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Everything you need to crush chemistry with confidence Chemistry All-in-One For Dummies arms you with all the no-nonsense, how-to content you'll need to pass your chemistry class with flying colors. You'll find tons of practical examples and practice problems, and you'll get access to an online quiz for every chapter. Reinforce the concepts you learn in the classroom and beef up your understanding of all the chemistry topics covered in the standard curriculum. Prepping for the AP Chemistry exam? Dummies has your back, with plenty of review before test day. With clear definitions, concise explanations, and plenty of helpful information on everything from matter and molecules to moles and measurements, Chemistry All-in-One For Dummies is a one-stop resource for chem students of all valences. * Review all the topics covered in a full-year high school chemistry course or one semester of college chemistry * Understand atoms, molecules, and the periodic table of elements * Master chemical equations, solutions, and states of matter * Complete practice problems and end-of-chapter quizzes (online!) Chemistry All-In-One For Dummies is perfect for students who need help with coursework or want to cram extra hard to ace that chem test.
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Chemistry All-in-One For Dummies®
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Library of Congress Control Number: 2022945633
ISBN 978-1-119-90831-9 (pbk); ISBN 978-1-119-90832-6 (ebk); ISBN 978-1-119-90833-3 (ebk)
Cover
Title Page
Copyright
Introduction
About This Book
Foolish Assumptions
Icons Used in This Book
Beyond the Book
Where to Go from Here
Unit 1: Getting Started with Chemistry
Chapter 1: Looking at Numbers Scientifically
Using Exponential and Scientific Notation to Report Measurements
Multiplying and Dividing in Scientific Notation
Using Scientific Notation to Add and Subtract
Distinguishing between Accuracy and Precision
Identifying Significant Figures
Doing Arithmetic with Significant Figures
Qualitative and Quantitative Observations
Practice Questions Answers and Explanations
Whaddya Know? Chapter 1 Quiz
Answers to Chapter 1 Quiz
Chapter 2: Using and Converting Units
Familiarizing Yourself with Base Units and Metric System Prefixes
Looking at Density
Using Conversion Factors
Working with the Factor Label Method
Practice Questions Answers and Explanations
Whaddya Know? Chapter 2 Quiz
Answers to Chapter 2 Quiz
Chapter 3: The Basic Properties of Matter
Describing the States of Matter
Classifying Pure Substances and Mixtures
Nice Properties You’ve Got There
Practice Questions Answers and Explanations
Whaddya Know? Chapter 3 Quiz
Answers to Chapter 3 Quiz
Chapter 4: Breaking Down Atoms into Their Subatomic Particles
The Atom: Protons, Electrons, and Neutrons
A Brief History of the Atom
Deciphering Chemical Symbols: Atomic and Mass Numbers
Keeping an Eye on Ions
Accounting for Isotopes Using Atomic Masses
Practice Questions Answers and Explanations
Whaddya Know? Chapter 4 Quiz
Answers to Chapter 4 Quiz
Unit 2: The Periodic Table
Chapter 5: Surveying the Periodic Table of the Elements
Organizing the Periodic Table
Practice Questions Answers and Explanations
Whaddya Know? Chapter 5 Quiz
Answers to Chapter 5 Quiz
Chapter 6: The Electron
Putting Electrons in Their Places: Electron Configurations
Quantifying Quantum Numbers
Valence Electrons
Measuring the Amount of Energy (or Light) an Excited Electron Emits
Practice Questions Answers and Explanations
Whaddya Know? Chapter 6 Quiz
Answers to Chapter 6 Quiz
Chapter 7: Periodic Trends
Nuclear Charge and Atomic Radius
Eyeing Trends in Ionization Energies
Attracting Electrons: Electronegativities
Practice Questions Answers and Explanations
Whaddya Know? Chapter 7 Quiz
Answers to Chapter 7 Quiz
Chapter 8: Doing Chemistry with Atomic Nuclei
Decaying Nuclei in Different Ways
Measuring Rates of Decay: Half-Lives
Making and Breaking Nuclei: Fusion and Fission
Practice Questions Answers and Explanations
