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The Technology of Discovery Incisive discussions of a critical mission-enabling technology for deep space missions In The Technology of Discovery: Radioisotope Thermoelectric Generators and Thermoelectric Technologies for Space Exploration, distinguished JPL engineer and manager David Woerner delivers an insightful discussion of how radioisotope thermoelectric generators (RTGs) are used in the exploration of space. It also explores their history, function, their market potential, and the governmental forces that drive their production and design. Finally, it presents key technologies incorporated in RTGs and their potential for future missions and design innovation. The author provides a clear and understandable treatment of the subject, ranging from straightforward overviews of the technology to complex discussions of the field of thermoelectrics. Included is also background on NASA's decision to resurrect the GPHS-RTG and discussion of the future of commercialization of nuclear space missions. Readers will also find: * A thorough introduction to RTGs, as well as their invention, history, and evolution * Comprehensive explorations of the contributions made by RTGs to US space exploration * Practical discussions of the evolution, selection, and production of RPS fuels * In-depth examinations of technologies and generators currently in development, including skutterudite thermoelectrics for an enhanced MMRTG Perfect for space explorers, aerospace engineers, managers, and scientists, The Technology of Discovery will also earn a place in the libraries of NASA archivists and other historians.

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Table of Contents

Cover

Title Page

Copyright Page

Foreward

Note From the Series Editor

Preface

Authors

Reviewers

Acknowledgments

Glossary

List of Acronyms and Abbreviations

1 The History of the Invention of Radioisotope Thermoelectric Generators (RTGs) for Space Exploration

References

2 The History of the United States’s Flight and Terrestrial RTGs

2.1 Flight RTGS

2.2 Unflown Flight RTGs

2.3 Terrestrial RTGs

2.4 Conclusion

References

3 US Space Flights Enabled by RTGs

3.1 SNAP‐3B Missions (1961)

3.2 SNAP‐9A Missions (1963–1964)

3.3 SNAP‐19 Missions (1968–1975)

3.4 SNAP‐27 Missions (1969–1972)

3.5 Transit‐RTG Mission (1972)

3.6 MHW‐RTG Missions (1976–1977)

3.7 GPHS‐RTG Missions (1989–2006)

3.8 MMRTG Missions: (2011‐Present (2021))

3.9 Discussion of Flight Frequency

3.10 Summary of US Missions Enabled by RTGs

References

4 Nuclear Systems Used for Space Exploration by Other Countries

4.1 Soviet Union

1

4.2 China

References

5 Nuclear Physics, Radioisotope Fuels, and Protective Components

5.1 Introduction

5.2 Introduction to Nuclear Physics

5.3 Historic Radioisotope Fuels

5.4 Producing Modern PuO

2

5.5 Fuel, cladding, and encapsulations for modern

5.6 Summary

References

6 A Primer on the Underlying Physics in Thermoelectrics

6.1 Underlying Physics in Thermoelectric Materials

6.2 Thermoelectric Theories and Limitations

6.3 Thermal Conductivity and Phonon Scattering

References

7 End‐to‐End Assembly and Pre‐flight Operations for RTGs

7.1 GPHS Assembly

7.2 RTG Fueling and Testing

7.3 RTG Delivery, Spacecraft Checkout, and RTG Integration for Flight

References

8 Lifetime Performance of Spaceborne RTGs

8.1 Introduction

8.2 History of RTG Performance at a Glance

8.3 RTG Performance by Generator Type

References

9 Modern Analysis Tools and Techniques for RTGs

9.1 Analytical Tools for Evaluating Performance Degradation and Extrapolating Future Power

9.2 Effects of Thermal Inventory on Lifetime Performance

9.3 (Design) Life Performance Prediction

9.4 Radioisotope Power System Dose Estimation Tool (RPS‐DET)

References

10 Advanced US RTG Technologies in Development

10.1 Introduction

10.2 Skutterudite‐based Thermoelectric Converter Technology for a Potential MMRTG Retrofit

10.3 Next Generation RTG Technology Evolution

10.4 Considerations for Emerging Commercial RTG Concepts

References

Index

End User License Agreement

List of Tables

Chapter 2

Table 2.1 A catalog and summarization of general characteristics of US buil...

Chapter 3

Table 3.1 The United States’ historic, current, and scheduled to be launche...

Chapter 5

Table 5.1 High‐level particle characteristics. Data referenced from the Nat...

Table 5.2 Natural decay modes relevant to RTG fuels.

Table 5.3 Nuclear reactions relevant to RTG fuels.

Table 5.4 Cermet target measuring performance.

Chapter 9

Table 9.1 Changes in Mission Power and Thermoelectric Degradation as a Func...

Table 9.2 Brief description of various RPS‐DET and SCALE software applicati...

Table 9.3 RPS‐DET geometry library selections.

List of Illustrations

Preface

Figure 0.1 A schematic of a silicon‐germanium thermoelectric unicouple used ...

Chapter 1

Figure 1.1 An early experimental thermoelectric generator designed by Jordan...

Figure 1.2 One of the latter prototype thermoelectric generators designed by...

Figure 1.3 The public debut of the SNAP‐3 RTG technology demonstration devic...

Chapter 2

Figure 2.1 Cross section of a SNAP‐3 RTG.[5]

Figure 2.2 A fully assembled SNAP‐9 RTG.[6],

Figure 2.3 Cross section of an assembled SNAP‐19 RTG as flown on the Pioneer...

Figure 2.4 Major components of the modified SNAP‐19 RTGs used on the Viking ...

Figure 2.5 Astronaut Alan Bean removing fuel from the lunar lander to insert...

Figure 2.6 Diagram of the SNAP‐27 RTG.

Figure 2.7 An assembled MHW RTG in cutaway.

Figure 2.8 Cutaway view of the MHW‐RTG heat source assembly.

Figure 2.9 Expanded view of a GPHS module.

Figure 2.10 Diagram illustrating several major components of the GPHS‐RTG....

