X-Ray Fluorescence in Biological Sciences E-Book

Vivek K. Singh

• Herausgeber: John Wiley & Sons
• Kategorie: Wissenschaft und neue Technologien
• Sprache: Englisch

Seitenzahl: 1493

Veröffentlichungsjahr: 2022

Beschreibung

X-Ray Fluorescence in Biological Sciences Discover a comprehensive exploration of X-ray fluorescence in chemical biology and the clinical and plant sciences In X-Ray Fluorescence in Biological Sciences: Principles, Instrumentation, and Applications, a team of accomplished researchers delivers extensive coverage of the application of X-ray fluorescence (XRF) in the biological sciences, including chemical biology, clinical science, and plant science. The book also explores recent advances in XRF imaging techniques in these fields. The authors focus on understanding and investigating the intercellular structures and metals in plant cells, with advanced discussions of recently developed micro-analytical methods, like energy dispersive X-ray fluorescence spectrometry (EDXRF), total reflection X-ray fluorescence spectrometry (TXRF), micro-proton induced X-ray emission (micro-PIXE), electron probe X-ray microanalysis (EPXMA), synchrotron-based X-ray fluorescence microscopy (SXRF, SRIXE, or micro-XRF) and secondary ion mass spectrometry (SIMS). With thorough descriptions of protocols and practical approaches, the book also includes: * A thorough introduction to the historical background and fundamentals of X-ray fluorescence, as well as recent developments in X-ray fluorescence analysis * Comprehensive explorations of the general properties, production, and detection of X-rays and the preparation of samples for X-ray fluorescence analysis * Practical discussions of the quantification of prepared samples observed under X-ray fluorescence and the relation between precision and beam size and sample amount * In-depth examinations of wavelength-dispersive X-ray fluorescence and living materials Perfect for students and researchers studying the natural and chemical sciences, medical biology, plant physiology, agriculture, and botany, X-Ray Fluorescence in Biological Sciences: Principles, Instrumentation, and Applications will also earn a place in the libraries of researchers at biotechnology companies.

Leseprobe

X‐Ray Fluorescence in Biological Sciences

Principles, Instrumentation, and Applications

Edited by

Vivek Kumar Singh

University of Lucknow

Lucknow, India

Jun Kawai

Kyoto University

Kyoto, Japan

Durgesh Kumar Tripathi

Amity University

Noida, Uttar Pradesh, India

This edition first published 2022© 2022 John Wiley & Sons Ltd

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Library of Congress Cataloging‐in‐Publication Data applied for

ISBN: 9781119645542 (Hardback); 9781119645665 (Adobe PDF); 9781119645580 (epub)

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List of Contributors

Tsenddavaa AmartaivanDepartment of PhysicsSchool of Arts and SciencesNational University of MongoliaUlaanbaatarMongoliaandNuclear Research CenterNational University of MongoliaUlaanbaatarMongolia

Evren Algın YaparAnalysis and Control Laboratories DepartmentTurkish Medicines and Medical Devices AgencyMoHAnkaraTurkey

Iztok ArcŏnDepartment for Low and Medium Energy PhysicsJožef Stefan InstituteLjubljanaSloveniaandLaboratory of Quantum OpticsUniversity of Nova GoricaNova GoricaSlovenia

Sandeep AroraChitkara College of PharmacyChitkara UniversityPunjabIndia

Volkan AylikciCenter for Science and Technology Studies and ResearchIskenderun Technical University‐ISTEHatayTurkeyandDepartment of Metallurgical and Material Science EngineeringIskenderun Technical University–ISTEHatayTurkey

Ersin BahceciCenter for Science and Technology Studies and ResearchIskenderun Technical University‐ISTEHatayTurkeyandDepartment of Metallurgical and Material Science EngineeringIskenderun Technical University–ISTEHatayTurkey

Sait A. BakhteevDepartment of Analytical ChemistryCertification and Quality ManagementKazan National Research Technological UniversityKazanRussia

Damdinsuren BolortuyaNuclear Research CenterNational University of MongoliaUlaanbaatarMongolia

