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Provides corrosion basics in a lucid manner to students and working professionals and over 80 corrosion-failure analysis case studies
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Veröffentlichungsjahr: 2015
WILEY SERIES IN CORROSION
R. Winston Revie, Series Editor
Corrosion Inspection and Monitoring • Pierre R. Roberge
Corrosion Resistance of Aluminum and Magnesium Alloys: Understanding, Performance, and Testing • Edward Ghali
Microbiologically Influenced Corrosion • Brenda J. Little and Jason S. Lee
Corrosion Resistance of Aluminum and Magnesium Alloys • Edward Ghali
Metallurgy and Corrosion Control in Oil and Gas Production • Robert Heidersbach
Green Corrosion Inhibitors: Theory and Practice • V. S. Sastri
Heterogenous Electode Processes and Localized Corrosion • Yongjun Tan
Stress Corrosion Cracking of Pipelines • Y Frank Cheng
Challenges in Corrosion: Costs, Causes, Consequences and Control • V. S. Sastri
Corrosion Failures: Theory, Case Studies, and Solutions • K. Elayaperumal and V. S. Raja
K. ELAYAPERUMAL
Corrosion and Metallurgical Consultant, 3034, Sobha Amethyst, Kannamangala, Bangalore 560 067 India
V.S. RAJA
Professor, Dept. of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Powai, Mumbai, India
Copyright © 2015 by John Wiley & Sons, Inc. All rights reserved
Published by John Wiley & Sons, Inc., Hoboken, New Jersey
Published simultaneously in Canada
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Library of Congress Cataloging-in-Publication Data:
Elayaperumal, K. (Kailasanathan), 1937- Raja, V.S (Vngaranahalli Srinivasan),1958-
Corrosion failures: theory, case studies, and solutions/K. Elayaperumal, V.S. Raja.
pages cm
Includes bibliographical references and index.
ISBN 978-0-470-45564-7 (cloth)
1. Corrosion and anti-corrosives. 2. Metals- Stress corrosion cracking. I. Title.
TA418.74.E42 2015
620.1′1223–dc23
2015000046
Cover image courtesy of V.S. Raja
Cover
Wiley Series in Corrosion
Title Page
Copyright
About the Authors
Foreword
Preface
Chapter 1 Introduction
1.1 The Phenomenon of Corrosion
1.2 Importance of Corrosion
1.3 The Purpose and Format of the Book
References
Chapter 2 Thermodynamics and Kinetics of Electrochemical Corrosion
2.1 Introduction
2.2 Thermodynamics
2.3 Kinetics of Corrosion
2.4 Corrosion Evaluation and Monitoring
References
Chapter 3 Forms of Corrosion
3.1 Introduction
3.2 Uniform Corrosion
3.3 Galvanic Corrosion
3.4 Pitting Corrosion
3.5 Differential Aeration-Assisted Corrosion (Crevice, Under Deposit, and Water-Line Corrosion)
3.6 Intergranular Corrosion
3.7 Selective Dissolution/Selective Attack
3.8 Flow-Assisted/Erosion/Cavitation Corrosion
3.9 Stress Corrosion Cracking
3.10 Hydrogen Damage
3.11 Stray Current Corrosion
3.12 High Temperature Corrosion
References
Chapter 4 Materials of Construction for Chemical Process Industries
4.1 Introduction
4.2 Cast Irons
4.3 Carbon Steels
4.4 Low Alloy Steels
4.5 Stainless Steels
4.6 Nickel Base Alloys
4.7 Copper Base Alloys
4.8 Titanium
4.9 Aluminum Alloys
4.10 Nonmetallic Materials
4.11 Ceramics/Inorganic Oxide Glasses
4.12 Organic Polymers/Plastics
4.13 Materials Selection for Corrosion Prevention in Hydrocarbon Service
References
Chapter 5 Failure Analysis Procedure with Reference to Corrosion Failures
5.1 Introduction
5.2 Purpose of Failure Analysis Investigations
5.3 Failure Analysis Steps
5.4 Failure Analysis Report: Contents and Preparation
References
Chapter 6 Case Studies
6.1 Preamble
Index
End User License Agreement
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Cover
Table of Contents
Begin Reading
Figure 1.1
Figure 2.1
Figure 2.2
Figure 2.3
Figure 2.4
Figure 2.5
Figure 2.6
Figure 2.7
Figure 2.8
Figure 3.1
Figure 3.2
Figure 3.3
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Figure 3.24
Figure 4.1
Figure 4.2
Table 1.1
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Dr. K. Elayaperumal holds degrees in Metallurgical Engineering from Indian Institute of Science, Bangalore, India, and Massachusetts Institute of Technology, Cambridge, Massachusetts, USA. He has acquired vast R&D experience in the field of corrosion of metallic materials in the nuclear power industry and the related chemical process industry in his two-decade career in the Department of Atomic Energy, Government of India, Bhabha Atomic Research Centre. His advisory consultancy services in the field of analysis of corrosion failure in chemical process industries have generated a great amount of interesting case studies and brought out in this book. He is a recipient of National Metallurgist Award by Govt. of India and Life Time Achievement Award by NACE India Section.
