Table of Contents
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Preface
List of Contributors
Nanocomposites: Introduction, Structure, Properties and Preparation Methods
Abstract
INTRODUCTION
STRUCTURE OF NANOCOMPOSITES
PROPERTIES OF NANOCOMPOSITES
CLASSIFICATION OF NANOCOMPOSITES
Polymer Matrix Nanocomposites
Ceramic Matrix Nanocomposites
Metal Matrix Nanocomposites
PREPARATION METHODS
Sol-Gel Method
Electrospinning Method
In Situ Polymerization Method
Melt Intercalation Method
ADVANTAGES OF NANOCOMPOSITES
APPLICATIONS OF NANOCOMPOSITES
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Nanocomposites: A Boon To Material Sciences
Abstract
INTRODUCTION
CLASSIFICATION
Binary Nanocomposite
Ternary Nanocomposite
Quaternary Nanocomposites
COMPUTATIONAL STUDIES ON NANOCOMPOSITES
METAL ORGANIC FRAMEWORK-BASED NANOCOMPOSITES
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Bimetallic-Carbon Based Composites for Electrochemical Sensors
Abstract
INTRODUCTION
STRUCTURE AND PROPERTIES OF BIMETALLIC NPs AND CARBON NANOMATERIALS
BIMETALLIC-2D GRAPHENE-BASED COMPOSITE FOR ELECTROCHEMICAL SENSORS
BIMETALLIC-CNT BASED COMPOSITE FOR ELECTROCHEMICAL SENSORS
BIMETALLIC/CARBON QDS BASED COMPOSITES FOR ELECTROCHEMICAL SENSORS
BIMETALLIC/G-C3N4 BASED COMPOSITE FOR ELECTROCHEMICAL SENSORS
CONCLUDING REMARKS AND CHALLENGES
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Two-dimensional Graphene-based Nanocomposites for Electrochemical Sensor
Abstract
INTRODUCTION
ELECTROCHEMICAL SENSING OF VARIOUS ANALYTES USING GRAPHENE BASED NANOCOMPOSITES
ELECTROCHEMICAL SENSING OF GLUCOSE AND HYDROGEN PEROXIDE USING GRAPHENE-BASED NANOCOMPOSITES
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Conducting Polymer Based Nanocomposites for Sensing
Abstract
INTRODUCTION
CONDUCTING POLYMERS - AN INTRODUCTION
CLASSIFICATIONS OF CONDUCTING POLYMERS
CONDUCTING POLYMERS; SYNTHESIS, STRUCTURE, PROPERTIES AND APPLICATIONS
CONDUCTING POLYMER NANOCOMPOSITES
CONDUCTIVE POLYMERS NANOCOMPOSITES FOR SENSING APPLICATIONS
Electrochemical Biosensors
Chemi-resistive Gas and Vapor Sensors
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Nanostructured Molecularly Imprinted Polymers in Electrochemical Sensing
Abstract
INTRODUCTION
NANOSTRUCTURED MOLECULARLY IMPRINTED POLYMER (MIP)
MULTI-WALLED CARBON NANOTUBE-BASED MIP
MWCNT-MIP COMPOSITES IN ELECTROCHEMICAL SENSING
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Multi-walled Carbon Nanotubes Based Molecular Imprinted Polymers for Sensing
Abstract
INTRODUCTION
FACTORS AFFECTING THE IMPRINTING PROCESS
Template
Functional Monomer
Crosslinker
Initiator
Porogen/Solvent
Temperature
NANOMATERIALS IN MOLECULAR IMPRINTING
MULTI-WALLED CARBON NANOTUBE BASED MOLECULAR IMPRINTED POLYMERS
SENSING APPLICATIONS OF MULTI-WALLED CARBON NANOTUBE-BASED MOLECULAR IMPRINTED POLYMERS
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Molecularly Imprinted Polymer (MIP) Nanocomposites–based Sensors
Abstract
INTRODUCTION
DEVELOPMENTS IN MOLECULAR IMPRINTING TECHNOLOGY
MIP SENSORS BASED ON METAL NANOCOMPOSITE/CARBON NANOTUBES
MIP SENSORS BASED ON GRAPHENE NANOCOMPOSITE
MIP SENSORS BASED ON CHITOSAN NANOPARTICLE/ NANOCOMPOSITE
MIP SENSOR BASED ON CHITOSAN NANOPARTICLE-GRAPHENE NANOCOMPOSITE
MIP SENSOR BASED ON STARCH NANOPARTICLE/ NANOCOMPOSITE
PERSPECTIVE
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Advancement in Nanocomposites for Explosive Sensing
Abstract
INTRODUCTION
EXPLOSIVES
π-ELECTRON RICH LUMINESCENT POLYMERIC NANOCOMPOSITES
CdSe QUANTUM DOTS CAPPED PAMAM DENDRIMER NANOCOMPOSITES
SAMPLE COLLECTION AND PRE-CONCENTRATION
SIGNAL TRANSDUCTION USING NANOSENSORS
RECEPTOR-BASED TRACE EXPLOSIVE DETECTION
ELECTRONIC NOSE APPROACH