Marco CarminatiDipartimento di ElettronicaInformazione e BioingegneriaPolitecnico di MilanoMilanoItalyandIstituto Nazionale di Fisica Nucleare (INFN), MilanoMilanoItaly

Shilpa ChakrabartiBiochemistry DepartmentUniversity of AllahabadPrayagrajIndia

Mansi ChitkaraChitkara UniversityInstitute of Engineering and TechnologyChitkara UniversityPunjabIndia

E.V. ChuparinaVinogradov Institute of GeochemistrySB RASIrkutskRussian Federation

Tolga DepciDepartment of Petroleum and Natural Gas EngineeringIskenderun Technical University–ISTEHatayTurkey

Sangita DharaFuel Chemistry DivisionBhabha Atomic Research CentreMumbaiIndiaandHomi Bhabha National InstituteMumbaiIndia

F.I. El‐AgawanyDepartment of PhysicsFaculty of ScienceMenoufia UniversityShebin El‐KoomMenoufiaEgypt

Neslihan EkinciDepartment of PhysicsFaculty of ScienceAtaturk UniversityErzurumTurkey

Ma Fernanda Gazulla BarredaInstitute of Ceramic Technology‐Ceramic Industries Research AssociationJaume I. Castellón UniversityCastellón de la PlanaSpain

Carlo FioriniDipartimento di ElettronicaInformazione e BioingegneriaPolitecnico di MilanoMilanoItalyandIstituto Nazionale di Fisica Nucleare (INFN), MilanoMilanoItaly

Anju GoyalChitkara College of PharmacyChitkara UniversityPunjabIndia

Kamya GoyalLaureate Institute of PharmacyKathog, Jawalamukhi, KangraHimachal PradeshIndiaandChitkara College of PharmacyChitkara UniversityPatialaPunjabIndia

Miriam GrenónFaculty of DentistryNational University of CórdobaCórdobaArgentina

Yukie IzumotoNational Institute of Radiological ScienceNational Institutes for Quantum Science and TechnologyInage‐kuChibaJapan

Brijbir S. JaswalDepartment of PhysicsUniversity of LucknowLucknowUttar PradeshIndia

Héctor Jorge SánchezFaculty of Mathematics, Physics, Astronomy, and Computer ScienceNational University of CórdobaCórdobaArgentinaandInstituto de Física Enrique GaviolaCONICETCórdobaArgentina

Abdelhalim KahoulDepartment of Materials ScienceFaculty of Sciences and TechnologyMohamed El Bachir El Ibrahimi UniversityBordj‐Bou‐ArreridjAlgeriaandLaboratory of Materials PhysicsRadiation and Nanostructures (LPMRN)Mohamed El Bachir El Ibrahimi UniversityBordj‐Bou‐ArreridjAlgeria

Navgeet KaurChitkara College of PharmacyChitkara UniversityPunjabIndiaandSwami Devi Dyal Institute of PharmacyPanchkulaHaryanaIndia

Rajwinder KaurChitkara College of PharmacyChitkara UniversityPatialaPunjabIndia

Arashmeet KaurChikara College of PharmacyChikara UniversityPunjabIndia

Esra KavazDepartment of PhysicsFaculty of ScienceAtaturk UniversityErzurumTurkey

Jun KawaiDepartment of Materials Science and EngineeringKyoto UniversitySakyo‐kuKyotoJapan

Dmitry KirsanovInstitute of ChemistrySt. Petersburg State UniversitySaint PetersburgRussia

Alojz KodreDepartment for Low and Medium Energy PhysicsJožef Stefan InstituteLjubljanaSloveniaandFaculty for Mathematics and PhysicsUniversity of LjubljanaLjubljanaSlovenia

Manish KumarChikara College of PharmacyChikara UniversityPunjabIndia

Pradeep KumarDepartment of Pharmaceutical Sciences and Natural ProductsCentral University of PunjabBathindaIndia

Vivek Kumar SinghDepartment of PhysicsUniversity of LucknowLucknowUttar PradeshIndia

