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The 81st Conference on Glass Problems (GPC) was organized by the Kazuo Inamori School of Engineering, The New York State College of Ceramics, Alfred University, Alfred, NY 14802 and The Glass Manufacturing Industry Council (GMIC), Westerville, OH 43082. The Program Director was S. K. Sundaram, Inamori Professor of Materials Science and Engineering, Kazuo Inamori School of Engineering, The New York State College of Ceramics, Alfred University, Alfred, NY 14802. The Conference Director was Bob Lipetz, Executive Director, Glass Manufacturing Industry Council (GMIC), Westerville, OH 43082. The GPC Advisory Board (AB) included the Program Director, the Conference Director, and several industry representatives. The Board assembled the technical program. Donna Banks of the GMIC coordinated the events and provided support. Due to world-wide COVID-19 pandemic, the conference was a virtual event. It started with a full-day plenary session followed by technical sessions.

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Table of Contents

Cover

Title Page

Copyright

Foreword

Preface

Acknowledgements

PLENARY

SURFACE VISCOSITY AND THE MELTING OF GLASS

ABSTRACT

GLASS FURNACE CORROSION

OBSERVED END OF LIFE FURNACE JOINT CORROSION

CORROSION AT THREE PHASE INTERFACES

SURFACE VISCOSITY

GLASS VISCOSITY

MODEL AND EQUATION

EQUATION DEVELOPMENT

STRUCTURAL RELAXATION

NETWORK BONDING

INTERNETWORK BONDING

FIT TO GLASS VISCOSITY

STRUCTURAL RELEVANCE OF PARAMETERS

SURFACE VISCOSITY

APPLICATION TO FURNACE CORROSION

CONCLUSIONS

ACKNOWLEDGEMENTS

REFERENCES

CONSTRUCTION AND REPAIR

SUPPORTING HOT AND COLD FURNACE REPAIRS

ABSTRACT

INTRODUCTION

EQUIPMENT USED

ADDITIONAL APPLICATIONS

REFERENCES

INFRASTRUCTURE AND PROCESS CONSIDERATIONS WHEN INCREASING THE SIZE OF YOUR FURNACE

ABSTRACT

INTRODUCTION

BUDGET ISSUES WITH LARGE CAPITAL PROJECTS

US GLASS MARKET CAPITAL EXPENDITURES

CAPITAL PROJECT SCENARIO

CONCLUSIONS AND RECOMMENDATIONS

REFERENCES

ANALYSIS OF EXPERIENCES IN RECURRING FURNACE CONSTRUCTION PROJECTS

ABSTRACT

INTRODUCTION

RESEARCH METHOD

RECOGNITION AND FIELD IMMERSION

DATA COLLECTION AND ANALYSIS

PHENOMENON DESCRIPTION

RFCP MANAGEMENT MODEL PROPOSAL

CONCLUSIONS

REFERENCES

MELTING

IMPROVED GLASS HOMOGENEITY AND HIGHER SUSTAINABILITY THROUGH TEXTURED EXPENDABLES TUBES IN CONTAINER GLASS FURNACE

ABSTRACT

TEXTURED EXPENDABLE TUBES – ROLE AND BENEFITS

INDUSTRIAL MEASUREMENTS OF GOBS PROPERTIES

CONCLUSION

EXTENDING CAMPAIGN LIFE IN AN ALL‐ELECTRIC MELTER USING HIGH LEVELS OF COMMERCIAL CULLET

ABSTRACT

INTRODUCTION

THE VALUE OF LONGER MELTER CAMPAIGNS

TECHNICAL APPROACH

CULLET TRIALS

RESULTS SUMMARY

SUMMARY

REFERENCES

CASE STUDY: COMPARISON OF AN AC IGBT CONTROLLED SYSTEM AND AC PHASE ANGLE SCR CONTROLLED SYSTEM IN A RESISTANCE HEATING APPLICATION

