Table of Contents
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FOREWORD
PREFACE
List of Contributors
Fenton and Fenton-Like Processes for the Degradation of Dye in Aqueous Solution
Abstract
INTRODUCTION
CONVENTIONAL FENTON PROCESS
PHOTO-FENTON PROCESS
ELECTRO-FENTON PROCESS
SONO-FENTON PROCESS
PHOTO-ELECTRO-FENTON PROCESS
SONO-PHOTO-FENTON PROCESS
SONO-ELECTRO-FENTON PROCESS
BIO-FENTON REACTION
Conclusion
References
Photocatalytic Dye Degradation Using Metal-Organic Frameworks
Abstract
INTRODUCTION
DEGRADATION OF DYES USING BARE MOFS (AS-SYNTHESIZED MOFS)
Lewis Acid MOF
Copper MOF
Cu3(BTC)2 or MOF-199
{[Cu(ttpa)(pim)].H2O}n MOF
{[Cu(AHP)2(H2O)](1,5-NDS)(S)} MOF1
Mechanism (Band theory)
Iron MOF
Cadmium MOF
TMU-16 (Zinc MOF, [Zn2(BDC)2(4-bpdh)].3DMF)
Brønsted Base MOF
Silica Supported MOF
Silica-supported Binary MOF (MIL 53 (Al-Fe)@SiO2)
Magnetic MOFs
Fe3O4@SiO2@PCN-222(Fe)
Photocatalytic Measurement
Ionic MOFs (iMOFs)
Anionic MOFs
Cationic MOFs
Bimetallic MOFs
Synthesis of Mixed Metal MOFs: [STA-12(Fe, Mn)]
Analyses of Degradation Products
METAL-ORGANIC FRAMEWORK NANOCOMPOSITE: (MOF NANOCOMPOSITE)
NH2-MIL-101(Fe) Nanocomposite
Synthesis of NH2-MIL-101(Fe)/ Phosphotungstic Acid (PA) Composite
Synthesis of g-C3N4/Fe-TDA Composites
Synthesis of Fe-TDA MOF
CONCLUSION
ACKNOWLEDGEMENT
REFERENCES
UV, Visible, and Near-Infrared Responsive Photocatalyst for Dye Degradation
Abstract
INTRODUCTION
Principle of Semiconductor Photocatalysis
Visible Light Photocatalyst
Metal and Non-metal Doping
Crystal Structure and Morphology Modifications
Sensitization of Semiconductor
Heterojunction Photocatalysts
Z-scheme Photocatalysts
Plasmonic Nanoparticles-based Photocatalysts
NIR Active Photocatalyst
Up-conversion Phosphor/ TiO2 Composites
CONCLUSION
ACKNOWLEDGEMENT
Reference
Transition Metal Dichalcogenide Hybrids for Visible-light-driven Photocatalytic Dye Degradation
Abstract
INTRODUCTION
TRANSITION METAL DICHALCOGENIDE HYBRIDS
TiO2-based Transition Metal Dichalcogenide Hybrids
g-C3N4-based Transition Metal Dichalcogenide Hybrids
g-C3N4@TiO2-based Transition Metal Dichalcogenide Hybrids
Applications of Transition Metal Dichalcogenide Hybrids
Mechanism of Dye Degradation
CONCLUSION AND FUTURE SCOPE
REFERENCES
Photocatalytic Degradation of Dyes Using Green Synthesized Metal Nanoparticles
Abstract
INTRODUCTION
PHOTOCATALYTIC DEGRADATION
GREEN SYNTHESIS OF METAL NANOPARTICLES
DEGRADATION OF DYES USING GREEN SYNTHESISED METAL NANOPARTICLES
CONCLUSION
ACKNOWLEDGEMENT
References
Recent Developments and Perspectives in Photocatalytic Degradation of Dyes Employing Metal Oxide Nanoparticles
Abstract
INTRODUCTION
PHOTOCATALYSIS
Semiconductors with n-type
TiO2 NPs
ZnO NPs
SnO2 NPs
CeO2
P-type Semiconductor
CuO NPs
Fe2O3 NPs
NiO NPs
Dye Degradation by Other Metal Oxides
Bimetallic Transition Metal Oxides as Photocatalyst
Variables Influencing the Degradation of Dyes by Photocatalysis
Impact of pH
Catalyst Load
Effect of Electron Acceptors
Dissolved Oxygen in Solution
Reaction Temperature
Light Intensity
CONCLUSIONS AND PERSPECTIVES
REFERENCES
Graphene Oxide Nanocomposites: Photocatalytic Dye Degradation Investigations
Abstract
Introduction
Background of Dye-contaminated Industrial Effluents
Treatment Methods for Dye-contaminated Industrial Effluents
Graphene Oxide Composite Dye Removal
Advantages of Graphene Oxide Composites in Dye-contaminated Industrial Effluents Treatment
Limitations of Graphene Oxide Composites in Dye-contaminated Industrial Effluents Treatment
Graphene Oxide-based Composite Membrane for Dye-contaminated Industrial Effluent Treatment
Synthesis of Graphene Oxide Composites
Glucose-Graphene Oxide Composite
Cyclodextrin-Graphene Oxide Composite
Chitosan-Graphene Oxide Composite
Metal Hydroxide-Graphene Oxide Composite
Metal-Graphene Oxide Composite
Titanium Oxide Graphene Oxide Composite
Photocatalysis Technology in the Purification of Dye-contaminated Industrial Effluents
Nanofibers Membranes
Nanocomposite Membranes
Thin-film Nanocomposite (TFN) Membranes
Photo Dye Degradation by Metal Nanoparticles Blended Graphene Oxide-Zinc Oxide Nanocomposites
Photo Dye Degradation of Polluted Water by Titanium Oxide/graphene Oxide Nanocomposites
Photo Dye Degradation by Zinc Oxide Ammonia Modified Graphene Oxide Nanocomposites
Photo Dye Degradation by Copper Oxide Modified Graphene Oxide Nanocomposites
Photo Dye Degradation by Graphene Oxide–iron Oxide Nanocomposites
Photo Dye Degradation by Graphene Oxide Tungsten Oxide Nanocomposites
Photo Dye Degradation by Graphene Oxide Nickel Oxide Nanocomposites
Conclusion
Advances in Dye Degradation
(Volume 2)
Edited by
Paulpandian Muthu Mareeswaran
Department of Chemistry
College of Engineering
Anna University, Chennai-600025
Tamil Nadu, India
&