Peter KumpDepartment for Low and Medium Energy PhysicsJožef Stefan InstituteLjubljanaSlovenia

Nuray Kup AylikciDepartment of Engineering SciencesIskenderun Technical University–ISTEHatayTurkeyandInstitute of Graduate StudiesDepartment of Energy SystemsEngineeringIskenderun Technical University–ISTEHatayTurkeyandCenter for Science and Technology Studies and ResearchIskenderun Technical University‐ISTEHatayTurkey

Changling LaoGuilin University of TechnologyGuilinChinaandNational Research Center of GeoanalysisBeijingChinaandChina University of Geosciences (Beijing)BeijingChina

Jian LiuCollege of Environmental Natural Resource SciencesZhejiang Provincial Key Laboratory of Agricultural Resources and EnvironmentZhejiang UniversityHangzhouChina

Liqiang LuoNational Research Center of GeoanalysisBeijingChina

Artem S. MaltsevCenter for Geodynamycs and GeochronologyInstitute of the Earth’s CrustSB RASIrkutskRussiaandDepartment of Analytical ChemistryCertification and Quality ManagementKazan National Research Technological UniversityKazanRussia

Eva MarguíDepartment of ChemistryUniversity of GironaGironaSpain

Devinder MehtaDepartment of PhysicsPanjab UniversityChandigarhIndia

N.L. MishraFuel Chemistry DivisionBhabha Atomic Research CentreMumbaiIndiaandHomi Bhabha National InstituteMumbaiIndia

Yeasmin Nahar JollyAtmospheric and Environmental Chemistry LaboratoryChemistry Division, Atomic Energy CentreBangladesh Atomic Energy CommissionDhakaBangladesh

Marijan NečemerDepartment of Low and Medium Energy PhysicsJožef Stefan InstituteLjubljanaSlovenia

Mónica Orduña CorderoInstitute of Ceramic Technology‐Ceramic Industries Research AssociationJaume I. Castellón UniversityCastellón de la PlanaSpain

Onder OrucInstitute of Graduate StudiesDepartment of Energy Systems EngineeringIskenderun Technical University–ISTEHatayTurkey

Vitaly PanchukInstitute of ChemistrySt. Petersburg State UniversitySaint PetersburgRussia

Galina V. PashkovaInstitute of the Earth’s CrustSB RASIrkutskRussia

Paula PongracDepartment of BiologyBiotechnical FacultyUniversity of LjubljanaLjubljanaSloveniaandDepartment for Low and Medium Energy PhysicsJožef Stefan InstituteLjubljanaSlovenia

Sanjiv PuriDepartment of Basic and Applied SciencesPunjabi UniversityPatialaIndia

Ignasi QueraltInstitute of Environmental Assessment and Water ResearchIDAEA‐CSICBarcelonaSpain

Kanishka RawatApplied Nuclear Physics DivisionSaha Institute of Nuclear PhysicsKolkataWest BengalIndia

Anatoly G. RevenkoInstitute of the Earth’s CrustSB RASIrkutskRussian Federation

Inderjeet S. SandhuChitkara UniversityInstitute of Engineering and TechnologyChitkara UniversityPunjabIndia

Valentin SemenovInstitute of ChemistrySt. Petersburg State UniversitySaint PetersburgRussia

Neha SharmaDepartment of PhysicsUniversity of LucknowLucknowUttar PradeshIndiaandSchool of PhysicsShri Mata Vaishno Devi UniversityKatraJammu and KashmirIndia

Darya S. SharykinaInstitute of the Earth’s CrustSB RASIrkutskRussian Federation

Yating ShenNational Research Center of GeoanalysisBeijingChina

Rakesh K. SindhuChitkara College of PharmacyChitkara UniversityRajpuraPunjabIndiaandSwami Devi Dyal Institute of PharmacyPanchkulaHaryanaIndia

Harinderjit SinghAdesh Institute of Pharmacy & Biomedical SciencesAdesh UniversityBathindaPunjabIndia