Figure 2.11 The white MMRTG for the Perseverance Rover after fueling and sit...

Figure 2.12 Cross‐section of a SNAP‐13 thermionic generator.[18]

Figure 2.13 Illustration of the SNAP‐29 concept showing integration with a s...

Figure 2.14 Concept of a SNAP‐7D thermoelectric generator powering a US Navy...

Figure 2.15 Model of SNAP‐15 power source in cutaway.[18]

Figure 2.16 Cutaway view of the SNAP‐21 system.[19]

Figure 2.17 Cutaway view of URIPS power supply.[31]

Figure 2.18 Cutaway view of RG‐1 power system.[31]

Chapter 3

Figure 3.1 Transit 4A spacecraft with companion payloads before launch. Tran...

Figure 3.2 Transit 4A (a) and Transit 4B (b) SNAP‐3B telemetry data. Voltage...

Figure 3.3 Transit 5BN‐1 (a) and Transit 5BN‐2 (b) power (W(o)) histories (s...

Figure 3.4 Intact SNAP‐19 fuel capsule from Nimbus B aborted launch, shown i...

Figure 3.5 Nimbus III spacecraft with 2 SNAP‐19 RTGs visible on the left. [1...

Figure 3.6 Nimbus III SNAP‐19 RTGs power output (W(e)) (smoothed data). [3]...

Figure 3.7 Pioneer 10/11, with 2 RTGs visible on each of 2 booms. [1], NASA....

Figure 3.8 Power history of the Pioneer SNAP‐19 RTGs (summed data). [11]

Figure 3.9 Viking lander model—the two RTGs are covered by windscreens and a...

Figure 3.10 Power (W(e)) history of the Viking SNAP‐19 RTGs (summed and smoo...

Figure 3.11 (a) Apollo landing sites where ALSEPs were deployed. Credit: NAS...

Figure 3.12 Power (W(e)) history of the ALSEP SNAP‐27 RTGs (smoothed data). ...

Figure 3.13 Triad spacecraft.

Figure 3.14 LES 8 and 9 deployed in geosynchronous orbit. [2]

Figure 3.15 Daily maximum and minimum RTG output powers (W) for LES‐8 during...

Figure 3.16 A Voyager spacecraft, with three MHW‐RTGs end‐to‐end on the boom...

Figure 3.17 Power (W(e)) history of Voyager MHW‐RTGs, incomplete data circa ...

Figure 3.18 Galileo at Io, with Jupiter in the background. The two GPHS‐RTGs...

Figure 3.19 Galileo Total RTG Power (telemetry and predictions, GE ’90 Estim...

Figure 3.20 Ulysses spacecraft. [20], NASA.

Figure 3.21 Measured and Predicted Power from the Ulysses GPHS‐RTG. F‐3 is t...

Figure 3.22 Cassini‐Huygens at Saturn. Two of the GPHS‐RTGs are visible on t...

Figure 3.23 Cassini recorded RTG power output telemetry data over the entire...

Figure 3.24 Artist’s rendition of New Horizons at Pluto, with GPHS‐RTG in th...

Figure 3.25 New Horizons (NH) Power History.

Figure 3.26 Curiosity took this self‐portrait on 11 May 2016.

Figure 3.27 Mars map showing landing sites of Viking 1, Viking 2, Curiosity,...

Figure 3.28 Curiosity Rover MMRTG monthly averaged power.

Figure 3.29 Artist’s rendition of Perseverance rover, with MMRTG on the left...

Figure 3.30 Perseverance Rover MMRTG Daily Averaged Power.

Figure 3.31 Perseverance MMRTG (F2) power output during surface operations, ...

Figure 3.32 Conceptual art of Dragonfly dual‐quadcopter on Titan, with RTG e...

Figure 3.33 NASA’s launched radioisotope spaceflight missions by destination...

Figure 3.34 Non‐NASA launched radioisotope spaceflight missions.

Figure 3.35 Past, current, and upcoming US RTG missions by decade.

Figure 3.36 RTG power in space from past, current, and upcoming US missions ...

Figure 3.37 The number of RTG units launched by past, current, and upcoming ...

Chapter 4

Figure 4.1 Model of the Lunokhod 1 rover in the Museum of Cosmonautics (Mosc...

Chapter 5

Figure 5.1 Illustration of a helium atom’s fundamental particles, regions, a...

Figure 5.2 Exponential decay behavior of radioisotopes related to first thre...

Figure 5.3 Decay chain of pure

238

Pu. Image permissions: OECD NEA, JANIS and...

Figure 5.4 Illustration of the fields that charged particles experience whil...

Figure 5.5 Total neutron cross sections for

1

H (a) and

238

Pu (b). Cross sect...

Figure 5.6 Production of

238

Pu from

237

Np.

Figure 5.7

238

Pu production process.

Figure 5.8 Chemical processing campaign flowsheet.

Figure 5.9 Potential full‐scale production schedule for chemical processing ...

Figure 5.10 SNAP‐19 heat source.

Figure 5.11 SNAP‐27 heat source.

Figure 5.12 Multi‐hundred watt heat source.

Figure 5.13 Aeroshell materials: fine weave pierced fabric and AXF‐5Q graphi...

Figure 5.14 Microstructure of carbon‐bonded carbon fiber (CBCF) insulation....

Figure 5.15 Clad vent set: shield cup assembly at left with weld shield at t...

Figure 5.16 Clad vent set: shield cup assembly in background with weld shiel...

Chapter 6

Figure 6.1 First Brillouin zones of (a) simple cubic, (b) face‐center cubic,...

Figure 6.2 Energy vs. lattice directions for (a) Free‐electron model and an ...

Figure 6.3 Calculated band structure and DOS of several thermoelectric mater...

Figure 6.4 Phonon dispersion plot within crystalline Si. [19]

Figure 6.5 Crystal structure of skutterudite, with the filler atoms in cyan,...

Chapter 7

Figure 7.1 Lipinski, Ronald J., Hensen, Danielle L. “Criticality Calculation...

