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Beschreibung

This book covers the recent advances in electrode materials and their novel applications at the cross-section of advanced materials. The book is divided into two sections: State-of-the-art electrode materials; and engineering of applied electrode materials. The chapters deal with electrocatalysis for energy conversion in view of bionanotechnology; surfactant-free materials and polyoxometalates through the concepts of biosensors to renewable energy applications; mesoporous carbon, diamond, conducting polymers and tungsten oxide/conducting polymer-based electrodes and hybrid systems. Numerous approaches are reviewed for lithium batteries, fuel cells, the design and construction of anode for microbial fuel cells including phosphate polyanion electrodes, electrocatalytic materials, fuel cell reactions, conducting polymer based hybrid nanocomposites and advanced nanomaterials.

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Seitenzahl: 893

Veröffentlichungsjahr: 2016

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Contents

Cover

Title page

Copyright page

Preface

Part 1: State-of-the-Art Electrode Materials

Chapter 1: Advances in Electrode Materials

1.1 Advanced Electrode Materials for Molecular Electrochemistry

1.2 Electrode Materials for Electrochemical Capacitors

1.3 Nanostructure Electrode Materials for Electrochemical Energy Storage and Conversion

1.4 Progress and Perspective of Advanced Electrode Materials

Acknowledgments

References

Chapter 2: Diamond-based Electrodes

2.1 Introduction

2.2 Techniques for Preparation of Diamond Layers

2.3 Why Diamond for Electrodes?

2.4 Diamond Doping

2.5 Electrochemical Properties of Doped Diamonds

2.6 Diamond Electrodes Applications

2.7 Conclusions

References

Chapter 3: Recent Advances in Tungsten Oxide/Conducting Polymer Hybrid Assemblies for Electrochromic Applications

3.1 Introduction

3.2 History and Technology of Electrochromics

3.3 Electrochromic Devices

3.4 Transition Metal Oxides

3.5 Tungsten Oxide

3.6 Conjugated Organic Polymers

3.7 Hybrid Materials

3.8 Electrochromic Tungsten Oxide/Conducting Polymer Hybrids

3.9 Conclusions and Perspectives

Acknowledgements

References

Chapter 4: Advanced Surfactant-free Nanomaterials for Electrochemical Energy Conversion Systems: From Electrocatalysis to Bionanotechnology

4.1 Advanced Electrode Materials Design: Preparation and Characterization of Metal Nanoparticles

4.2 Electrocatalytic Performances Toward Organic Molecules Oxidation

4.3 Metal Nanoparticles at Work in Bionanotechnology

4.4 Conclusions

Acknowledgments

Notes

References

Part 2: Engineering of Applied Electrode Materials

Chapter 5: Polyoxometalate-based Modified Electrodes for Electrocatalysis: From Molecule Sensing to Renewable Energy-related Applications

5.1 Introduction

5.2 POMs and POMs-based (Nano)Composites

5.3 POMs-based Electrocatalysis for Sensing Applications

5.4 POMs-based Electrocatalysis for Energy Storage and Conversion Applications

5.5 Concluding Remarks

Acknowledgments

List of Abbreviations and Acronyms

References

Chapter 6: Electrochemical Sensors Based on Ordered Mesoporous Carbons

6.1 Introduction

6.2 Electrochemical Sensors Based on OMCs

6.3 Electrochemical Sensors Based on Redox Mediators/OMCs

6.4 Electrochemical Sensors Based on NPs/OMCs

6.5 Conclusions

Acknowledgments

References

Chapter 7: Non-precious Metal Oxide and Metal-free Catalysts for Energy Storage and Conversion

7.1 Metal–Nitrogen–Carbon (M–N–C) Electrocatalysts

7.2 Transition Metal Oxide Electrode Materials for Oxygen Evolution Reaction, Oxygen Reduction Reaction and Bifuctional Purposes (OER/ORR)

7.3 Transition Metal Chalcogenides, Nitrides, Oxynitrides, and Carbides

7.4 Oxygen Reduction Reaction for Metal-free

References

Chapter 8: Study of Phosphate Polyanion Electrodes and Their Performance with Glassy Electrolytes: Potential Application in Lithium Ion Solid-state Batteries

