchers will find this book as a key reference for the fundamental understanding of surface science, rational catalyst design, and the applications of various nanocatalysts for environmental applications. We would like to thank the authors for accepting the invitation and submitting the chapters to this book. We also thank the production team at Wiley for their invaluable assistance and support.

Dr. Putla SudarsanamDepartment of ChemistryIndian Institute of Technology HyderabadKandi, Telangana, India

Professor Yusuke YamauchiAustralian Institute for Bioengineering and Nanotechnology (AIBN)School of Chemical EngineeringThe University of QueenslandBrisbane, Queensland, Australia

Dr. Pankaj BharaliDepartment of Chemical SciencesTezpur UniversityNapaam, Assam, India

List of Contributors

Aderemi Timothy AdeleyeCAS Key Laboratory of Science and Technology on Applied CatalysisDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian, China

and

University of Chinese Academy of SciencesBeijing, China

Mehrdad AsgariInstitute of Chemical Sciences and EngineeringÉcole Polytechnique Fédérale de Lausanne (EPFL)EPFL‐ISIC‐ValaisSion, Switzerland

and

Department of Chemical Engineering and BiotechnologyUniversity of CambridgeCambridge, UK

Jonathan O. BabalolaDepartment of ChemistryUniversity of IbadanIbadan, Nigeria

Satyajit Dey BaruahDepartment of Chemical SciencesTezpur UniversityTezpur, Assam, India

Purashri BasyachMaterials Science & Technology DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

and

Academy of Scientific and Innovative ResearchGhaziabad, Uttar Pradesh, India

Nishant BiswakarmaDepartment of Chemical SciencesTezpur UniversityTezpur, Assam, India

Ankur BordoloiCSIR – Indian Institute of PetroleumDehradun, Uttarakhand, India

and

Academy of Scientific and Innovative Research (AcSIR)Ghaziabad, Uttar Pradesh, India

Rajashree BortamulyDepartment of Applied Sciences (Chemical Science Division)Gauhati UniversityGuwahati, Assam, India

Sukanya BorthakurMaterials Science & Technology DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

and

Academy of Scientific and Innovative ResearchGhaziabad, Uttar Pradesh, India

Purna K. BoruahAdvanced Materials GroupMaterials Science DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

Pubali ChetiaMaterials Science & Technology DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

and

Academy of Scientific and Innovative ResearchGhaziabad, Uttar Pradesh, India

Francisco G. CirujanoInstituto de Ciencia Molecular (ICMol)Universitat de ValènciaPaterna, Valencia, Spain

Manash R. DasAdvanced Materials GroupMaterials Science DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

and

Academy of Scientific and Innovative Research (AcSIR)Ghaziabad, India

Punamshree DasAdvanced Materials GroupMaterials Science DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

and

Academy of Scientific and Innovative Research (AcSIR)Ghaziabad, India

Ernest Pahuyo DelmoDepartment of Chemical and Biological EngineeringThe Hong Kong University of Science and TechnologyHong Kong, China

Ajanta DekaDepartment of PhysicsGirijananda Chowdhury Institute of Management and TechnologyGuwahati, Assam, India

Ramesh Ch. DekaDepartment of Chemical SciencesTezpur UniversityTezpur, Assam, India

Dikshita DowerahDepartment of Chemical SciencesTezpur UniversityTezpur, Assam, India

Xu DuNational Bioenergy CenterNational Renewable Energy Laboratory (NREL)Golden, CO, USA

Rituparna DuarahAdvanced Materials Group, Materials Science DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

and

CRANN/School of ChemistryTrinity College DublinThe University of DublinCollege Green, Dublin, Ireland

Jyoti GahtoriCSIR – Indian Institute of PetroleumDehradun, Uttarakhand, India

and

Academy of Scientific and Innovative Research (AcSIR)Ghaziabad, Uttar Pradesh, India

Roohangiz Shivaee‐GarizSchool of Chemical EngineeringCollege of EngineeringUniversity of TehranTehran, Iran

Aniruddha GogoiDepartment of ChemistryIIT GuwahatiGuwahati, Assam, India

Parikshit GogoiDepartment of ChemistryNowgong CollegeNagaon, Assam, India

Kingsley I. JohnLab of Department of Pure and Applied ChemistryCollege of Natural SciencesVeritas University AbujaAbuja, Nigeria

Lisamoni KalitaMaterials Science & Technology DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

and

Academy of Scientific and Innovative ResearchGhaziabad, Uttar Pradesh, India

Yuri KalvachevInstitute of CatalysisBulgarian Academy of SciencesSofia, Bulgaria

Trishanku KashyapDepartment of Applied Sciences (Chemical Science Division)Gauhati UniversityGuwahati, Assam, India