Figure 7.2 Cutaway and Exploded View of Step‐0 GPHS Module and Stack.

Figure 7.3 GPHS aeroshell cap with lune form made in upper left corner.

Figure 7.4 GPHS module set‐up on the jig grinder before performing an aerosh...

Figure 7.5 Two GPHS fuel clads retrieved from a cut‐open PC and placed in th...

Figure 7.6 A fueled GIS being lowered into a GPHS cavity using a vacuum lift...

Figure 7.7 An ETG received at INL. This ETG became an RTG once fueled and wa...

Figure 7.8 An MMRTG’s cavity following removal of the electrical heater and ...

Figure 7.9 A fueled GPHS module inside the MRM canister being prepared for f...

Figure 7.10 RTG assembly fixture applying preload to the end of an RTG fueli...

Figure 7.11 INL vibration technician monitoring RTG test date displayed on t...

Figure 7.12 An MMRTG mounted to its vibration test fixture in the vertical t...

Figure 7.13 An RTG being weighed. Note the gold and red rigging for lifting ...

Figure 7.14 An RTG mounted to the custom aluminum fixture for mass propertie...

Figure 7.15 An RTG positioned for magnetics measurements.

Figure 7.16 Thermal Vacuum Atmosphere Chamber to test RTGs.

Figure 7.17 An MMRTG suspended in a Thermal Vacuum Atmosphere Chamber.

Figure 7.18 MMRTG Flight Unit 1 long‐term storage preparation at INL.

Figure 7.19 INL nuclear operators disassemble a 9904 shipping cask. The whit...

Figure 7.20 INL nuclear operators load the MMRTG Flight Unit 2 (F2), for the...

Figure 7.21 MMRTG Flight Unit 2 (F2) for Mars 2020 mission “hot‐fit” checks ...

Figure 7.22 MMRTG Flight Unit 2 (F2) for Mars 2020 mission being hoisted up ...

Chapter 8

Figure 8.1 Compilation of lifetime performance for nearly all missions power...

Figure 8.2 Lifetime performance for RTG missions that predate SNAP‐19 (a) ve...

Figure 8.3 Lifetime performance of the SNAP‐9A flight systems normalized to ...

Figure 8.4 Lifetime performance of the two SNAP‐19B flight systems on the Ni...

Figure 8.5 Lifetime performance of the SNAP‐27 flight systems normalized to ...

Figure 8.6 Lifetime performance of the SNAP‐19 flight systems normalized to ...

Figure 8.7 Lifetime performance of the MHW‐RTG flight systems normalized to ...

Figure 8.8 Lifetime performance of the GPHS‐RTG flight systems normalized to...

Figure 8.9 Lifetime performance of the MMRTG flight system powering Curiosit...

Chapter 9

Figure 9.1 Power generation for Cassini RTGs as a fraction of the beginning‐...

Figure 9.2 Example log‐log plots of RTG data. (a) The first five years of Ca...

Figure 9.3 Rate constant plot for Cassini RTG performance after thermal inve...

Figure 9.4 Plot of residuals for the thermoelectric converter degradation.

Figure 9.5 Power losses originating from decreased BOM power caused by lower...

Figure 9.6 Power losses originating from thermoelectric degradation during M...

Figure 9.7 Radioisotope thermoelectric generator power degradation mechanism...

Figure 9.8 Variations of Seebeck coefficient (a) electrical resistivity, (b)...

Figure 9.9 Comparison of Voyager RTG power output actuals and original DEGRA...

Figure 9.10 Examples of RPS‐DET geometries. (a) Voyager‐like environment, (b...

Figure 9.11 Examples of RPS‐DET 2D cross‐sectional slices of 3D mesh tallies...

Chapter 10

Figure 10.1 Changes under consideration for the potential eMMRTG.

Figure 10.2 Illustration of the MMRTG and eMMRTG thermoelectric couples.

Figure 10.3 Photograph of the SKD couples currently on test at JPL and TESI....

Figure 10.4 The first fabricated SKD 48‐couple module. (a) is the top of the...

Figure 10.5 Cross‐section of a 48‐couple module showing the super‐critically...

Figure 10.6 The normalized peak power of the p‐legs as a function of time an...

Figure 10.7 The normalized peak power of the n‐legs as a function of time an...

Figure 10.8 The normalized peak power of SKD couples as a function of time a...

Figure 10.9 Measured and predicted power for the SKD 48‐couple module is in ...

Figure 10.10 Comparison of current‐best‐estimate of eMMRTG and MMRTG 17‐year...

Figure 10.11 Cutaway diagram of a GPHS‐RTG. Available from: https: //en.wiki...

Figure 10.12 SiGe Unicouple Components. Available from: https://en.wikipedia...

Figure 10.13 GPHS‐RTG Converter Shell and Thermopile Mating Operations. [16]...

Figure 10.14 Illustration Showing NSPM‐20 Tier Factors. [28]

Figure 10.15 Encapsulation and heat source architectures for an

241

Am RTG de...

Guide

Cover Page

Title page

Copyright page

Foreward

Note From the Series Editor

Preface

Authors

Reviewers

Acknowledgments

Glossary

List of Acronyms and Abbreviations

Table of Contents

Begin Reading

Index

Wiley End User License Agreement

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The Technology of Discovery

Radioisotope Thermoelectric Generators and Thermoelectric Technologies for Space Exploration

Edited by

David Friedrich Woerner

Jet Propulsion LaboratoryCalifornia Institute of Technology, USA

This edition first published 2023© 2023 John Wiley & Sons, Inc.

All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, except as permitted by law. Advice on how to obtain permission to reuse material from this title is available at http://www.wiley.com/go/permissions.

The right of David Friedrich Woerner to be identified as the author of the editorial material in this work has been asserted in accordance with law.

Registered OfficeJohn Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, USA

Editorial Office9600 Garsington Road, Oxford, OX4 2DQ, UK

For details of our global editorial offices, customer services, and more information about Wiley products visit us at www.wiley.com.