8.1 Introduction

8.2 Glass Samples Preparation

8.3 Nanostructured Composites Sample Preparation

8.4 X-ray Powder Diffraction

8.5 Thermal Analysis

8.6 Density and Appearance

8.7 Structural Features

8.8 Electrical Behavior

8.9 All-solid-state Lithium Ion Battery

8.10 Final Remarks

Acknowledgments

References

Chapter 9: Conducting Polymer-based Hybrid Nanocomposites as Promising Electrode Materials for Lithium Batteries

9.1 Introduction

9.2 Electrode Materials of Lithium Batteries Based on Conducting Polymer-based Nanocomposites Prepared by Chemical and Electrochemical Methods

9.3 Mechanochemical Preparation of Conducting Polymer-based Hybrid Nanocomposites as Electrode Materials of Lithium Batteries

9.4 Conclusion

References

Chapter 10: Energy Applications: Fuel Cells

10.1 Introduction

10.2 Catalyst Supports for Fuel Cell Electrodes

10.3 Anode and Cathode Catalysts for Fuel Cells

10.4 Conclusions

References

Chapter 11: Novel Photoelectrocatalytic Electrodes Materials for Fuel Cell Reactions

11.1 Introduction

11.2 Basic Understanding on the Improved Catalytic Performance of Photo-responsive Metal/Semiconductor Electrodes

11.3 Synthetic Methods for Metal/Semiconductor Electrodes

11.4 Photo-responsive Metal/Semiconductor Anode Catalysts

11.5 Conclusions and Future Outlook

References

Chapter 12: Advanced Nanomaterials for the Design and Construction of Anode for Microbial Fuel Cells

12.1 Introduction

12.2 Carbon Nanotubes-based Anode Materials for MFCs

12.3 Graphene-based Anode Materials for MFCs

12.4 Other Anode Materials for MFCs

12.5 Conclusions

Acknowledgments

References

Chapter 13: Conducting Polymer-based Electrochemical DNA Biosensing

13.1 Introduction

13.2 Electrochemical DNA Biosensors

13.3 Conducting Polymer-based Electrochemical DNA Biosensors

13.4 Conclusions and Outlook

Acknowledgments

References

Index

End User License Agreement

Guide

Cover

Copyright

Contents

Begin Reading

List of Tables

Chapter 1

Table 1.1: Applications of traditional graphite-based materials including carbon fibers [6].

Table 1.2: Specific capacitance of conducting polymers-based materials.

Chapter 5

Table 5.1: Electrocatalytic reduction of nitrite by homogeneously dissolved POMs.

Table 5.2: Reaction pathways of ORR in aqueous electrolytes (potentials vs. NHE).

Chapter 6

Table 6.1: Electrochemical sensors based on OMCs.

Table 6.2: Electrochemical sensors based on redox mediators/OMCs.

Table 6.3: Electrochemical sensors based on noble metal NPs/OMCs.

Chapter 7

Table 7.1: Possible reaction mechanisms of OER reactions in acidic and alkaline media [96–100].

Table 7.2: Synthesis variations in Co

3+

: Ni

2+

concentrations and solvent in sol–gel preparation of anode substrate coatings [119].

Chapter 8

Table 8.1: T

g

value of each glassy system.

Table 8.2: Glasses density in this chapter.

Table 8.3: Raman MWT glass bands.

Table 8.4: FTIR MWT glass bands.

Table 8.5: Raman BNT glass bands.

Table 8.6: FTIR BNT glass bands.

Table 8.7: Raman band assignation carbon coating and LiVP-Cit.- CB.

Table 8.8: Raman band assignation carbon coating and LiVP-Cit.- CNF.

Chapter 10

Table 10.1: Examples of recently developed fuel cell electrodes prepared using commercial carbon supports.

Table 10.2: Properties of recently developed anode and cathode catalysts for fuel cells.

Chapter 12

Table 12.1: Examples of MFCs on the basis of CNTs-based anode.

Table 12.2: Examples of MFCs on the basis of graphene-based anode.

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