NANOWIRE PLATFORM
NANOMECHANICAL SENSOR PLATFORM
RECEPTOR-FREE TRACE EXPLOSIVE DETECTION
COMBINED PLATFORMS
CHALLENGES IN MOVING TOWARDS PRACTICAL APPLICATION
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICTS OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Nanocomposite Materials Interface for Heavy Metal Ions Detection
Abstract
INTRODUCTION
IMPORTANCE OF CHEMICAL MODIFICATION
TYPES OF ELECTRODES
Glassy Carbon Electrode (GCE)
Carbon Paste Electrode (CPE)
Screen-printed Electrodes (SPEs)
Pencil Graphite Electrodes (PGEs)
Basal and Edge Plane Pyrolytic Graphite Electrodes
TOXIC METAL IONS, THEIR DISTRIBUTION, AND HEALTH HAZARDS
Lead
Cadmium
Mercury (Hg)
Copper
THRESHOLD LIMIT VALUES (TLV) OF TOXIC METAL IONS IN DRINKING WATER
ELECTROCHEMICAL SENSING OF HEAVY METAL IONS
NANOCOMPOSITE BASED ELECTRODES FOR HEAVY METAL ION SENSOR
CONCLUSION
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Nanocomposites as Electrochemical Sensing Platforms for Glucose Detection
Abstract
INTRODUCTION
NANOCOMPOSITES FOR ENZYMATIC GLUCOSE SENSORS
NANOCOMPOSITES FOR NON-ENZYMATIC GLUCOSE SENSORS
Metal/Metal Oxide Based Nanocomposites as Glucose Sensors
Carbon Nanocomposites in Glucose Sensing
Polymer Nanocomposites for Glucose Detection
MOF Based Composites
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Tailored Nanocomposites for Hydrazine Electrochemical Sensors
Abstract
INTRODUCTION
COPPER BASED NANOCOMPOSITES FOR HYDRAZINE SENSOR
ZINC BASED NANOCOMPOSITES FOR HYDRAZINE SENSOR
NOBLE METALS BASED NANOCOMPOSITES FOR HYDRAZINE SENSOR
OTHER NANOCOMPOSITES FOR HYDRAZINE SENSOR
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Optical Detection Of Toxic Cations And Anions By Nanocomposite Materials
Abstract
INTRODUCTION
DETECTION OF TOXIC HEAVY METALS
Mercury Detection
Chromium Detection
Silver Detection
NANOCOMPOSITES FOR ANION SENSORS
Fluoride Ion Detection
Sulfide Detection
Cyanide Detection
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Nanocomposites for Humidity Sensor: An Overview
Abstract
INTRODUCTION
OVERVIEW ON NANOCOMPOSITE BASED HUMIDITY SENSORS
Absolute Humidity
Relative Humidity
Dew Point
NANOCOMPOSITES FOR HUMIDITY SENSING
Ceramic Nanocomposite
Carbon Nanocomposite
Polymer Nanocomposite
CONCLUDING REMARKS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Current and Future Developments in Nanomaterials and Carbon Nanotubes
(Volume 2)
(Nanocomposite Materials for Sensors)
Edited by
Dr. Manorama Singh
Department of Chemistry,
Guru Ghasidas Vishwavidyalaya,
Bilaspur, CG-495009
India
Dr. Vijai K Rai
Department of Chemistry,
Guru Ghasidas Vishwavidyalaya,
Bilaspur, CG-495009
India
&
Dr. Ankita Rai
School of Physical Sciences,
Jawaharlal Nehru University,
New Delhi-110067
India
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Preface
Manorama Singh
Department of Chemistry
Guru Ghasidas Vishwavidyalaya
Bilaspur, Chhattisgarh
INDIA
Nanocomposites are rapidly emerging as novel materials for sensor technology; therefore, the scientific community has recently focused on the advancement in the development of innovative methods and materials relied upon efficient composites. The implementation of nanocomposite materials for the development of specific and sensitive sensing platforms receives good attention. This book focuses on the reviews of important reported literature for new approaches of nanocomposite material preparation and their applications in the development of physical, chemical, electrochemical, biological, and optical sensors, etc. These nanomaterials have been extensively used widely (to amplify the signal) in the detection of heavy metal ions, vital signs (i.e., glucose, etc.), explosives, hydrazine, humidity, etc.