Wiley also publishes its books in a variety of electronic formats and by print‐on‐demand. Some content that appears in standard print versions of this book may not be available in other formats.Trademarks: Wiley and the Wiley logo are trademarks or registered trademarks of John Wiley & Sons, Inc. and/or its affiliates in the United States and other countries and may not be used without written permission. All other trademarks are the property of their respective owners. John Wiley & Sons, Inc. is not associated with any product or vendor mentioned in this book.

Limit of Liability/Disclaimer of WarrantyWhile the publisher and authors have used their best efforts in preparing this work, they make no representations or warranties with respect to the accuracy or completeness of the contents of this work and specifically disclaim all warranties, including without limitation any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives, written sales materials or promotional statements for this work. The fact that an organization, website, or product is referred to in this work as a citation and/or potential source of further information does not mean that the publisher and authors endorse the information or services the organization, website, or product may provide or recommendations it may make. This work is sold with the understanding that the publisher is not engaged in rendering professional services. The advice and strategies contained herein may not be suitable for your situation. You should consult with a specialist where appropriate. Further, readers should be aware that websites listed in this work may have changed or disappeared between when this work was written and when it is read. Neither the publisher nor authors shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages.

Library of Congress Cataloging‐in‐Publication DataNames: Woerner, David Friedrich, editor.Title: The technology of discovery : radioisotope thermoelectric generators and thermoelectric technologies for space exploration / David Frederich Woerner.Description: Hoboken, NJ : Wiley, 2023. | Includes bibliographical references and index.Identifiers: LCCN 2022051673 (print) | LCCN 2022051674 (ebook) | ISBN 9781119811367 (hardback) | ISBN 9781119811374 (adobe pdf) | ISBN 9781119811381 (epub)Subjects: LCSH: Thermoelectric generators. | Radioisotopes in astronautics. | Thermoelectric apparatus and appliances. | Outer space–Exploration.Classification: LCC TK2950 .W647 2023 (print) | LCC TK2950 (ebook) | DDC 621.31/243–dc23/eng/20221108LC record available at https://lccn.loc.gov/2022051673LC ebook record available at https://lccn.loc.gov/2022051674

Cover Design: WileyCover Images: © NASA/JPL‐Caltech/Malin Space Science Systems

Foreward

I am pleased to commend the Jet Propulsion Laboratory (JPL) Space Science and Technology Series, and to congratulate and thank the authors for contributing their time to these publications. It is not easy for busy scientists and engineers who face constant launch date and deadline pressures to find the time to tell others clearly and in detail how they solve important and difficult problems. So, I applaud the authors of this series for the time and care they devoted to documenting their contributions to the adventure of space exploration. In writing these books, these authors are truly living up to JPL’s core value of openness.

JPL has been NASA’s primary center for robotic planetary and deep‐space exploration since the Laboratory launched the nation’s first satellite, Explorer 1, in 1958. In the years since this first success, JPL has sent spacecraft to each of the planets, studied our own planet in wavelengths from radar to visible, and observed the universe from radio to cosmic ray frequencies. Even more exciting missions are planned for the next decades in all these planetary and astronomical studies, and these future missions must be enabled by advanced technology that will be reported in this series. The JPL Deep Space Communications and Navigation book series captures the fundamentals and accomplishments of those two related disciplines. This companion Science and Technology Series expands the scope of those earlier publications to include other space science, engineering, and technology fields in which JPL has made important contributions.

I look forward to seeing many important achievements captured in these books.

Laurie Leshin, Director

Jet Propulsion Laboratory

California Institute of Technology

Note From the Series Editor

This title is the latest contribution to the Jet Propulsion Laboratory (JPL) Space Science and Technology Series. This series is a companion series of the ongoing Deep Space Communications and Navigation Systems (DESCANSO) Series and includes disciplines beyond communications and navigation. DESCANSO is a Center of Excellence formed in 1998 by the National Aeronautics and Space Administration (NASA) at JPL, which is managed under contract by the California Institute of Technology.

The JPL Space Science and Technology series, authored by scientists and engineers with many years of experience in their fields, lays a foundation for innovation by sharing state‐of‐the‐art knowledge, fundamental principles and practices, and lessons learned in key technologies and science disciplines. We would like to thank the support of the Interplanetary Network Directorate at JPL for their encouragement and support of this series.

Jon Hamkins, Editor‐in‐Chief

JPL Space Science and and Technology Series

Jet Propulsion Laboratory

California Institute of Technology

Preface

“Far better is it to dare mighty things, to win glorious triumphs, even though checkered by failure … than to rank with those poor spirits who neither enjoy nor suffer much, because they live in a gray twilight that knows not victory nor defeat.”

— Theodore Roosevelt

Radioisotope Thermoelectric Generators (RTGs) have proven to be one of the most creative solutions to the challenge of providing a reliable source of electrical power for deep space missions. RTGs have powered spacecraft that have discovered Ocean Worlds in our solar system, evidence that Mars harbored persistent liquid water in its ancient past, the largest known glacier in the solar system on Pluto, that Enceladus—a moon of Saturn—spouts icy plumes fed from a subterranean ocean, and given us our first taste of interstellar space.

This book is a history, primer, reference book, and partial record of what has become one of the most successful technologies ever fielded for the sake of space science, and an educated look at potential futures for RTGs. This title binds all of this together with an explanation of the basic physics of how RTGs are able to produce power from heat, along with discussions of specific programs, missions, failures, and more.

The history of RTG production has been episodic. The first RTG was invented during the Eisenhower administration in the 1950s and gave rise to frequent RTG‐powered space missions in the 1960s and 1970s. However, in subsequent decades, the pace of missions that required this enabling technology waned to approximately the one to two launches per decade we see today. Production of various types of RTGs was stopped and restarted in concert with demand. This led to a dwindling of the industrial base and expertise required to produce these unique generators, and imprinted an ebb and flow or episodic pattern onto the production rate of RTGs over time.