Harpreet Singh KainthDepartment of Basic and Applied SciencesPunjabi UniversityPatialaIndia

Tejbir SinghDepartment of CIL/SAIFPanjab UniversityChandigarhIndia

Gurjeet SinghDepartment of PhysicsPunjabi UniversityPatialaIndia

M. SudarshanUGC‐DAE Consortium for Scientific ResearchKolkataIndia

M.K. TiwariSynchrotrons Utilization SectionRaja Ramanna Centre for Advanced Technology (RRCAT)IndoreIndia

V.A. TrunovaNikolaev Institute of Inorganic Chemistry SB RASNovosibirskRussia

Onkar N. VermaDepartment of PhysicsUniversity of LucknowLucknowUttar PradeshIndia

Inderjeet VermaM.M. College of PharmacyMM(DU)Mullana‐AmbalaIndia

Katarina Vogel‐MikušDepartment of Low and Medium Energy PhysicsJožef Stefan InstituteLjubljanaSloveniaandDepartment of BiologyBiotechnical FacultyUniversity of LjubljanaLjubljanaSlovenia

Neera YadavCollege of PharmacyGachon University of Medicine and ScienceIncheon CitySouth Korea

Shantanu K. YadavChikara College of PharmacyChikara UniversityPunjabIndia

Hiroshi YoshiiNational Institute of Radiological ScienceNational Institutes for Quantum Science and TechnologyChibaJapan

Jing YuanEast China Center for Geoscience InnovationNanjing Center of Geological SurveyChina Geological SurveyNanjingChina

Rafail A. YusupovDepartment of Analytical ChemistryCertification and Quality ManagementKazan National Research Technological UniversityKazanRussia

Shuai ZhuNational Research Center of GeoanalysisBeijingChina

Purev ZuzaanNuclear Research CenterNational University of MongoliaUlaanbaatarMongolia

Preface

X‐ray fluorescence (XRF) spectroscopy is a well‐established analytical technique being used extensively for mining, metallurgy, petroleum, and geological studies, though not widely used for biological applications. During the past decade, XRF spectrometry has gone through major changes in the field of biological sciences. This book is a guide which provides an up‐to‐date review of XRF spectrometry for biological, medical, food, environmental, and plant science researchers. It covers the basic principles and latest developments in instrumentation and applications of X‐ray fluorescence in biological sciences. This also provides a thoroughly updated and expanded overview to industry professionals in X‐ray analysis over the last decades. The main feature of this book is that it provides information about XRF techniques and procedures for qualitative and quantitative analysis of biological specimens worth modern applications and industrial trends.

The chapters are contributed by independent groups in the world. Four chapters are contributed by the members of editorial advisory board of the journal “X‐Ray Spectrometry” from Wiley. The chapters are divided into six parts. Part 1 is a general introduction of XRF. Parts 2 and 3 are most advanced methods of SR‐XRF and TXRF, which are micro‐XRF, high sensitivity (low detection limit) XRF. Part 4, a beginner’s guide, is one of the characteristics of the present book. Parts 5 and 6 are the main parts of the present book.

Part I (General Introduction) consists of seven (07) chapters. Chapter 1 describes about the XRF and comparison with other analytical methods such as AAS, ICP‐AES, LA‐ICP‐MS, IC, LIBS, SEM‐EDS, and XRD. Chapter 2 highlights the significant role of different XRF configurations for both multi‐elemental bulk analysis and element distribution within vegetal tissues. In Chapter 3, the application of XRF analysis is described for the chemical compositions of tea and coffee samples. Chapter 4 deals with total reflection X‐ray fluorescence (TXRF) spectrometry and its suitability for biological samples. In this chapter, the fundamentals, basic principles, and theoretical aspects of TXRF have been discussed along with its advantages and limitations. Chapter 5 describes the use and application of μ‐XRF and XANES to understand the interaction process and mechanism between microorganisms and heavy metal. Chapter 6 covers the details of EDXRF techniques for the application to clinical samples such as blood and hair. In Chapter 7, all considerations related with the sample preparation process are summarized which is very crucial for XRF analysis.