Whaddya Know? Chapter 8 Quiz
Answers to Chapter 8 Quiz
Unit 3: Making and Breaking Bonds
Chapter 9: Building Bonds
Forming Ions
Pairing Charges with Ionic Bonds
Forming Sodium Chloride
Ionic Salts
Sharing Electrons with Covalent Bonds
Practice Questions Answers and Explanations
Whaddya Know? Chapter 9 Quiz
Answers to Chapter 9 Quiz
Chapter 10: The Shape of Molecules
Drawing the Structural Formulas of Molecules
Occupying and Overlapping Molecular Orbitals
Polarity: Sharing Electrons Unevenly
Shaping Molecules: VSEPR Theory and Hybridization
Wondering About Water and Intermolecular Forces
Practice Questions Answers and Explanations
Whaddya Know? Chapter 10 Quiz
Answers to Chapter 10 Quiz
Chapter 11: Naming Compounds and Writing Formulas
Labeling Ionic Compounds and Writing Their Formulas
Getting a Grip on Ionic Compounds with Polyatomic Ions
Naming Covalent Compounds and Writing Their Formulas
Addressing Acids
Mixing the Rules for Naming and Formula Writing
Beyond the Basics: Naming Organic Carbon Chains
Practice Questions Answers and Explanations
Whaddya Know? Chapter 11 Quiz
Answers to Chapter 11 Quiz
Unit 4: Working with Reactions
Chapter 12: Understanding the Many Uses of the Mole
The Mole Conversion Factor: Avogadro’s Number
Doing Mass and Volume Mole Conversions
Determining Percent Composition
Calculating Empirical Formulas
Using Empirical Formulas to Find Molecular Formulas
Practice Questions Answers and Explanations
Whaddya Know? Chapter 12 Quiz
Answers to Chapter 12 Quiz
Chapter 13: Getting a Grip on Chemical Equations
Translating Chemistry into Equations and Symbols
Understanding How Reactions Occur
Balancing Chemical Equations
Recognizing Reactions and Predicting Products
Canceling Spectator Ions: Net Ionic Equations
Practice Questions Answers and Explanations
Whaddya Know? Chapter 13 Quiz
Answers to Chapter 13 Quiz
Chapter 14: Putting Stoichiometry to Work
Using Mole-Mole Conversions from Balanced Equations
Putting Moles at the Center: Conversions Involving Particles, Volumes, and Masses
Calculating Limiting Reactants
Counting Your Chickens after They’ve Hatched: Percent Yield Calculations
Practice Questions Answers and Explanations
Whaddya Know? Chapter 14 Quiz
Answers to Chapter 14 Quiz
Unit 5: Examining Changes in Energy
Chapter 15: Understanding States of Matter in Terms of Energy
Changing States of Matter
Figuring Out Phase Diagrams
Taking a Look at Energy and Temperature
Measuring Energy
Practice Questions Answers and Explanations
Whaddya Know? Chapter 15 Quiz
Answers to Chapter 15 Quiz
Chapter 16: Warming Up to Thermochemistry
Understanding the Basics of Thermodynamics
Working with Specific Heat Capacity and Calorimetry
Absorbing and Releasing Heat: Endothermic and Exothermic Reactions
Summing Heats with Hess’s Law
Practice Questions Answers and Explanations
Whaddya Know? Chapter 16 Quiz
Answers to Chapter 16 Quiz
Chapter 17: Obeying Gas Laws
Working with the Kinetic Molecular Theory
Measuring and Converting Pressure
Boyle’s Law: Playing with Pressure and Volume
Charles’s Law and Absolute Zero: Looking at Volume and Temperature
Gay-Lussac’s Law: Examining Pressure and Temperature
Combining Pressure, Temperature, and Volume into One Law
Dealing with Amounts: Avogadro’s Law and the Ideal Gas Law
Mixing It Up with Dalton’s Law of Partial Pressures
Diffusing and Effusing with Graham’s Law
Practice Questions Answers and Explanations
Whaddya Know? Chapter 17 Quiz
Answers to Chapter 17 Quiz
Unit 6: Studying Solutions
Chapter 18: Dissolving into Solutions
Seeing Different Forces at Work in Solubility
Concentrating on Molarity and Percent Solutions
Changing Concentrations by Making Dilutions
Altering Solubility with Temperature
Practice Questions Answers and Explanations
Whaddya Know? Chapter 18 Quiz
Answers to Chapter 18 Quiz
Chapter 19: Playing Hot and Cold: Colligative Properties
Portioning Particles: Molality and Mole Fractions
Too Hot to Handle: Elevating and Calculating Boiling Points
How Low Can You Go? Depressing and Calculating Freezing Points