Today, the US Department of Energy and NASA have formed a strong team using a “constant rate” approach to serve the demand and needs of a power‐hungry community of space explorers. RTGs provide power where the sun does not shine regularly or strongly enough, and, we believe, RTGs will continue to be a vital power and energy source for complex deep space missions for generations to come. They are solid‐state, quiet, extremely reliable, and long‐lived.

The history of RTGs is glorious. That may sound like hyperbole, it is not. Some RTGs have been powering spacecraft in flight for over 45 years. No RTG has ever caused a mission or spacecraft failure. Their performance and lifetimes are unmatched by any other power source for spaceflight that humankind has mastered. They require no periodic maintenance in flight. RTGs are electrical generators that enable humankind to explore our darkest, dustiest, coldest regions of the solar system, and the vastness of the space outside of our sun’s minuscule heliosphere.

RTGs use materials that exhibit the Seebeck effect to convert heat into Direct Current (DC) electrical power. The Seebeck effect was first reported in 1823 by the Baltic German physicist Thomas Johann Seebeck. His discovery is the foundation for the technologies employed in RTGs for space missions using thermoelectric couples.

RTGs convert heat to power by directing heat flow through thermoelectric couples. Heated thermoelectric couples produce a voltage and when a load is applied, current will flow from each couple. Voila, DC electricity. Yet, RTGs are products of chemistry, materials science, nuclear physics, and decades of sophisticated engineering. They are solid‐state, have no moving parts, and each is unitary, needing no ancillary equipment to produce power. Since their creation, extensive and well‐funded research, engineering, and flight experience forged modern RTG designs for space exploration.

RTGs are not simple. They are annular in design and employ rings of thermoelectric couples arrayed around a stack of heat sources to convert heat to electricity. Drawings of them tend to unintentionally mask some of the internal components, some of which can reach temperatures over 1,000 degrees Centigrade or 1,832 degrees Fahrenheit, and are maintained at those temperatures for years. It is difficult to comprehend what happens to materials at those temperatures. Chemical reactions are vastly accelerated over our day‐to‐day experiences. Materials that are solid at room temperature may sublimate when heated to such temperatures. In addition, materials can diffuse into one another.

A schematic of a thermoelectric couple suggests simplicity and masks several phenomena, such as the dramatic temperature reduction between its hot‐ and cold‐side components. For example, Figure 0.1 shows a silicon‐germanium thermoelectric couple (aka unicouple), which comprises five subassemblies that include eighteen separate components. During steady‐state operation in today’s RTGs, the temperature along the length of this type of unicouple drops from 1,035 °C (1,895 °F) at the hot shoe to 290 °C (554 °F) at the heat shunt. That gradient stretches just over one inch and yields a temperature change of ~750 °C (~1,382 °F). This dramatic temperature gradient suggests deep, unobvious complexities tied to thermoelectric technologies and RTGs.

Figure 0.1 A schematic of a silicon‐germanium thermoelectric unicouple used in the GPHS‐RTGs flown on the Cassini mission. Parenthetical letters refer to chemical elements or compounds.

Credit: Lockheed Martin.

Insight into the unobvious is what you will discover in these pages and should provide the reader with enough RTG history to make them conversant, enough flight history to incorporate this knowledge into deep space mission designs, some background to inform policy and funding decisions, and comprehensive insights intended to help sidestep many of the failures of the past. We employed real‐world examples throughout and applied theory to practical situations. We intend this book to bridge the gap between university studies and professional work. Therefore, we provide extensive lists of references to point readers to fundamental and referential sources.

The material herein complements and expands the public history of RTGs, explores the current state‐of‐ the‐art, and attempts to peer forward in time. We intend to provide more historical detail of both successes and failures, discuss advances and setbacks of novel thermoelectric materials and technologies that scientists have investigated and abandoned, and chart possible courses to future RTGs and their technologies.

The reinvigorated search for life beyond Earth and NASA’s drive to install a permanent human presence on the Moon have breathed new life into space exploration, and each thrust will require technologies that operate effectively in cold and dark spaces. RTGs provide hope for these immediate goals and will enable many more important discoveries. It is a marvelous time to be exploring space!

David Friedrich Woerner,

Jet Propulsion Laboratory/California Institute of Technology, Pasadena, California, USA

Authors

Brian K. BairstowJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena California

Chadwick D. BarklayUniversity of Dayton ResearchInstitute, Dayton, Ohio

Russell BennettTeledyne Energy Systems, Inc.Hunt Valley, Maryland

Thierry CaillatJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Ike C. ChiJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Emory D. CollinsOak Ridge National LaboratoryOak Ridge, Tennessee

Shad E. DavisIdaho National LaboratoryIdaho Falls, Idaho

David W. DePaoliOak Ridge National LaboratoryOak Ridge, Tennessee

Patrick E. FryeAerojet RocketdyneCanoga Park, California

Nidia C. GallegoOak Ridge National LaboratoryOak Ridge, Tennessee

Lawrence H. HeilbronnUniversity of TennesseeKnoxville, Tennessee

Tim HolgateJohn Hopkins University AppliedPhysics Laboratory, Laurel, Maryland

Chris L. JensenOak Ridge National LaboratoryOak Ridge, Tennessee

Steve KeyserTeledyne Energy Systems, Inc.Hunt Valley, Maryland

Andrew M. LaneAerojet RocketdyneCanoga Park, California

Young H. LeeJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Jong‐Ah PaikJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Kaara K. PattonOak Ridge National LaboratoryOak Ridge, Tennessee

Brian PhanJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Stan PinkowskiJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Glenn R. RomanoskiOak Ridge National LaboratoryOak Ridge, Tennessee

Kevin L. SmithJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Michael B.R. SmithOak Ridge National LaboratoryOak Ridge, Tennessee