Rishu KatwalDepartment of Chemistry and BiochemistryCSKHPKVPalampur, Himachal Pradesh, India

Hristo KolevInstitute of CatalysisBulgarian Academy of SciencesSofia, Bulgaria

Tiehuai LiDepartment of Chemical and Biological EngineeringThe Hong Kong University of Science and TechnologyHong Kong, China

Xinliang LiuCollege of Light Industry and Food EngineeringGuangxi UniversityNanning, P. R. China

Nuria MartínInstituto de Ciencia Molecular (ICMol)Universitat de ValènciaPaterna, Valencia, Spain

Madhukar NavgireDepartment of ChemistryJijamata College of Science and ArtsBhende, Maharashtra, India

Anton NaydenovInstitute of General and Inorganic ChemistryBulgarian Academy of SciencesSofia, Bulgaria

Martins O. OmorogieEnvironmental and Chemical Processes Research LaboratoryDepartment of Chemical SciencesRedeemer’s UniversityEde, Nigeria

and

Centre for Chemical and Biochemical ResearchDepartment of Chemical SciencesRedeemer’s UniversityEde, Nigeria

and

Africa Centre of Excellence for Water and Environment Research (ACEWATER)Redeemer’s UniversityEde, Nigeria

Deepak PathaniaDepartment of Environmental SciencesCentral University of JammuRahya‐SuchaniBagla, Samba, Jammu and Kashmir, India

and

Department of ChemistrySardhar Vallabhbhai Patel Cluster UniversityMandi, Himachal Pradesh, India

Petya PetrovaInstitute of CatalysisBulgarian Academy of SciencesSofia, Bulgaria

Fahimeh Hooriabad SaboorDepartment of Chemical EngineeringFaculty of EngineeringUniversity of Mohaghegh ArdabiliArdabil, Iran

Lakshi SaikiaMaterials Science & Technology DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

and

Academy of Scientific and Innovative ResearchGhaziabad, Uttar Pradesh, India

Pranjal SaikiaDepartment of Applied Sciences (Chemical Science Division)Gauhati UniversityGuwahati, Assam, India

Plaban J. SarmaDepartment of Chemical SciencesTezpur UniversityTezpur, Assam, India

Minhua ShaoDepartment of Chemical and Biological EngineeringThe Hong Kong University of Science and TechnologyHong Kong, China

Kank Chandra SharmaDepartment of Instrumentation & USICGauhati UniversityGuwahati, Assam, India

Vivek Kumar ShrivastawCSIR – Indian Institute of PetroleumDehradun, Uttarakhand, India

and

Academy of Scientific and Innovative Research (AcSIR)Ghaziabad, Uttar Pradesh, India

Abesa SolomonChemistry DepartmentFederal University of Agriculture MakurdiNigeria

Karanika SonowalMaterials Science & Technology DivisionCSIR‐North East Institute of Science and TechnologyJorhat, Assam, India

and

Academy of Scientific and Innovative ResearchGhaziabad, Uttar Pradesh, India

Xun SunKey Laboratory of High Efficiency and Clean Mechanical ManufactureMinistry of EducationSchool of Mechanical EngineeringShandong UniversityJinan, China

and

National Demonstration Center for Experimental Mechanical Engineering EducationShandong UniversityJinan, China

Totka TodorovaInstitute of CatalysisBulgarian Academy of SciencesSofia, Bulgaria

Sahar VahdatifarCatalysis and Nanostructured Materials Research LaboratorySchool of Chemical EngineeringCollege of EngineeringUniversity of TehranTehran, Iran

Ralitsa VelinovaInstitute of General and Inorganic ChemistryBulgarian Academy of SciencesSofia, Bulgaria

Xingtao XuInternational Center for Materials Nanoarchitectonics (WPI‐MANA)National Institute for Materials ScienceIbaraki, Japan

Xiaoxu XuanKey Laboratory of High Efficiency and Clean Mechanical ManufactureMinistry of EducationSchool of Mechanical EngineeringShandong UniversityJinan, China

and

National Demonstration Center for Experimental Mechanical Engineering EducationShandong UniversityJinan, China

Meng ZhangThe College of Optical Science and EngineeringZhejiang UniversityHangzhou, China

Shangqian ZhuDepartment of Chemical and Biological EngineeringThe Hong Kong University of Science and TechnologyHong Kong, China