Determining Molecular Masses with Boiling and Freezing Points
Practice Questions Answers and Explanations
Whaddya Know? Chapter 19 Quiz
Answers to Chapter 19 Quiz
Chapter 20: Working with Acids and Bases
Getting to Know Acids and Bases
Acids and Bases at the Atomic Level
Measuring Acidity and Basicity: p H, p OH, and K
W
Dissociating with Strong and Weak Acids
Practice Questions Answers and Explanations
Whaddya Know? Chapter 20 Quiz
Answers to Chapter 20 Quiz
Chapter 21: Achieving Neutrality with Titrations and Buffers
Using Indicators and Titration to Figure Out Molarity
Maintaining Your pH with Buffers
Measuring Salt Solubility with
K
sp
Practice Questions Answers and Explanations
Whaddya Know? Chapter 21 Quiz
Answers to Chapter 21 Quiz
Glossary
Index
About the Authors
Advertisement Page
Connect with Dummies
End User License Agreement
Chapter 2
TABLE 2-1 SI (Metric) Prefixes
TABLE 2-2 SI Base Units
TABLE 2-3 Densities of Typical Solids and Liquids
TABLE 2-4 Conversion Factors
Chapter 4
TABLE 4-1 The Three Major Subatomic Particles
TABLE 4-2 The Elements
Chapter 6
TABLE 6-1 Electron Configurations for Members of IA (Alkali Metals)
TABLE 6-2 Electron Configurations for Members of IIA (Alkaline Earth Metals)
TABLE 6-3 Electron Configurations for Members of VIIA (Halogens)
TABLE 6-4 Electron Configurations for Members of VIIIA (Noble Gases)
TABLE 6-5 Summary of the Quantum Numbers
TABLE 6-6 Letter Designation of the Subshells
TABLE 6-7 Quantum Numbers for the First Two Energy Levels
Chapter 8
TABLE 8-1 Half-Life Decay of a Radioactive Isotope
TABLE 8-2 Common Radioisotopes, Half-Lives, and Decay Modes
Chapter 9
TABLE 9-1 Some Common Monatomic Cations
TABLE 9-2 Some Common Monoatomic Anions
TABLE 9-3 Some Common Metals with More Than One Oxidation State
Chapter 10
TABLE 10-1 Predicting Molecular Shape with the VSEPR Theory
Chapter 11
TABLE 11-1 Common Polyatomic Ions
TABLE 11-2 Common Prefixes for Binary Covalent Compounds
TABLE 11-3 Common Acids
TABLE 11-4 Carbon Prefixes
Chapter 13
TABLE 13-1 Symbols Commonly Used in Chemical Equations
TABLE 13-2 Activity Series
TABLE 13-3 Solubility of Selected Ionic Compounds
Chapter 16
TABLE 16-1 Specific and Molar Heat Capacities of Selected Substances at 25°C
Chapter 19
TABLE 19-1
M
Words Related to Concentration
TABLE 19-2 Common
K
b
Values
TABLE 19-3 Common
K
f
Values
Chapter 20
TABLE 20-1 Common Acids Found in the Home
TABLE 20-2 Common Bases Found in the Home
TABLE 20-3 Average pH Values of Some Common Substances
TABLE 20-4 Strong Acids and Bases
Chapter 2
FIGURE 2-1: Determining the volume of an irregular solid: Archimedes’ principle...
Chapter 3
FIGURE 3-1: Solid (a), liquid (b), and gaseous (c) states of matter.
FIGURE 3-2: Classification of matter.
Chapter 4
FIGURE 4-1: General representation of an element using isotope notation.
Chapter 5
FIGURE 5-1: The periodic table of the elements.
FIGURE 5-2: Groups on the periodic table.
FIGURE 5-3: The metals.
FIGURE 5-4: The nonmetals.
FIGURE 5-5: The metalloids.
Chapter 6
FIGURE 6-1: The periodic table with orbitals in place.
FIGURE 6-2: The Aufbau filling diagram.
FIGURE 6-3: Shapes of the s (a), p (b), and d (c) orbitals.
FIGURE 6-4: Number of valence electrons for each family on the periodic table.
FIGURE 6-5: Properties of waves.
FIGURE 6-6: The electromagnetic spectrum.
Chapter 7
FIGURE 7-1: General trend of atomic radius.
FIGURE 7-2: General trend of ionization energy.
FIGURE 7-3: Electronegativities of the elements.
Chapter 8
FIGURE 8-1: Decay of a radioactive isotope.
FIGURE 8-2: Chain reaction.
Chapter 9
FIGURE 9-1: Electron dot structures for elements in the first two rows of the ...
FIGURE 9-2: The transfer of an electron from sodium to chlorine to form an ion...
FIGURE 9-3: Energy-level diagrams for sodium and chlorine.
FIGURE 9-4: The lattice structure of an ionic solid, sodium chloride.
FIGURE 9-5: The formation of a covalent bond in hydrogen.
FIGURE 9-6: The covalent bond formation of Br
2
.
FIGURE 9-7: Triple bond formation in N
2
.
FIGURE 9-8: Formation of carbon dioxide.