Ying SongTeledyne Energy Systems, Inc.Hunt Valley, Maryland

George B. UlrichOak Ridge National LaboratoryOak Ridge, Tennessee

Joe VanderVeerTeledyne Energy Systems, Inc.Hunt Valley, Maryland

Hsin WangOak Ridge National Laboratory,Oak Ridge, Tennessee

Karl A. WefersAerojet RocketdyneCanoga Park, California

Robert M. WhamOak Ridge National LaboratoryOak Ridge, Tennessee

Christofer E. WhitingUniversity of Dayton Research InstituteDayton, Ohio

David Friedrich WoernerJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Andrew J. ZillmerIdaho National LaboratoryIdaho Falls, Idaho

Reviewers

Chadwick D. BarklayUniversity of Dayton ResearchInstitute, Dayton, Ohio

Charles E. BensonJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Thierry CaillatJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Eric S. ClarkeIdaho National LaboratoryIdaho Falls, Idaho

Joe C. GiglioIdaho National LaboratoryIdaho Falls, Idaho

Terry J. HendricksRetired—Jet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Douglas M. IsbellJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Stephen G. JohnsonIdaho National LaboratoryIdaho Falls, Idaho

Vladimir JovovicJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Emily F. KlonickiJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Christopher S. MatthesJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Lucas T. RichIdaho National LaboratoryIdaho Falls, Idaho

Glenn R. RomanoskiOak Ridge National LaboratoryOak Ridge, Tennessee

Carl E. SandiferNASA Glenn Research CenterCleveland, Ohio

Michael B.R. SmithOak Ridge National LaboratoryOak Ridge, Tennessee

George B. UlrichOak Ridge National LaboratoryOak Ridge, Tennessee

Christofer E. WhitingUniversity of Dayton Research InstituteDayton, Ohio

David Friedrich WoernerJet Propulsion Laboratory/CaliforniaInstitute of TechnologyPasadena, California

Andrew J. ZillmerIdaho National LaboratoryIdaho Falls, Idaho

Acknowledgments

I wish to acknowledge my parents, Robert Woerner and Mary Crow. It is their devotion to me, love, and upbringing that made my participation in this project possible.I want to thank Brett Kurzman and Stacey Woods, our editors, and their colleagues at Wiley.com. They were responsive, dedicated, patient, and extremely helpful in preparing this manuscript.

I want to thank the small army of women and men that made this publication possible, those tireless souls that founded, grew, and built the Radioisotope Power System community into what it is today. The list of their names could fill the pages of this book, and I struggled with who to single out and mention here and concluded I would err on the side of not slighting anyone and just say thank you to the entire RPS community. Thank you. Thank you. You gave me friends, companions, and a career I did not expect.

I am deeply humbled and fascinated by the work and achievements of the RPS community and hope that this manuscript does them at least some small amount of justice. I know the authors have poured their hearts into the book and deserve a round of applause.

I/we are indebted to the reviewers whose clarity of mind and perceptive insights kept us focused and out of the “ditch” of lousy writing.

Lastly, I want to thank those space exploring scientists and engineers who thrill the world with their fabulous discoveries. The draft of the next Planetary Science and Astrobiology Decadal Survey was released less than a handful of days before I typed these words. The draft promises that the search for past and present life in our solar system will continue. It describes new and exciting scientic missions to come in the next decade should Congress and NASA fund them. Several missions to destinations in our solar system are only achievable by RPS powered robots. Expect grand findings.

A portion of this research was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (80NM0018D0004).

Portions of this work were authored under the support of Oak Ridge National Laboratory managed UT‐ Battelle, LLC, under contract DE‐AC05‐00OR22725 with the US Department of Energy (DOE).

Portions of this work were authored thanks to the generous support of the University of Dayton Research Institute.

A portion of this research was carried out at the Idaho National Laboratory, under a contract with the US

Department of Energy (DE‐AC07‐05ID14517).