THE CHALLENGE

BACKGROUND AND DEFINITIONS

SETUP

TESTING RESULTS

COMPARISON

RESULTS AND CONCLUSIONS

CONCLUSIONS

FROM LANDFILL TO RAW MATERIAL: OBTAINING HIGH QUALITY RECYCLED CULLET TO AVOID GLASS MANUFACTURING PROBLEMS

ABSTRACT

HISTORY OF GLASS RECYCLING IN THE NETHERLANDS

THE RECYCLING PROCESS

THE INSPECTION PROCESS

IMPROVEMENTS IN CULLET QUALITY

FURTHER DEVELOPMENTS

CONCLUSIONS

REFERENCES

QUALITY CONTROL AND SENSORS

GLASS MELT QUALITY OPTIMIZATION BY MATHEMATICAL MODELING OF REDOX AND BUBBLES IN THE GLASS MELT

ABSTRACT

INTRODUCTION

REDOX CHEMISTRY OF CONTAINER GLASSES WITH CHROMIUM

REDOX REACTIONS UNDER REDUCING CONDITIONS

REDOX REACTIONS IN THE FULL 3D MODEL

BUBBLE PREDICTION IN THE FULL 3D MODEL

APPLICATION OF THE MODEL IN AN INDUSTRIAL SITUATION

CONCLUSIONS

REFERENCES

THE DETECTION AND ROOT CAUSES OF CORD IN GLASS

ABSTRACT

INTRODUCTION

ROOT CAUSES OF CORD

CASE STUDIES

DETECTION OF CORD

ABRADED THERMAL SHOCK TESTING

CONCLUSION

ACKNOWLEDGEMENTS

REFERENCES

FLOAT GLASS FLATNESS: PROCESS CONSEQUENCES, AND HOW TO IMPROVE CONTROL

EFFICIENT FLOAT GLASS INSPECTION IN A MATTER OF SECONDS: 3D MEASUREMENT FOR TOP‐QUALITY LARGE GLASS

3D MEASUREMENT PROVIDES DATA FOR COMPREHENSIVE PROCESS OPTIMIZATION

POTENTIAL OF FLOAT GLASS INSPECTION FOR INNOVATIVE INDUSTRY SECTORS

CONCLUSION

ENVIRONMENT AND SUSTAINABILITY

WASTE HEAT RECOVERY IN OXY‐FUEL GLASS FURNACES –A PATH TO SUSTAINABILITY AND LOWER CO

2

EMISSIONS

INTRODUCTION

FUTURE OF OXY‐FUEL GLASS MELTING

BATCH AND/OR CULLET PREHEATING

THERMO‐CHEMICAL REGENERATOR SYSTEM (TCR) TECHNOLOGY

ACHIEVING FULL HEAT RECOVERY

BRIDGE TO FUTURE WITH GREEN H

2

SUMMARY

REFERENCES

End User License Agreement

List of Tables

Chapter 1

Table 1 Comparison of predictions

Chapter 2

Table 1 Target vs. actual temperatures

Chapter 3

Table 1 Typical Container Glass Process Fan Lineup

Chapter 4

Table 1 Study group

Table 2 Documents and analysis units count

Table 3 Coding syntaxis for analysis units

Table 4 Code list

Chapter 6

Table 1 Cost Effect of Extending Melter Campaign

Table 2 Manganese Dioxide Reactions and Oxygen Release2

Table 3 Project Glass Temperature Reductions

Chapter 10

Table 1 Comparing outcomes of stress birefringence measurements and abraded t...

Chapter 12

Table 1 List of commercial references for Batch and Cullet Preheating from Jo...

List of Illustrations

Chapter 1

Figure 1 Photo of AZS sidewall at furnace end of life

Figure 2 Image of furnace surface created from laser dot mapping. Left is fr...

Figure 3 Corrosion at the joints as seen from the back and bottom of the fur...

Figure 4 Expected convective currents

Figure 5 Observed corrosion shape at metal line.

Figure 6 Observed corrosion patterns for upward drilling, downward drilling,...

Figure 7 Glass transition temperature as a function of crosslinking in Ge‐Sb...

Figure 8 Silicon tetrahedra in a four coordinated state and in a two coordin...

Figure 9 Representation of Strength and Number of Ionic and Covalent Bonds a...