Part II (Synchrotron Radiation XRF) consists of five (05) chapters which show how Synchrotron Radiation XRF (SRXRF) can be used to provide analytical information in biological sciences for elemental composition. Chapter 8 covers numerous aspects of SRXRF and its applications. This chapter highlights the usefulness of XRF technique for the elemental characterization of different sample matrixes in non‐destructive manners. Chapter 9 deals with the application of SR‐based micro‐XRF spectroscopy for plants. Chapter 10 covers the application of μ‐XRF to study toxic elements in plants. Chapter 11 highlights the application of micro‐XRF for the analysis of benthonic fauna (earthworm and nematodes) in soils and sediments. Chapter 12 discusses in detail the use of SRXRF for the analysis of microelements in biopsy tissues.

Part III (Total Reflection XRF) consists of four (04) chapters which describe in detail the principles and basic fundamentals of total reflection XRF (TXRF) along with their biological applications. Chapter 13 covers the applications of TXRF for the trace element determinations in marine organisms, blood samples, saliva and oral fluids, hairs, nails, kidney stones, urine samples, and forensic samples. Chapter 14 demonstrates the applications of combined X‐ray reflectivity(XRR) andgrazing incidence X‐ray fluorescence (GIXRF) technique for the characterization of thin films and nano‐structured materials. Chapter 15 deals with the analysis of alcoholic and non‐alcoholic beverages by TXRF. Chapter 16 describes the details of using TXRF and XRT techniques for trace elemental analysis of blood and serum samples.

Part IV (Beginner's Guide) consists of four (04) chapters which cover the basics theory of XRF and historical fundamentals of XRF instruments, quantitative analysis methods, electronics and instrumentation, methods of using XRF to study biological samples. Chapter 17 introduces the atomic physics of the XRF spectrometry which is very useful for beginners to learn for its applications. Chapter 18 includes general principles, production, and detectors of X‐ray waves. Chapter 19 introduces general discussion on quantitative analysis methods and procedures which is the principal subject of XRF spectroscopy. Chapter 20 deals with the crucial aspects concerning the operation and optimization of electronics for X‐ray detection and fluorescence spectrometry.

Part V (Application to Biological Samples) consists of eleven (11) chapters which include the different biological applications of XRF spectrometry. Chapter 21 highlights the theoretical basics of the EDXRF followed by some relevant case studies such as elemental profiling for ionomic studies and food authenticity studies. Chapter 22 deals the application of XRF including TXRF to milk and dairy products. Chapter 23 includes the literature review on the elemental concentration analysis of medical plants using XRF technique. Chapter 24 deals with the application of XRF in animal and human cell biology. Chapter 25 covers a variety of biomedical applications using XRF spectrometry. Chapter 26 describes the usefulness of XRF technique to analyze uranium (U) in blood extracted from wounds. Chapter 27 highlights the use of XRF for the analysis of human hair. Chapter 28 discusses the potential utility of XRF methods to analyze different kinds of biological samples such as calcified/dental tissues, gallbladder and kidney stones, hair, nails, blood, urine, and clinical samples. Chapter 29 describes the principles of using WDXRF for the chemical analysis of plant samples. Chapter 30 covers the use and application of XRF in medicinal biology. Chapter 31 describes in details the use of XRF in pharmacology.

Part VI (Special Topics and Comparison with Other Methods) consists of eight (08) chapters. This section includes some chapter based on special topics and comparisons of XRF with other techniques. Chapter 32 describes the XRF technique and state‐of‐the‐art related techniques specifically as they regard the study of teeth, tartar, and oral tissues. Chapter 33 describes in details the principles, theory and applications of WDXRF spectrometry. Chapter 34 describes the chemometric processing of XRF data which is one of the most important steps in XRF spectrometry. Chapter 35 briefly describes the applications of X‐ray crystallography in medicinal biology. Chapter 36 describes the historical fundamentals of X‐ray instruments and present trends in the field of biological science. Chapter 37