List of Acronyms and Abbreviations

3M

Minnesota Mining and Manufacturing Company

AEC

Atomic Energy Commision

ALSEP

Apollo Lunar Surface Experiments Package

APL

Applied Physics Laboratory

AR

Aerojet Rocketdyne

ARC

Ames Research Center

ATLO

Assembly, Test, and Launch Operations

ATR

Advanced Test Reactor

AU

Astronomical Unit

BOL

Beginning of Life

BOM

Beginning of Mission

CBCF

Carbon Bonded Carbon Fiber

CCAFS

Cape Canaveral Air Force Station

CFC

Chlorofluorocarbon

CFR

Code of Federal Regulations

CG

Center of Gravity

CLPS

Commercial Lunar Payload Services

CM

Configuration Manager

CMOS

Complementary Metal Oxide Semiconductor

COC

Certificate of Compliance

COPV

Composite Over‐Wrapped Pressure Vessel

CSCBA

Converter Shipping Container Base Assembly

DARPA

Defense Advanced Research Projects Agency

DC

Direct Current

DoD

Department of Defense

DOE

Department of Energy

DOS

Density of States

DOT

Department of Transportation

DPA

Destructive Physical Analysis

DSA

Design Safety Analysis

ECR

Electrical Contact Resistance

EHS

Electric Heat Source

EM

Electromagnetic

EMI/EMC

Electromagnetic Interference/Electromagnetic Compatibility

eMMRTG

Enhanced Multi‐Mission Radioisotope Thermoelectric Generator

ENDF

Evaluated Nuclear Data File

EODL

End of Design Life

EOM

End of Mission

ESA

European Space Agency

ESD

Electrostatic Discharge

ETG

Electrically Heated Thermoelectric Generator

EU

Engineering Unit

FAA

Federal Aviation Administration

FC

Fuel Clad

FET

Field Effect Transistor

FWPF

TM

Fine Weave Pierced

TM

Fabric

GE

General Electric

GFY

Government Fiscal Year

GIS

Graphite Impact Shell

GLFC

Graphite LM Fuel Cask

GPHS

General Purpose Heat Source

GPHS‐RTG

General Purpose Heat Source Radioisotope Thermoelectric Generator

GPS

Global Positioniong System

GRC

Glenn Research Center, NASA

GSE

Ground Support Equipment

GSFC

Goddard Spaceflight Center, NASA

GUI

Graphical User Interface

HBM

Human‐Body Model

HDBK

Handbook

HEOMD

Human Exploration and Operations Mission Directorate

HEPA

High‐Efficiency‐Air‐Particulate

HFIR

High Flux Isotope Reactor

HRS

Heat Rejection System

HS

Heat Source

I&T

Integration and Test

IAAC

Inert Atmosphere Assembly Chamber

ICV

Inner Containment Vessel

IECEC

International Energy Conversion Engineering Conference

INL

Idaho National Laboratory, DOE

INSRB

Interagency Nuclear Safety Review Board

IRD

Interface Requirements Document

IRHS

Intact Reentry Heat Source

ISPM

International Solar Polar Mission

ISRO

Indian Space Research Organization

JHUAPL

Johns Hopkins University Applied Physics Laboratory

JPL

Jet Propulsion Laboratory/California Institute of Technology

KAERI

Korea Atomic Energy Research Institute

KBO

Kuiper Belt Object

KSC

Kennedy Space Center

LANL

Los Alamos National Laboratory, DOE

LDS

Ling Dynamic System

LES

Lincoln Experimental Satellite

LET

Linear Energy Transfer

Li‐ion

Lithium Ion

LMTO

Linear Muffin‐Tin Orbital

LPPM

Life Performance Prediction Model

LSP

Launch Services Program

LTOF

Lift Turnover Fixture

LV

Launch Vehicle

LWRHU

Lightweight Radioisotope Heater Unit, aka RHU

MACS

Medium Altitude Communications Satellite

MHW

Multi‐Hundred‐Watt

MHW HS

Multi‐Hundred‐Watt Heat Source

MHW‐RTG

Multi‐Hundred‐Watt‐Radioisotope Thermoelectric Generator

MIL

Military

min

minimum; except when min is clearly being used to denote the time unit minute

MIT

Massachusetts Institute of Technology

MITG

Modular Isotopic Thermoelectric Generator

ML

Mission Life

MMAS

Martin Marietta Astro Space

MMLT

Mini‐Modules Life Tester

MMRTG

Multi‐Mission Radioisotope Thermoelectric Generator

MRM

Module Reduction and Monitoring

MSL

Mars Science Laboratory

NASA

National Aeronautics and Space Administration

NEPA

National Environmental Policy Act

NETS

Nuclear and Emerging Technologies for Space Conference

Next Gen RTG

Next Generation Radioisotope Thermoelectric Generator

NGRTG

Next Generation Radioisotope Thermoelectric Generator

NH

New Horizons

NNDC

National Nuclear Data Center

NNL

National Nuclear Laboratory

NOAA

National Oceanic and Atmospheric Administration

NPAS

Nuclear Power Assessment Study

NPS

Nuclear Power System

NRC

Nuclear Regulatory Commission

NSPM

National Security Presidential Memoranda

ORNL

Oak Ridge National Laboratory, DOE

PAWS

Powered Polar Automated Weather Station

PGS

Power Generation and Storage

PHSF

Payload Hazardous Servicing Facility

PMC

Plutonia Molybdenum Cermet

PMP

Portable Monitoring Package

PPO

Pure Plutonium Oxide

PRT

Platinum Resistance Thermometer

PSD

Planetary Science Division, NASA

QU

Qualification Unit

REDC

Radiochemical Engineering Development Center, ORNL

RFP

Request For Proposal

RHU

Radioisotope Heater Unit

RIC

RTG Integration Cart

RPS

Radioisotope Power System

RPS‐DET

Radioisotope Power System Dose Estimation Tool

RSICC

Radiation Safety Information Computational Center

RTG

Radioisotope Thermoelectric Generator

RTGF

Radioisotope Thermoelectric Generator Facility

RTGTS

Radioisotope Thermoelectric Generator Transportation System

SAM

Sample Analysis Mars

SAR

Safety Analysis Report

SARC

Safety Analysis Report Commitment

SEB

Single‐Event Burnout

SEE

Single‐Event Effect

SEFI

Single‐Event Functional Interupt

SEGR

Single‐Event Gate Rupture

SER

Safety Evaluation Report

SET

Single‐Event Transient

SEU

Single‐Event Upset

SIG

Selenide Isotope Generator

SiGe

Silicon germanium

SKD

Skutterudite

SMD

Science Mission Directorate, NASA

SNAP

Systems for Nuclear Auxiliary Power

SNS

Space Nuclear System

SOW

Statement of Work

SPF

Single Point Failure

SRG

Stirling Radioisotope Generator

SRS

Savannah River Site

SSPSF

Space and Security Power Systems Facility

STD

Standard

SUV

Sports Utility Vehicle

SV

Space Vehicle

SwRI

Southwest Research Institute

TAGS

Tellurium antimony germanium silver alloy

TBR

To Be Reviewed

TCR

Thermal Contact Resistance

TE

Thermoelectric

TEC

Thermoelectric Couple

TEG

Thermoelectric Generator

TEM

Thermoelectric Multicouple

TESI

Teledyne Energy Systems, Incorporated

TRN

Terrain Relative Navigation

TSOC

Test and Operations Support Contract

TVAC

Thermal Atmosphere Vacuum Chamber

UDRI

University of Dayton Research Institute

UK

United Kingdom

US

United States

USAF

United States Air Force

USN

United States Navy

VA

Verification Activity

VCE

Voltage, Collector‐Emitter

VDS

Volts, Drain‐Source

VHP

Vaporous Hydrogen Peroxide

VIF

Vertical Integration Facility

wrt

with respect to

1The History of the Invention of Radioisotope Thermoelectric Generators (RTGs) for Space Exploration

Chadwick D. Barklay

University of Dayton Research Institute, Dayton, Ohio

In December of 1903, the Wright Brothers made the first successful powered flight of an airplane. There are significant levels of examination of Orville and Wilbur’s incremental improvements to the original design of their flying machine to build the Wright Flyer II. However, there is not much appreciation of the backstory that inspired the brothers to explore the fundamentals of aerodynamics and pursue the research and development required to make a powered, heavier‐than‐air aircraft. Wilbur Wright indicated in a letter he wrote in 1912 that the pioneering work of Otto Lilienthal in the late 1800s was a precursor to their efforts. But it was a rubber band‐powered toy helicopter their father, Milton Wright, gave them in 1878 that Orville credited as the object that sparked their interest in flight.