Jegathalaprathaban Rajesh
Department of Chemistry
Saveetha School of Engineering
Institute of Medical and Technical Science
Saveetha University, Chennai-602105
Tamil Nadu, India
BENTHAM SCIENCE PUBLISHERS LTD.
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FOREWORD
Regarding the environmental aspects, dye removal is more crucial. The “process” of eliminating dyes is just as significant because it has various economic and chemical effects. Degrading or removing dyes needs to be low-energy and safe for the environment. Once more, the process of chemical degradation will result in environmental hazards. High energy consumption will also result in environmental issues since there will be a greater energy demand. For this reason, the best method for meaningful dye degradation or removal will be to use reusable, effective materials that require less energy.
The editors in volume I have already covered basic aspects of dye degradation. In volume II, the editors address efficient degradation through light, a benign and sustainable energy source, and absorption for removing dyes. Given that the energy required for photochemical dye degradation is found in nature, this is an intriguing aspect of dye degradation. Numerous kinds of photocatalysts for dye degradation are covered in this book. Various materials for effective photodegradation are discussed in this volume. The relevant chapters justify the materials' suitability and go into great detail about their inherent qualities.
C. Stella
Department of Oceanography and
Coastal Area Studies, Thondi Campus
Alagappa University
Karaikudi-630003, India
PREFACE
The environmental and economic perspectives create a need for dye degradation techniques. The fundamentals and importance of the dye degradation process were covered in “Advances in Dye Degradation,” volume I. In this volume, we have covered advanced oxidation techniques for degrading dyes. The Fenton process, a radical reaction, is used in Chapter 1 to degrade dyes. Radical production can break the dye materials into a safe byproduct when iron is present. The Fenton process can be combined with other processes, such as photochemical and electrochemical ones because it can be adjusted to produce a chain reaction that produces radicals. As a result, the Fenton process is among the most effective methods for degrading dyes.
The application of metal-organic frameworks to dye degradation is covered in Chapter 2. Metal-organic frameworks are porous materials whose synthetic pore modification allows for tuning the selectivity of these compounds. One of the key elements in the field of dye degradation is the application of electrocatalytic or photocatalytic degradation of these materials.
The photocatalytic materials active in the visible light and near-infrared regions of the electromagnetic spectrum are covered in Chapter 3. The band gap is the crucial factor for a successful photocatalyst. The ultimate goal of photocatalysis will be the utilization of solar light. As a result, the materials must absorb the entire spectrum of solar light's wavelengths. Nonetheless, there are several benefits to using NIR and the red region. This chapter provides a detailed discussion of the NIR active materials.
The photocatalytic degradation of transition metal dichalcogenides (TMDs) is covered in Chapter 4. The back combination of electrons and holes is the main element that lowers the degradation reaction's efficiency. Chalcogenides can, therefore, be used to create hybrid composites that inhibit the back combination process and yield beneficial outcomes in the degradation of dyes. The mechanism underlying each of these dye degradation processes is covered in this chapter.
The synthesis of photocatalysts for dye degradation is covered in Chapter 5. This chapter discusses the green synthetic approach of photocatalytic materials and their efficiency towards dye degradation since the production of photocatalysts should be benign. The use of metal oxide nanoparticles in dye degradation is covered in Chapter 6. The latest developments and trends regarding metal oxide nanoparticles and dye degradation are covered in this chapter.
The photocatalytic dye degradation employing graphene oxide composite materials is covered in Chapter 7. Effective conductive materials, such as graphene oxide, can control their electron injection by mixing it with materials that receive electron injection and synthetic modification to create composites. Because of these materials' high reusability, this chapter discusses their recent advantages. We hope that this volume will be helpful to both those working in the field and students who are about to enter it, as it starts with basic methods and provides information about advanced techniques.