Figure 10 Region of Composition Studied. Al (+Fe) (not shown) varied from 0....

Figure 11 Prediction vs best fit values of To

Figure 12 Prediction vs best fit values for E

Figure 13 Bulk and estimated surface viscosity curves calculated for a SLS g...

Figure 14 Photo of downward drilling with a mixed metal droplet in contact w...

Figure 15 AZS coupon extending 9 mm above glass melt

Figure 16 AZS coupon extending 3 mm above glass melt

Chapter 2

Figure 1 200 Degree range for sharper image

Figure 2 B&W gives the highest “visible” contrast

Figure 3 Rainbow Palette shows the highest thermal contrast

Figure 4 1.5* Zoom for closer inspection

Figure 5 2* Zooms shows extent of the holes/damage

Figure 6 First ever view of welding

Figure 7 Utilising isotherms to see the port flame temperatures and correspo...

Figure 8 2*Zoon END R‐L same isotherms

Figure 9 4*zoom Re Range Isotherms

Figure 10 +45 minutes

Figure 11 +90 minutes

Figure 12 Slide from 2019 Glass Problems ‐ Comparison with static 5 Deg

Figure 13 Three weeks later – Drain started – Auto temp range

Figure 14 End firing L‐R – Manual temp range 1575‐1425°C

Figure 15 End firing R‐L – 1.5 Zoom on wall to be re‐used‐Manual temp range ...

Figure 16 End firing R‐L – 1.5 Zoom on wall to be re‐used‐Manual temp range ...

Figure 17 + 4 hours ‐ End firing R‐L – 1.5 Zoom on wall to be re‐used‐Manual...

Figure 18 + 4 hours ‐ End firing R‐L – 1.5 Zoom on wall to be re‐used‐Manual...

Figure 19 + 4 hours ‐ End firing R‐L – 1.5 Zoom on wall to be re‐used‐Manual...

Figure 20 + 8 hours ‐ End firing R‐L – Auto temp range Polygons of interest ...

Figure 21 + 8 hrs End firing R‐L – Manual temp range (‐160) 1415‐1265°C Poly...

Figure 22 + 20 hrs End firing R‐L – Auto temp range Polygons of Interest by ...

Figure 23 + 20 hrs End firing R‐L – Manual temp range (‐425) 1150‐1000°C Pol...

Figure 24 + 24 hrs End firing R‐L – Manual temp range (‐475) 1100‐1000°C Pol...

Figure 25 Additive at RHS peephole – Premix burner

Figure 26 The last port flame 1050‐1000°C

Figure 27 Next frame

Figure 28 +36 hrs – Below 1000°C Range

Figure 29 + 48 hrs

Figure 30 +60 hrs – Regenerator ports

Chapter 3

Figure 1 Core Sample From Testing of Mat Slab

Figure 2 New Mat Slab & Support Steel

Figure 3 Deteriorated Furnace Support Column

Figure 4 Existing Support Steel with 7 Layers of Beams

Chapter 4

Figure 1 Research method with an empirical phenomenological design

Figure 2 Selection of analysis units and coding in Atlas.ti

Figure 3 Additional work network

Chapter 5

Figure 1 Operating Vortex tube

Figure 2 Comparison between a standard tube after 6 months of operation (lef...

Figure 3 Gobs thermal signature acquired using a thermal camera (left) and p...

Figure 4 Evolution of front & back gobs average temperature in time.

Figure 5 Determination method for Feret diameters.

Figure 6 Evolution of front and back gobs dimensions in time.

Chapter 6

Figure 1 Sidewall temperature contour (top) and plotted temperatures (bottom...

Figure 2 Model predicted sidewall temperature correlated to refractory wear ...

Figure 3 Total PM

10

emissions vs. bottle cullet percentage

Figure 4 Total PM

10

emissions vs. bottle cullet percentage

Figure 5 FeO content vs. 1050 nm absorbance normalized to 1 cm glass sample ...

Figure 6 Improved redox control with fewer formulation changes (FeO results ...