Chapter 10
FIGURE 10-1: Electron dot formula of H
2
O.
FIGURE 10-2: The Lewis formula for H
2
O.
FIGURE 10-3: Electron dot formula of C
2
H
4
O.
FIGURE 10-4: The Lewis formula for C
2
H
4
O.
FIGURE 10-5: Condensed structural formulas for C
2
H
4
O.
FIGURE 10-6: Two representations of resonance structures of ozone.
FIGURE 10-7: Formation of bonding and antibonding molecular orbitals from the ...
FIGURE 10-8: Formation of pi and pi* molecular orbitals.
FIGURE 10-9: Formation of a sigma bond (σ) from two s orbitals and formation o...
FIGURE 10-10: Molecular orbital diagram for H
2
.
FIGURE 10-11: MO diagram for O
2
(valence shell electrons only).
FIGURE 10-12: Polar covalent bonding in HF and NH
3
.
FIGURE 10-13: Lewis structures of hydrogen and chlorine fluoride with electron...
FIGURE 10-14: The Lewis structure of chlorine fluoride shows partial charges.
FIGURE 10-15: Two possible Lewis structures of water with the partial positive...
FIGURE 10-16: Common molecular shapes.
FIGURE 10-17: Lewis formulas for H
2
O and NH
3
.
FIGURE 10-18: Hybridization involving the s, p, and d orbitals.
FIGURE 10-19: Hybridization in ethylene.
FIGURE 10-20: Polar covalent bonding in water.
FIGURE 10-21: Hydrogen bonding in water.
FIGURE 10-22: The structure of ice.
Chapter 11
FIGURE 11-1: Figuring the formula of magnesium bromide.
FIGURE 11-2: Figuring the formula of aluminum oxide.
FIGURE 11-3: Pentane’s carbon skeleton.
FIGURE 11-4: Pentane’s hydrocarbon structure.
Chapter 13
FIGURE 13-1: Exothermic reaction of
.
FIGURE 13-2: Endothermic reaction of
.
Chapter 14
FIGURE 14-1: Building mole-mole conversion factors from a balanced equation.
FIGURE 14-2: A problem-solving flowchart showing the use of mole-mole, mole-mas...
Chapter 15
FIGURE 15-1: A general phase diagram.
FIGURE 15-2: The phase diagrams for water, H
2
O, and carbon dioxide, CO
2
.
FIGURE 15-3: Comparison of the Fahrenheit, Celsius, and Kelvin temperature sca...
Chapter 16
FIGURE 16-1: A constant-pressure calorimeter made from coffee cups.
FIGURE 16-2: A constant-volume (bomb) calorimeter.
Chapter 17
FIGURE 17-1: A barometer.
FIGURE 17-2: The manometer.
FIGURE 17-3: Pressure-volume relationship of gases (Boyle’s law).
FIGURE 17-4: The temperature-volume relationship of gases (Charles’s law).
FIGURE 17-5: The pressure-temperature relationship of gases — Gay-Lussac’s law.
Chapter 18
FIGURE 18-1: Making a 1-molar KCl solution.
Chapter 19
FIGURE 19-1: Boiling point elevation and freezing point depression of a soluti...
Chapter 20
FIGURE 20-1: The reaction between ammonia and hydrogen chloride gases.
FIGURE 20-2: The Lewis structures of ammonia and boron trifluoride.
FIGURE 20-3: The pH scale.
Chapter 21
FIGURE 21-1 Titration of an acid with a base.
FIGURE 21-2 A typical titration curve.
FIGURE 21-3 The effect of adding acid and base on the ratio of products and re...
Cover
Title Page
Copyright
Table of Contents
Begin Reading
Glossary
Index
About the Authors
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Chemistry is at once practical and wondrous, humble and majestic. And for someone studying it for the first time, chemistry can be tricky and rather challenging in some spots.
That’s why we wrote this book. It is designed to be an all-encompassing companion for you as you journey through the wonderful yet sometimes confusing world of chemistry. It is going to help you work through anything you might need in your class or whatever you want to investigate further in the wide chemical world.
Chemistry is sometimes called the central science (mostly by chemists), because in order to have a good understanding of biology or geology or even physics, you must have a good understanding of chemistry. We live and work in a world of chemistry, and after your journey is complete, hopefully you won’t find the word chemistry so frightening.
This book is a one-stop chemistry shop. Each chapter explains key concepts covered in any high school or introductory college chemistry class, along with example problems and opportunities for practice. You’ll find the absolute basics that you need to succeed in a chemistry course, all the way up to some rather complicated material.