Paulpandian Muthu Mareeswaran
Department of Chemistry
College of Engineering
Anna University, Chennai-600025
Tamil Nadu, India
&Jegathalapradhaban Rajesh
Department of Chemistry
Saveetha School of Engineering
Institute of Medical and Technical Science
Saveetha University, Chennai-602105
Tamil Nadu, India
List of Contributors
Eswaran RajkumarDepartment of Chemistry, Madras Christian College (Autonomous), Affiliated to University of Madras, Chennai-600059, Tamil Nadu, IndiaJeyaraj Dhaveethu RajaDepartment of Chemistry, The American College, Tallakkulam, Madurai, Tamil Nadu-625002, IndiaJegathalaprathapan RajeshDepartment of Chemistry, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai, Tamil Nadu-602105, IndiaK. SrinivasSchool of Electronic Science and Technology and State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu-610054, PR ChinaMuhammad Y. BashoutiDepartment of Solar Energy and Environmental Physics, Ben-Gurion University of the Negev, Midreshet Ben-Gurion-8499000, Beersheba, IsraelMukkanan ArivananthanCenter for Nanoscience and Technology, Anna University, Chennai-600025, Tamil Nadu, IndiaMurugesan SankarganeshDepartment of Chemistry, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai, Tamil Nadu-602105, IndiaM. KarpuraranjithSchool of Electronic Science and Technology and State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu-610054, PR ChinaNainamalai DevarajanSolid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore, Karnataka-560012, IndiaNatarajan PrakashDepartment of Materials Chemistry, SIMATS School of Engineering, Saveetha Institute of Medical and Technical Sciences, Thandalam-600056, Tamil Nadu, India
Department of Solar Energy and Environmental Physics, Ben-Gurion University of the Negev, Midreshet Ben-Gurion-8499000, Beersheba, IsraelPaulpandian Muthu MareeswaranDepartment of Chemistry, College of Engineering, Anna University, Chennai-600025, Tamil Nadu, India
Department of Industrial Chemistry, Alagappa University, Karaikudi-630003, Tamil Nadu, IndiaPaulraj Adwin JoseDepartment of Chemistry, E.G.S. Pillay Engineering College (Autonomous), Nagapattinam, Tamil Nadu-611002, IndiaR. ManigandanSchool of Electronic Science and Technology and State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu-610054, PR ChinaR. LijuDepartment of Chemistry, Madras Christian College (Autonomous), Affiliated to University of Madras, Chennai-600059, Tamil Nadu, IndiaS. RajaboopathiDepartment of Chemistry, Government Arts College for Women, Sivagangai-630561, Tamil Nadu, IndiaSPR. PoonkodiDepartment of Chemistry, Government Arts College for Women, Sivagangai-630561, Tamil Nadu, IndiaSheeba DanielDepartment of Chemistry, Holy Cross College (Autonomous), Nagercoil, Tamil Nadu, IndiaSelvakumaran NagamaniDepartment of Biotechnology and Department of Chemistry, Anand Institute of Higher Technology, OMR, Chennai-603103, Tamil Nadu, IndiaSubramanian BalachandranDepartment of Physiology, Saveetha Dental College and Hospitals, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai-600077, Tamil Nadu, IndiaYasuhiro HayakawaResearch Institute of Electronics, Shizuoka University, Hamamatsu, Shizuoka-432-8011, JapanY.F. ChenSchool of Electronic Science and Technology and State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu-610054, PR China
Fenton and Fenton-Like Processes for the Degradation of Dye in Aqueous Solution
R. Liju1,Eswaran Rajkumar1,*
1 Department of Chemistry, Madras Christian College (Autonomous), Affiliated to University of Madras, Chennai-600059, Tamil Nadu, India
Abstract
Water is necessary for the growth of humans and all other living things. Water is becoming scarce due to industrialization and its rapid growth, and the water ecosystem is negatively impacted by the direct release of wastewater into the environment. The textile, tanning, coating, plastics, paint, printing, and other industries, discharge dyes and pigments into the environment. One major problem is to remove dyes and pigments from industrial wastewater in a inexpensive and environmentally friendly way. Before they are released into the environment, there are several ways to mitigate the situation, including chemical, biological, and chemical oxidation processes. The advanced oxidation process (AOP) is a widely employed technique for eliminating contaminants from water and wastewater. The dye molecules are broken down by a Fenton and Fenton-like mechanism, in which the breakdown of hydrogen peroxide produces hydroxyl radicals. This chapter focuses on the most current advancements and various strategies used in the Fenton and/or Fenton-like processes used to degrade the dye molecules.
Keywords: Decolourization, Dye degradation, Fenton process, Hybrid Fenton processes.
*Corresponding author Eswaran Rajkumar: Department of Chemistry, Madras Christian College (Autonomous), Affiliated to University of Madras, Chennai-600059, Tamil Nadu, India; E-mail:
[email protected]