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Liquid Crystal Displays E-Book

Robert H. Chen

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Beschreibung

An unprecedented look into the basic physics, chemistry, and technology behind the LCD Most notably used for computer screens, televisions, and mobile phones, LCDs (liquid crystal displays) are a pervasive and increasingly indispensable part of our lives. Providing both an historical and a business-minded context, this extensive resource describes the unique scientific and engineering techniques used to create these beautiful, clever, and eminently useful devices. In this book, the history of the science and technology behind the LCD is described in a prelude to the development of the device, presenting a rational development theme and pinpointing innovations. The book begins with Maxwell's theory of electromagnetism, and the ultimately profound realization that light is an electromagnetic wave and an electromagnetic wave is light. The power of mathematical physics thus was brought to bear upon the study of light, and particularly the polarization of light by material bodies, including liquid crystals. After a brief historical description of polarization, a physical interpretation provides substance to the mathematical concepts. Subsequent chapters cover: * Thermodynamics for liquid crystals * The Maier-Saupe mean field, phenomenological, static continuum, and dynamic continuum theories * The transistor and integrated circuit * Glass, panels, and modules * The calculus of variations * The active matrix * Semiconductor fabrication * The global LCD business Additionally, the book illustrates how mathematics, physics, and chemistry are put to practical use in the LCDs we use every day. By describing the science from an historical perspective and in practical terms in the context of a device very familiar to readers, the book presents an engaging and unique view of the technology for everyone from science students to engineers, product designers, and indeed anyone curious about LCDs. Series Editor: Anthony C. Lowe, The Lambent Consultancy, Braishfield, UK The Society for Information Display (SID) is an international society, which has the aim of encouraging the development of all aspects of the field of information display. Complementary to the aims of the society, the Wiley-SID series is intended to explain the latest developments in information display technology at a professional level. The broad scope of the series addresses all facets of information displays from technical aspects through systems and prototypes to standards and ergonomics.