Prof. V. S. Raja received his doctoral degree from Indian Institute of Science, Bangalore, India. He is a Professor of Corrosion Science and Engineering in the Department of Metallurgical Engineering and Materials Science and also Institute Chair Professor in the Indian Institute of Technology Bombay, India. For the past 28 years, he taught several corrosion and materials related courses, supervising about 20 doctoral students. His main research lies in understanding the interrelation between metallurgy and corrosion, especially passivity, localized corrosion, and stress corrosion cracking. He is also actively involved in solving industrial problems related to corrosion. He has received several awards for his contribution to teaching, research, and industry and is a NACE International Fellow.
In this unique book, the authors provide a concise presentation of the essence of corrosion principles with an orientation toward corrosion failures and management of corrosion to prevent failures. By appropriate design, construction, operation, and maintenance, the cost of failure can, indeed, be avoided. The book is divided into the following six chapters that are essential reading for any person concerned with the use of materials in applications where safety, integrity, and reliable, cost-effective operation are required:
Introduction: The significance of corrosion failures is described in economic and engineering terms.
Thermodynamics and kinetics of corrosion: The basic principles of corrosion are presented along with an outline of techniques for assessing the extent of corrosion in engineering installations.
Forms of corrosion: Ten basic forms of corrosion are described, including the critical controlling factors for each form. The authors present a valuable collection of photographs to illustrate the forms of corrosion.
Materials of construction for chemical process industries: An extensive discussion of the materials available is presented, along with properties on which materials selection is based. The discussion includes not only metallic materials but also nonmetals – ceramics, glasses, and polymers.
Failure analysis procedures with reference to corrosion failures: The steps involved in failure analysis are succinctly described from the perspective of developing an understanding of the cause of failure as necessary to prevent future failures.
Case studies: Eighty case studies are photographically illustrated, presented, and discussed. Each case study includes a description of the type of service involved, the specific problem, the material, observations, diagnosis, and remedy.
I am delighted to commend this book to all readers with an interest in reliable application of engineering materials, and I congratulate the authors on their success in achieving the completion of this valuable book.
R. Winston Revie
CANMET Materials Technology Laboratory
Ottawa, Ontario
Canada
Corrosion cuts across almost all industries, and the corroded components prematurely fail and/or operate at suboptimal level. It affects productivity, safety, and environments and devours nonrenewable natural resources and therefore is of great concern to society. Although industrial components do fail by other mechanisms such as mechanical overload, fatigue, creep, brittle fracture, corrosion remains the single most destruction causing the highest damage to all industrial components. For example, in chemical processing industries, corrosion of process equipment vessels and the associated piping, tubing, and utility components such as boilers, heat exchangers, and condensers is the most predominant damage-causing mechanism among the others mentioned earlier. Corrosion takes place on the inside surface of the vessels and other components because of the action of process chemicals and also on the outside surfaces because of the atmospheric moisture laden with chemical vapors and also by wet insulation materials. On the other hand, corrosion damage in aerospace and other transportation industry is relatively less, though found to be critical in life and safety and in the cost of the components. It is estimated that corrosion causes loss of about 3.5% of GNP of a nation. Hence, corrosion control becomes an important subject of science and engineering.
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