As an opening discussion of the history of the radioisotope thermoelectric generator (RTG), it is essential to understand the backstory of the invention that has allowed humankind to explore beyond the solar system’s boundaries. In 1954, Kenneth Jordan and John Birden invented the RTG at the Atomic Energy Commission (AEC) Mound Laboratory. Oral history posits that the two inventors drafted their initial design concept during lunch on a napkin in the Mound Laboratory cafeteria. Their initial research efforts used a small steam‐electric generator to demonstrate that heat utilized from the radioactive decay of polonium‐ 210 could generate electricity. However, more‐efficient methods for producing electricity were required, and Jordan and Birden coupled a polonium‐210 heat source to a thermoelectric material array to generate electricity (Figure 1.1). This early prototype used forty chromel‐constantan thermocouples to generate power from a suspended sphere containing 146 curies of encapsulated polonium‐210. The outside container of the prototype was made of aluminum and used an early form of silica aerogel (Santocel) as insulation. This unit produced 9.4 milliwatts of power for a total efficiency of 0.20%.[1] In 1959, Jordan and Birden received a patent for their invention, which is still the underpinning innovation for all RTGs used by the National Aeronautics and Space Administration (NASA) for planetary and deep‐space exploration.[2]

Figure 1.1 An early experimental thermoelectric generator designed by Jordan and Birden that couples a polonium‐210 heat source with a thermoelectric material array.

Credit: Mound Science and Energy Museum Association.

Similarly, the events leading up to the first powered flight at Kittyhawk, the backdrop of Jordan and Birden’s early efforts, are not widely known. The US Congress established the AEC in the shadows of World War II to establish centralized governmental controls to manage the research and production of atomic weapons in the post‐war era.[3] During the first decade of the AEC, laboratories under the AEC umbrella conducted a broad spectrum of research activities on producing natural and synthetic radioisotopes in reactors and cyclotrons. These early efforts focused on how radioisotopes can influence thermonuclear fusion produced by weapons. In conjunction with research and development activities for weapons programs, research was also ongoing to determine the utility of radioisotopes for particle physics, medicine, geography, and several industrial applications.

Within the same timeframe, the War Department, the predecessor to the Department of Defense, recognized a need for establishing a non‐profit, global policy think tank, and the Douglas Aircraft Company created the RAND Project, later the RAND Corporation, to fulfill this need. In 1946, the RAND Project explored the preliminary design of a satellite vehicle [4], and in 1947, RAND expanded its examination to evaluate the use of radioisotopes to address the electrical power requirements for satellite vehicles.[5] This initial analysis considered the use of polonium‐210 and strontium‐89 as thermal sources for power generation. In 1949, RAND published a study that outlined the use of nuclear power sources for satellites in Earth orbit, and in 1951, the Department of Defense (DOD) requested that the AEC initiate research on nuclear power for spacecraft.[6] As a result, the AEC initiated a series of studies that concluded that both fission and radioisotope power systems were technically feasible for satellites. [7]

In late 1953, President Dwight D. Eisenhower delivered his “Atoms‐for‐Peace” address at the United Nations to promote the peaceful uses of atomic energy. During that same timeframe, Jordan and Birden built two experimental thermal batteries using polonium‐210 and chromel‐constantan thermocouples to validate their thermal battery theory and develop fabrication techniques. These experimental units had approximately ten times the work capacity of ordinary dry cell batteries of the same weight.[1]

Jordan and Birden fabricated seven experimental units in total, and the third unit (Figure 1.2) was the prototype of the remaining generators built. These later units employed twelve thermopiles, each consisting of thirty‐seven chromel‐constantan thermocouples supported by mica cards that were vertically mounted and radially spaced on aluminum rings. Figure 1.2 also shows an assembled and disassembled thermopile.

Figure 1.2 One of the latter prototype thermoelectric generators designed by Jordan and Birden.

Credit: Mound Science and Energy Museum Association.

Jordan and Birden made extensive measurements on these units to determine efficiencies and the effects of various types of insulation, including vacuum, noise levels, ambient temperatures, matched and unmatched loads on the units’ performance.[8] In general, these latter prototypes produced approximately 50 milliwatts of power for a total efficiency of 0.32%. The last units in this series of prototypes were designed and built based on specifications that delineated load voltage, power, durability, and design life requirements. It was the first step to ensuring that future generators would be sufficiently rugged to withstand the vibrational and quasi‐static forces associated with space launches.

In 1955 the AEC formally initiated the Systems for Nuclear Auxiliary Power (SNAP) program, which focused on experimental radioisotope and fission systems. The objective of this program was to develop compact, lightweight, reliable atomic electric devices for use in space and terrestrial applications. Under the SNAP program, odd numbers designated RTGs systems, and even numbers represented fission reactor systems. In 1957, the Martin Company developed the SNAP‐1 RTG, which was assembled at the AEC Mound Laboratory. As the development of SNAP‐1 progressed, the Martin Company subcontracted with Westinghouse Electric and the Minnesota Mining and Manufacturing Company (3M) to develop the SNAP‐3 RTG. In 1958, 3M delivered the SNAP‐3 to the Martin Company, which fueled the unit with encapsulated polonium‐210 from Mound Laboratory. The SNAP‐3 produced 2.5 We, and President Eisenhower displayed the power system in the US White House’s Oval Office on 16 January 1959 (Figure 1.3).[9]