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Veröffentlichungsjahr: 2011

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Table of Contents

Cover

Wiley-SID Series in Display Technology

Title page

Copyright page

Series Editor’s Foreword

Preface

Acknowledgments

About the Author

1 Double Refraction

2 Electromagnetism

Faraday’s Intuitive Field

Maxwell’s Equations

The Derivation of

The Derivation of

The Derivation of

The Derivation of

Vector Analysis

Light Is an Electromagnetic Wave

The Light Wave

3 Light in Matter

The Electric Dipole Moment

The Lorentz–Lorenz Equation

4 The Polarization of an Electromagnetic Wave

Unpolarized Light

Elliptical, Linear, and Circular Polarization

Birefringence

Ordinary and Extraordinary Waves

Quantum Mechanical Polarization

5 Liquid Crystals

Carrots

Liquid Crystal Genealogy

The Chiral Nematic

The Ferroelectric Chiral Smectic-C

The Blue Flash

Lyotropic Liquid Crystals

The Director and the Order Parameter

Stiff But Flexible

Liquid Crystal Character

The Induced Dipole Moment

6 Thermodynamics for Liquid Crystals

The Three Laws of Thermodynamics

Phase Transitions

Entropy

The Boltzmann Distribution

The Minimization of Free Energy

7 The Calculus of Variations

The Brachistochrone Problem

Catenary and Suspension

The Euler–Lagrange Equation

Deeper Meanings of the Euler–Lagrange Equation

8 The Mean Field

Ideal Gas in Crystal Lattice

Long Rod Models

The Composite Electric Field and Average Index of Refraction

The Dipole Mean Field Is Born

9 Maier–Saupe Theory

The Nematic to Isotropic Phase Transition Calculation

Dielectric Anisotropy Calculation

Near Neighbor Correlation

10 Phenomenological Theory

The Nematic to Isotropic Phase Transition Calculation

Birefringence Calculation

11 Static Continuum Theory

Basic Principles

Static Continuum Theory Examples

The Freedericksz Cell

In Memoriam

12 Dynamic Continuum Theory

Conservation Principles

The Leslie Work Hypothesis

Turn-On Example

Hydrodynamic Instability

Conclusion

13 The First Liquid Crystal Display

Dynamic Scattering

The Liquid Crystal Display Calculator

14 Liquid Crystal Display Chemistry

The Aromatic Compounds

The Search for a Robust Display Liquid Crystal

15 The Twisted Nematic

A Twist of Fate

The Gathering Patent Storm

Watches and Calculators

16 Engineering the Liquid Crystal

Poincaré Sphere

Refractive Index Ellipsoid

Jones Vector

The Phase Retardation Parameter

The Mauguin Condition

The Gooch–Tarry Condition

Twisted Nematic Waveguiding

The Twisted Nematic Cell

17 The Active Matrix

Matrix Addressing

The Super Twisted Nematic

Active Matrix Addressing

18 New Screens

Twisted Nematic Television

Notebook Computer Screens

19 The Transistor and Integrated Circuit

The Bohr Atom

The Point Contact Transistor

The Junction Transistor

The Tyranny of Numbers

Monolithic Component Integration

Monolithic Circuit Integration

20 A Transistor for the Active Matrix

Hydrogenated Amorphous Silicon

The Field Effect Transistor

The a-Si:H Field Effect Thin-Film Transistor

21 Semiconductor Fabrication

Growing Crystals

The Planar Process

The Four-Mask Bottom Gate

22 Enhancing the Image

The Grayscale

The On/Off Ratio

The Production of Color

The CCFL Backlight and Color Filter

Field Sequential Color

The LED Backlight

Signal Processing

23 The Wider View

c-axis a-plate c-plate

Mid-Layer Tilt

Twisted Nematic Display Oblique Viewing

Negative and Positive Compensation

The Discotic Solution

Grayscale Inversion

Compensation Overview

24 Liquid Crystal Television

Vertical Alignment

Multiple-Domain Vertical Alignment

In-Plane Switching

Fringing Field Switching

Response Time

Overdrive

Flicker

25 Glass, Panels, and Modules

Glass Generations

The TFT Array Plate

The Color Filter Plate

Side Injection and One Drop Fill

Spacers

Sealing, Cutting, and Inspection

Electrostatic Damage Protection

Laser Repair

Yield

LCDModule Assembly

26 The Global LCD Business

RCA’s Legacy

Optical Imaging Systems

The Electronics Manufacturing Paradigm

Korea, the Emerging Economy Model

Taiwan’s Twin Stars

Japan’s Closed Shop

The Worldwide Financial Tsunami

Is China a Rising Liquid Crystal Star?

The Solar Cell

27 New Technologies and Products

Light Scattering

Liquid Crystal Polymer Composites

Cholesteric Bistable Reflective Displays

Ferroelectric Chiral Smectic-C Bistable Displays

Electrophoretic Paper

The Organic Light-Emitting Diode Display

The Blue Phase Display

Reflective Displays

Transflective Displays

Projection Displays

Brightness Enhancement Film

Touch Screens

3D

LCD Products

Index

Wiley-SID Series in Display Technology

Series Editor:

Anthony C. Lowe

Consultant Editor:

Michael A. Kriss

Display Systems: Design and Applications

Lindsay W. MacDonaldand Anthony C. Lowe (Eds.)

Electronic Display Measurement: Concepts, Techniques, and Instrumentation

Peter A. Keller

Reflective Liquid Crystal Displays

Shin-Tson Wuand Deng-Ke Yang

Colour Engineering: Achieving Device Independent Colour

Phil Greenand Lindsay MacDonald (Eds.)

Display Interfaces: Fundamentals and Standards

Robert L. Myers

Digital Image Display: Algorithms and Implementation

Gheorghe Berbecel

Flexible Flat Panel Displays

Gregory Crawford (Ed.)

Polarization Engineering for LCD Projection

Michael G. Robinson, Jianmin Chen,and Gary D. Sharp

Fundamentals of Liquid Crystal Devices

Deng-Ke Yangand Shin-Tson Wu

Introduction to Microdisplays

David Armitage, Ian Underwood,and Shin-Tson Wu

Mobile Displays: Technology and Applications

Achintya K. Bhowmik, Zili Li,and Philip Bos (Eds.)

Photoalignment of Liquid Crystalline Materials: Physics and Applications

Vladimir G. Chigrinov, Vladimir M. Kozenkov and Hoi-Sing Kwok

Projection Displays, Second Edition

Matthew S. Brennesholtz and Edward H. Stupp

Introduction to Flat Panel Displays

Jiun-Haw Lee, David N. Liu and Shin-Tson Wu

LCD Backlights

Shunsuke Kobayashi, shigeo Mikoshiba and Sungkyoo Lim (Eds.)

Liquid Crystal Displays: Addressing Schemes and Electro-Optical Effects, Second Edition

Ernst Lueder

Transflective Liquid Crystal Displays

Zhibing Ge and Shin-Tson Wu

Liquid Crystal Displays: Fundamental Physics and Technology

Robert H. Chen

Copyright © 2011 by John Wiley & Sons, Inc. All rights reserved

Published by John Wiley & Sons, Inc., Hoboken, New Jersey

Published simultaneously in Canada

No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/permissions.

Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages.

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Library of Congress Cataloging-in-Publication Data:

Chen, Robert H., 1947-

 Liquid crystal displays : fundamental physics & technology / Robert H. Chen.

p. cm.

 Includes index.

 ISBN 978-0-470-93087-8 (cloth)

 1. Liquid crystal displays. 2. Liquid crystal devices. I. Title.

 TK7872.L56C44 2011

 621.3815’422–dc22

2010045220

Obook ISBN 978-1-118-08435-9

ePDF ISBN 978-1-118-08433-5

ePub ISBN 978-1-118-08434-2

Series Editor’s Foreword

For once, I found it difficult to know how to begin. Writing forewords for the Wiley-SID series (this is my twentieth) is a demanding but extremely pleasurable task. In a qualitative sense this foreword is no different; it is the book that is different. Let me explain.

On reading two sample chapters of Robert Chen’s manuscript, I realized that this would be like no other book in the series. Not only was its intended scope to cover the entirety of liquid crystal display (LCD) science and technology from the fundamentals of mathematics and physics to the production of products, but it was written by an author who has not only the academic background but also the experience as an executive in several major companies to provide first-hand insight and understanding of the global development of what is now a predominantly Asia-based industry.

The author has covered his subject matter with great proficiency and style. But there is more: the book is filled with interesting footnotes, often witty, of technical or historical relevance or a combination of all three. The most significant references are cited, but this is not a book where the reader will find a comprehensive list of all relevant publications. Other books in the series which address specific aspects of the technology provide that.

The unique feature of this book is that when discussing the global industrial development of the LCD industry, the author provides an account which is unprecedented—certainly in this series—in its level of detail, its understanding of cultural influences, and its degree of frankness. I believe that few will disagree with his arguments, but some will find it uncomfortable reading.

So, as the author aspires, this book may be read at several different levels. Anyone who reads it will find it rewarding as a technical introduction to the field replete with a sense of history. They will realize that this industry, which has made most of its growth in the last two decades, is built on the shoulders of scientific progress going back two centuries. Last, but certainly not least, I hope that they will find it a first-rate literary experience.

Anthony C. Lowe

Series Editor

Braishfield, UK

Preface

The liquid crystal display (LCD) has become the principal modern medium for visual information and image appreciation. It is now a pervasive and increasingly indispensable part of our everyday lives. Apart from its utility, this marvelous device relies on a science and technology that I believe makes the device all the more attractive and interesting.

This book is organized to highlight the basic physics, chemistry, and technology behind this intriguing product, and while describing the LCD, I attempt to provide some insight into that physics, chemistry, and technology. I believe that the history of the development of the LCD is equally intriguing, and thus I make excursions into tales of the principal contributors and their achievements and thinking in their research. Finally, the allure of liquid crystal television has made it a coveted symbol of modern life worldwide, and so apart from the technical descriptions, I also describe how the LCD business has become a global enterprise.

I attempt to describe the physics and technology in a clear and simple manner understandable to an educated reader. Further, I have endeavored to pay attention to literary exposition as far as I am able, in the hope that, in addition to describing the technology, the book may also provide some literary enjoyment. Of course whether I have succeeded here depends on the reader’s assessment.

This book is written at an introductory level suitable for advanced undergraduates and first-year graduate students in physics and engineering, and as a reference for basic concepts for researchers. I also have tried to make the scientific and technical descriptions intuitively clear so that any educated person who has studied calculus can easily understand the exposition and thereby understand and appreciate liquid crystal displays and the science behind them.

Readers new to the field should read this book in chapter sequence to understand the gradual development of the LCD and the science and engineering involved; advanced researchers and practitioners can select the chapters and sections to find descriptions of the background of those selected topics.

Robert H. Chen

Taipei, Taiwan

June 2011

Acknowledgments

I would like to thank Professor Paul Nahin, for his books on mathematics and engineering from which I learned a great deal and borrowed liberally, and for his kind encouragement; Simone Taylor, Editorial Director at Wiley, who saw the potential of the manuscript and undertook the task of getting this book published while guiding me along the way; and most gratefully Dr. Anthony C. Lowe, the Editor of the Wiley-SID Series, who corrected mistakes and blocked metaphors (I am of course solely responsible for any that have gotten through). Further thanks are due to my wife Fonda, for her patient understanding; my daughter Chelsea, for cheerful enthusiasm; and my cat Amao, for accompanying me all the while. For my technical education, I would like to thank Dr. Hsu Chenjung, whose intelligence inspired me; Professor Andrew Nagy of Michigan and Professor Von Eshleman of Stanford, who supported me; and Chimei Optoelectronics Corporation where I learned about LCDs. Many of the drawings were done by Ingrid Hung at Chimei and Tsai Hsin-Huei of the National Taiwan University of Art.