This book focuses on representing some state-of-the-art review chapters based on reported works in the last few decades, outlining the synthesis, role, and progress of nanocomposite materials in fabricating flexible and multifunctional sensing platforms in sensor technologies. The book is intended to prepare a highly compiled knowledge for designing novel nanocomposite materials to be used as sensing platforms in sensor technologies. A broad range of readers such as graduates and post-graduates, Ph.D. scholars, faculty members, professionals working in the area of material science, the healthcare industry, biological sciences, medical sciences, environmental science will be benefitted from the topics preferred in the proposed book.
Manorama Singh
Department of Chemistry
Guru Ghasidas Vishwavidyalaya
Bilaspur, CG-495009
IndiaVijai K Rai
Department of Chemistry
Guru Ghasidas Vishwavidyalaya
Bilaspur, CG-495009
India
&Ankita Rai
School of Physical Sciences
Jawaharlal Nehru University
List of Contributors
A RajapriyaDepartment of Nanoscience and Technology, Bharathiar University, Coimbatore, Tamilnadu, IndiaA RebekahDepartment of Nanoscience and Technology, Bharathiar University, Coimbatore, Tamilnadu, IndiaAnu Rose ChackoMahatma Gandhi University, Kottayam, Kerala 686560, IndiaArchana AravindNSS Hindu College, Changanashery, Kerala, IndiaAshoka SDayananda Sagar University, Banglore, IndiaBeena MathewMahatma Gandhi University, Kottayam, Kerala, IndiaChandra Shekhar KushwahaDepartment of Polymer Science, Bhaskaryacharya College of Applied Sciences, University of Delhi, Delhi, IndiaD Amilan JoseDepartment of Chemistry, National Institute of Technology, Kurukshetra, IndiaD NavadeepthyDepartment of Nanoscience and Technology, Bharathiar University, CoimbatoreBharathiar University, Coimbatore, Tamilnadu, IndiaG SrividhyaDepartment of Nanoscience and Technology, Bharathiar University, Coimbatore, Tamilnadu, IndiaJ DebbarmaDepartment of Chemistry, National Institute of Technology, Agartala, Tripura (West), IndiaJuhi SrivastavaDepartment of Chemistry, MMV, Banaras Hindu University, Varanasi, Uttar Pradesh, IndiaM Swapna SaiCentre for Applied Research, Chennai Institute of Technology, Chennai, IndiaM Varsha ShreeCentre for Applied Research, Chennai Institute of Technology, Chennai, IndiaManju SrivastavaDayalbagh Educational Institute, Agra, Uttar Pradesh, IndiaMeenakshi SinghDepartment of Chemistry, MMV, Banaras Hindu University, VaranasiUttar Pradesh, Uttar Pradesh, IndiaMitali SahaDepartment of Chemistry, National Institute of Technology, Agartala, Tripura (West), IndiaN PonpandianDepartment of Nanoscience and Technology, Bharathiar University, Coimbatore, Tamilnadu, IndiaNancy SharmaDepartment of Chemistry, National Institute of Technology, Kurukshetra, IndiaNazia SiddiquiDayalbagh Educational Institute, Agra, Uttar Pradesh, IndiaPrashanth S. AdarakattiSVM Arts, Science and Commerce College, Karnataka, IndiaPratibha SinghDepartment of Polymer Science, Bhaskaryacharya College of Applied Sciences, University of Delhi, Delhi, IndiaS KeerthanaDepartment of Nanoscience and Technology, Bharathiar University, Coimbatore, Tamilnadu, IndiaSachin SaxenaDayalbagh Educational Institute, Agra, Uttar Pradesh, IndiaSajini TSt Berchmans Autonomous College (Affiliated to Mahatma Gandhi University), Kottayam, IndiaSaroj Kr ShuklaDepartment of Polymer Science, Bhaskaryacharya College of Applied Sciences, University of Delhi, Delhi, IndiaSrushti GadiyaramDepartment of Chemistry, National Institute of Technology, Kurukshetra, IndiaSuma B. PatriDepartment of Chemistry, Bangalore University, Central College Campus, Bengaluru, IndiaV DhinakaranCentre for Applied Research, Chennai Institute of Technology, Chennai, India