Figure 7 Glass Temperature Decreases with High Cullet Use

Chapter 7

Figure 1 SCR Control and Transformer Schematic

Figure 2 Full Sine Wave

Figure 3 75% of Sine Wave

Figure 4 50% of Sine Wave

Figure 5 IGBT Control and Transformer Schematic

Figure 6 IGBT Waveforms (shown with a 480 Volt System)

Figure 7 Impedance Triangle

Figure 8 Power Triangle

Figure 9 Transformer Schematic for Primary Turns

Figure 10 Transformer Taps Highlighted are Used for Testing

Figure 11 SCR Application Schematic

Figure 12 IGBT Application Setup

Chapter 8

Figure 1 Examples of cullet related inclusions from left to right: Pottery, ...

Figure 2 Typical recycling process (1)

Figure 3 (a) Result of color distribution inspection and (b) Result of findi...

Figure 4 (a) Glass Melting test and (b) COD measurements.

Figure 5 Top: Trend on cullet quality improvements; Bottom: Trend on cullet ...

Figure 6 One of the inspection buses used

Chapter 9

Figure 1 Picture of bubbles in a glass melt. There are billions of bubbles b...

Figure 2 Relative concentrations of Fe and Cr in different valences as a fun...

Figure 3 Products of sodium sulphate chemical reactions in the glass melt

Figure 4 Speciation of iron and redox in the glass tank

Figure 5 Speciation of chromium oxide in the glass tank

Figure 6 Partial pressures of gasses released by the fining reactions the to...

Figure 7 Calculation of the amount of bubbles per kilo of glass melt on two ...

Figure 8 Industrial problem model including temperature validation

Figure 9 Bubble count prediction in two forehearths calculated for the base ...

Chapter 10

Figure 1 Samples demonstrating optical distortion created by cord or straie...

Figure 2 (A) Examination of the bottom of a glass container in a polariscope...

Figure 3 Stress birefringence effect that allows stress in glass to be quant...

Figure 4 The Michel‐Levy birefringence chart, with approximately levels of s...

Figure 5 Abraded thermal shock tests performed at increasing temperatures un...

Chapter 11

Figure 1 Within seconds, precise data on flatness, waviness and reflection o...

Figure 2 The three‐dimensional full surface optical measurement offers fast ...

Figure 3 With the P2‐3D, glass manufacturers ensure their products are suita...

Chapter 12

Figure 1 Flue gas heat recovery systems on commercial furnaces ‐ Cullet Preh...

Figure 2 Historical trend of specific electric power consumption to make VPS...

Figure 3 Potential improvements in fuel consumption for a 300t/d container f...

Figure 4 Schematic Representation of Batch Cullet Preheating System

Figure 5 Schematic representation of OPTIMELT TCR Process

Figure 6 OPTIMELT

TM

TCR System Arrangement in End‐fired Configuration at Lib...

Figure 7 Combining different waste heat recovery technologies to maximize he...

Guide

Cover

Table of Contents

Begin Reading

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81st Conference on Glass Problems

Ceramic Transactions, Volume 269

A Collection of Papers Presented at the 81st Conference on Glass Problems October 26‐30, 2020

Edited by

S. K. Sundaram

 

 

 

 

 

 

 

 

 

This edition first published 2021

© 2021 The American Ceramic Society

All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, except as permitted by law. Advice on how to obtain permission to reuse material from this title is available at http://www.wiley.com/go/permissions .

The right of S K Sundaram to be identified as the author of the editorial material in this work have been asserted in accordance with law

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Library of Congress Cataloging‐in‐Publication Data applied for:

ISBN: 9781119822998

Foreword

The 81st Conference on Glass Problems (GPC) was organized by the Kazuo Inamori School of Engineering, The New York State College of Ceramics, Alfred University, Alfred, NY 14802 and The Glass Manufacturing Industry Council (GMIC), Westerville, OH 43082. The Program Director was S. K. Sundaram, Inamori Professor of Materials Science and Engineering, Kazuo Inamori School of Engineering, The New York State College of Ceramics, Alfred University, Alfred, NY 14802. The Conference Director was Bob Lipetz, Executive Director, Glass Manufacturing Industry Council (GMIC), Westerville, OH 43082. The GPC Advisory Board (AB) included the Program Director, the Conference Director, and several industry representatives. The Board assembled the technical program. Donna Banks of the GMIC coordinated the events and provided support. Due to world‐wide COVID‐19 pandemic, the conference was a virtual event. It started with a full‐day plenary session followed by technical sessions. The themes and chairs of four technical sessions were as follows:

Construction/Repair

Larry McCloskey, Anchor Acquisition, LLC, Lancaster, OH

Melting

Uyi Iyoha, Linde Inc., Peachtree City, GA

Quality Control & Sensors

Kenneth Bratton, Bucher Emhart Glass, Windsor, CT

Environmental and Sustainability

Adam Polycn, Vitro Architectural Glass, Cheswick, PA

In addition, one session entitled, “In‐Furnace Thermal Imaging for Survey and Operations Optimization,” was held at the end Monday October 26th sponsored by Land Ametek. Two sessions entitled, “New Technology Spotlight Webminar: Synchronized Oxy‐Fuel Boost Burners for Zero‐Port Performance Optimization,” sponsored by Air Products and “Current and Future Melting & Conditioning Solutions for All Glassmakers,” sponsored by fives were held at the end of Tuesday 27th.

Preface

This volume is a collection of papers presented at the 81st year of the Glass Problems Conference (GPC) in 2020. The GPC continues the tradition of publishing the papers that goes back to 1934. The manuscripts included in this volume are reproduced as furnished by the presenting authors but were reviewed prior to the presentation and submission by the respective session chairs. These chairs are also the members of the GPC Advisory Board.

As the Program Director of the GPC, I am thankful to all the presenters at the 80th GPC. This year’s meeting was record breaking in many senses. We had a total of 570 registered attendees including 40 students from across the country. I appreciate all the support from the members of Advisory Board. Their volunteering sprit, generosity, professionalism, and commitment through an unprecedented world‐wide pandemic were critical to the high‐quality technical program at this Conference. I also appreciate continuing support and strong leadership from the Conference Director, Mr. Bob Lipetz, Executive Director of GMIC and excellent support from Ms. Donna Banks of GMIC in organizing the GPC. I look forward to continuing our work with the entire team in the future.

Please note that The American Ceramic Society and myself did minor editing and formatting of these papers. Neither Alfred University nor GMIC is responsible for the statements and opinions expressed in this volume.

S. K. SundaramAlfred, NYNovember 2020

Acknowledgements

It is my great pleasure to acknowledge the dedicated service, advice, and team spirit of the members of the GPC AB in planning this Conference, inviting key speakers, reviewing technical presentations, chairing technical sessions, and reviewing manuscripts for this publication:

Kenneth Bratton ‐

Bucher Emhart Glass, Windsor, CT

Chris Bloom ‐

Owens Corning, Granville, OH

Weijian Chen ‐

Libbey Glass, Toledo, OH

Eric Dirlam ‐

Ardagh Glass, Muncie, IN

Uyi Iyoha –

Linde Inc., Peachtree City, GA

Bob Lipetz ‐

Glass Manufacturing Industry Council, Westerville, OH

Larry McCloskey –

Anchor Acquisition, LLC, Lancaster, OH

Glenn Neff ‐

Glass Service USA, Inc., Stuart, FL

Adam Polcyn –

Vitro Architectural Glass, Cheswick, PA

Jan Schep –

Owens‐Illinois, Inc., Perrysburg, OH

Christopher Tournour –

Corning Incorporated, Corning, NY

Phillip Tucker ‐

Johns Manville, Littleton, CO

James Uhlik –

Toledo Engineering Co., Inc., Toledo, OH

Justin Wang –

Guardian Industries, Auburn Hills, MI

I am indebted to Donna Banks, GMIC for her patience, support, and attention to detail in making this conference a big success and this Proceedings possible.

Finally, the whole team has worked tirelessly against all odds of the ongoing world‐wide pandemic making this a successful conference. The determination and enthusiasm are enduring and inspiring.

PLENARY