About the Author

Robert Hsin Chen

Robert Hsin Chen is an adjunct professor at National Taiwan University and also teaches at Tsinghua and Jiaotong Universities in Taiwan. He was formerly a Senior Vice-President at Chimei Optoelectronics, a Director at Taiwan Semiconductor Manufacturing Company, Vice-President at Acer Corporation, and Of Counsel at the law firm Baker & McKenzie. Dr. Chen has a PhD from the University of Michigan (Space Physics Research Lab), a postdoctorate from Stanford University (Center for Radar Astronomy), and a JD from the University of California at Berkeley. He is a member of many scientific organizations, as well as the California Bar, and is a registered patent attorney; he has written many articles for international scientific and intellectual property journals, and is the author of Made in Taiwan (1997) and Crystals, Physics, and Law (in Chinese, 2010).

1

Double Refraction

The operation of liquid crystal displays is founded on the phenomenon of the double refraction of light as first recorded in Denmark by Erasmus Bartholinus in 1670. A piece of translucent calcite apparently divides incident light into two streams, producing a double image. This is depicted in Figure 1.1, as shown by the offset of the word “calcite.” At about the same time in the Netherlands, Christian Huygens discovered that the light rays through the calcite could be extinguished by passing them through a second piece of calcite if that piece were rotated about the direction of the ray; this is depicted in Figure 1.2. This may be observed by taking two pairs of polarizing sunglasses and rotating them relative to each other.

Figure 1.1 Double refraction in calcite.

From http://www.physics.gatech.edu/gcuo/lectures.

Figure 1.2 Two pieces of calcite at an angle.

From http://www.physics.gatech.edu/gcuo/lectures.

One hundred and thirty-eight years later, in 1808, a protégé of the famous French mathematician Fourier, Etienne Louis Malus, observed that light reflected from a window, when passing through a piece of calcite also would change intensity as the calcite was rotated, apparently showing that reflected light was also altered in some way. The intensity of the light changed in both cases because the molecules of calcite have a crystal order that affects the light in an intricate but very understandable way called polarization.

It would be another 80 years later in Austria that double refraction, also called birefringence, and light polarization would be observed, not in crystalline rocks, but in a viscous liquid, later to be called a “liquid crystal.” Although no doubt intriguing to natural scientists, intensive investigation of liquid crystals had to wait for yet another 80 years, when commercial interests provided the impetus for further study.

Briefly, a liquid crystal display can reproduce an image of a scene through the use of a video camera that, upon receiving the light reflected from the scene through its lens, in accord with the photoelectric effect first explained by Einstein, an electric current is generated in a metal when struck by light of sufficient energy, the current being proportional to the intensity of that light. That current is then transmitted to transistors that control an analog voltage that is applied to a pair of transparent electrode plates. Those plates enclose a thin layer of liquid crystal between them, and the voltage on the plates generates an electric field that is used to control the orientation of the electric dipole moment of the liquid crystal molecules, causing them to turn. Then light from a light source placed behind the liquid crystal layer, after being linearly polarized by a polarizer, will have its polarization states altered by the different orientations of the liquid crystal molecules, in accord with the liquid crystal’s degree of birefringence. The beauty of the liquid crystal display is that the birefringence effected by a liquid crystal is precisely controllable by that electric field. The different polarization states of the light in conjunction with a second polarizer changes the brightness of the light emanating from the backlight source, and that modulated brightness can represent the light intensity of the original scene; the millions of picture elements so produced then combine to form an image that replicates the original scene.

Liquid crystal displays thus are based on an optical phenomena of electrically controlled birefringence and polarization, which can only be understood through knowledge of the interaction of light and matter.

However, light may be familiar to everybody, but Samuel Johnson succinctly observed that [1]*

We all know what light is, but it is not easy to tell what it is.

The understanding of light can gainfully begin at the outset with an appreciation of light as described by the Maxwell equations.

Note

* Samuel Johnson (1709–1784), English lexicographer, critic, poet, and moralist who completed the Dictionary of the English Language in 1755; Johnson is one of the preeminent authorities on the English language.

Reference

[1] Johnson, S. 1755. Boswell’s Life; Dictionary of the English Language; quoted in Clegg, B. 2001. Light Years. Piatkus, London.