Nanocomposites: Introduction, Structure, Properties and Preparation Methods
V Dhinakaran1,*,M Swapna Sai1,M Varsha Shree1
1 Centre for Applied Research, Chennai Institute of Technology, Chennai-600069, India
Abstract
The production of composites and materials based on nanocellulose has attracted considerable attention in the last few decades since their abundance, renewability, high strength and rigidity, environmental friendliness, and low weight are all unmissable and potentially useful. This analysis deals with crucial factors in the manufacture of nanocellulose composites and presents and explores different composite processing techniques. Rare combinations of features and new design opportunities are seen in high-performance nanocomposites. Their potential is so high that their utility in different fields, ranging from packaging to biomedicine, with an annual growth rate projected at around 25% and a standardized summary emphasizes the need for such products, their methods of fabrication, and several recent studies on structure, properties and potential applications. There is a focus on the possible use of naturally occurring materials like clay-based minerals, chrysotile and lignocellulose fibers. In this chapter, an overview of nanocomposites is deliberated in detail and the nanocomposite applications provide new technology and business options for different industries in the aerospace, vehicle, electronics, electrical and biomedical engineering sector as they are naturally friendly.
Keywords: Carbon nanotubes, Nanocomposites, Nanometers, Polymer matrix, Scanning tunnel microscope, Sensors.
*Corresponding author V. Dhinakaran: Centre for Applied Research, Chennai, Institute of Technology, Chennai- 600069, India; Email:
[email protected]CONSENT FOR PUBLICATION
Not applicable.
CONFLICT OF INTEREST
The author declares no conflict of interest, financial or otherwise.
ACKNOWLEDGEMENTS
Declared none.
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Nanocomposites: A Boon To Material Sciences
Sachin Saxena1,*,Nazia Siddiqui1,Manju Srivastava1
1 Dayalbagh Educational Institute, Dayalbagh-282005, India
Abstract
The imperfections of microstructures and monolithic in different realms of material sciences have been completely engulfed by the improved characteristics and excellent properties of nanocomposites. Their multiphase components with nano dimensions provide these structures with much superiority over conventional composites. This paper is a brief review about nanocomposites and their classification. Based on the dimensionality of particle size these can be grouped into one-two- and three-dimensional nanomaterial derived composites while if the number of components form the basis, they can be classified into binary, ternary and quaternary nanocomposites. This work also discusses and focuses on the computational analysis of nanocomposites with designing and energy calculation studies, based on DFT, and other mathematical tools and models. The role of metal organic framework-based nanocomposites in sensor fabrication and quantification of different redox system have also been listed.
Keywords: Nanocomposites, Binary, Ternary, Quaternary, Metal organic frameworks.
*Corresponding Author S. Saxena: Dayalbagh Educational Institute, Dayalbagh-282005, India; Email:
[email protected]