One thing that will stand out to you is all of the calculations throughout the book. Chemistry has a lot of math in it, and this book doesn’t shy away from that. The beginning chapters of this book, though, are going to help you make sure you are comfortable working through the calculations you’ll see throughout the rest of it, so make sure you don’t skip over those if you think you need a little review. Once you are past those you’re going to see every major chemistry topic covered that you’re likely to encounter:
Each new topic provides
Example problems with answers and solutions
Practice problems with answers and solutions
Each chapter provides
An end-of-chapter quiz with problems representing the topics covered
Solutions to those quiz questions
Online quizzes are also available for even more practice and confidence-building.
Because you’re interested in this book, we assume you probably fall into one of a few categories:
You’re a student taking a high school chemistry course or a student in college taking an introductory chemistry class and are just not even sure where to start.
You’re a parent of a student taking chemistry in high school and are trying to help your kid out with their chemistry but need some brushing up.
You’re just naturally curious about science and mathematics and you want to get a little more acquainted with chemistry.
We also assume that you can add, subtract, multiply, and divide numbers without any real issue, but that you will still use a calculator for all this stuff. Calculators are there for a reason, and they are helpful, so please use them!
In this book, I use these five icons to signal what’s most important along the way:
Each example is an algebra question based on the discussion and explanation, followed by a step-by-step solution. Work through these examples, and then refer to them to help you solve the practice test problems at the end of the chapter.
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When you see this icon, it’s time to put on your thinking cap and work out a few practice problems on your own. The answers and detailed solutions are available so you can feel confident about your progress.
In addition to what you’re reading right now, this book comes with a Cheat Sheet that provides quick access to some formulas, rules, and processes that are frequently used. To get this Cheat Sheet, simply go to www.dummies.com and type Chemistry All-in-One For Dummies Cheat Sheet in the Search box.
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This book is organized so that you can safely move from whichever chapter you choose to start with and in whatever order you like. You can strengthen skills you feel less confident in or work on those that need some attention.
If you need some help with scientific notation, unit conversions, or otherwise feel you could use a little practice on the math side of things then we recommend strongly that you look over Chapters 1 and 2. Those are going to get you ready for all of the other material you’ll see throughout the book. After that Chapters 3, 4, and 5 are going to give you a solid grounding in matter, atoms, and the world-renowned periodic table. Those are probably where you’re going to be starting in almost any chemistry class you encounter, so those are likely going to be a great place to begin your journey.
Beyond that, check out whatever chapters you might need help with. Each chapter is designed to be self-sufficient and will walk you through whatever material you need to understand a particular topic. Do keep in mind, though, that different aspects of chemistry are very much interrelated. Even though a chapter might be set up to be self-contained, there are likely going to be things in that chapter you are assumed to understand from previous chapters. The concepts you learn in chemistry rarely go away; they pop up again and again when you’re learning new material so don’t hesitate to look back at whatever you might need to review.
You can use the table of contents at the beginning of the book and the index in the back to navigate your way to the topic that you need to brush up on. Regardless of your motivation or what technique you use to jump into the book, you won’t get lost because you can go in any direction from there.
Enjoy!
Unit 1
In This Unit …
Chapter 1: Looking at Numbers Scientifically
Using Exponential and Scientific Notation to Report Measurements
Multiplying and Dividing in Scientific Notation
Using Scientific Notation to Add and Subtract
Distinguishing between Accuracy and Precision
Identifying Significant Figures
Doing Arithmetic with Significant Figures
Qualitative and Quantitative Observations
Practice Questions Answers and Explanations
Whaddya Know? Chapter 1 Quiz
Answers to Chapter 1 Quiz
Chapter 2: Using and Converting Units
Familiarizing Yourself with Base Units and Metric System Prefixes
Looking at Density
Using Conversion Factors
Working with the Factor Label Method
Practice Questions Answers and Explanations
Whaddya Know? Chapter 2 Quiz
Answers to Chapter 2 Quiz
Chapter 3: The Basic Properties of Matter
Describing the States of Matter
Classifying Pure Substances and Mixtures
Nice Properties You’ve Got There
Practice Questions Answers and Explanations
Whaddya Know? Chapter 3 Quiz
Answers to Chapter 3 Quiz
Chapter 4: Breaking Down Atoms into Their Subatomic Particles
The Atom: Protons, Electrons, and Neutrons
A Brief History of the Atom
Deciphering Chemical Symbols: Atomic and Mass Numbers
Keeping an Eye on Ions
Accounting for Isotopes Using Atomic Masses
Practice Questions Answers and Explanations
Whaddya Know? Chapter 4 Quiz
Answers to Chapter 4 Quiz