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The determination of food authenticity is a vital component of quality control. Its importance has been highlighted in recent years by high-profile cases in the global supply chain such as the European horsemeat scandal and the Chinese melamine scandal which led to six fatalities and the hospitalisation of thousands of infants. As well as being a safety concern, authenticity is also a quality criterion for food and food ingredients. Consumers and retailers demand that the products they purchase and sell are what they purport to be.
This book covers the most advanced techniques used for the authentication of a vast number of products around the world. The reader will be informed about the latest pertinent analytical techniques. Chapters focus on the novel techniques & markers that have emerged in recent years. An introductory section presents the concepts of food authentication while the second section examines in detail the analytical techniques for the detection of fraud relating to geographical, botanical, species and processing origin and production methods of food materials and ingredients. Finally, the third section looks at consumer attitudes towards food authenticity, the application of bioinformatics to this field, and the Editor’s conclusions and future outlook.
Beyond being a reference to researchers working in food authentication it will serve as an essential source to analytical scientists interested in the field and food scientists to appreciate analytical approaches. This book will be a companion to under- and postgraduate students in their wander in food authentication and aims to be useful to researchers in universities and research institutions.
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Veröffentlichungsjahr: 2017
Cover
Title Page
Copyright
List of Contributors
Preface
Part A: Introduction and Status
Chapter 1: Introduction, Definitions and Legislation
1.1 Introduction
1.2 Definitions
1.3 Geographical Indications
1.4 Organics
1.5 Conclusion
References
Legislation Acts
Chapter 2: Food Authentication by Numbers
2.1 Introduction
2.2 Research Trends
2.3 Analytical Techniques
2.4 Countries
2.5 Journals
References
Part B: Consumer Attitudes Towards Authentic Food and Market Analysis
Chapter 3: The Concept of Authenticity and its Relevance to Consumers: Country and Place Branding in the Context of Food Authenticity
3.1 Introduction: The Challenge of Authenticity
3.2 Countries as Brands: The Country-of-Origin (COO) Effect on Product Choices
3.3 Place Branding: Geographic Indication Labels and their Effect on Food Choice
3.4 Conclusion: Towards a Definiton of Authenticity in a Business Context
Acknowledgements
References
Part C: Geographical, Botanical, and Species Origin, Method of Production and Food Frauds Detection
Chapter 4: Elemental Fingerprinting
4.1 Introduction
4.2 Elemental Techniques
4.3 Sample Preparation: Pretreatment
4.4 Applications
4.5 Conclusions and Outlook
References
Chapter 5: Isotopic Fingerprinting
5.1 Light Isotopes
5.1.1 Introduction
5.1.2 Application of Stable Isotope Ratios in Food Control
References
5.2 Heavy Isotopes
5.2.1 Introduction
5.2.2 Quality vs. Geographical Traceability
5.2.3 The Isotopic Approach to Food Traceability
5.2.4 Bioavailability
References
Legislation
Chapter 6: Nuclear Magnetic Resonance – Metabolomics
6.1 Introduction
6.2 Olive Oils
6.3 NMR for Investigating Fruit Metabolomics
6.4 NMR Metabolomics of Transgenic Vegetable Food
References
Chapter 7: Chromatography
7.1 Introduction to Chromatography – Techniques
7.1.1 Introduction
7.1.2 Chromatography
Acknowledgements
References
7.2 Chromatography – Applications
7.2.1 Introduction
7.2.2 Carbohydrates
7.2.3 Food Proteins and Peptides
7.2.4 Fatty Acids and Triacylglicerols
7.2.5 Volatile Compounds
7.2.6 Phenolic Compounds
7.2.7 Organic Acids
7.2.8 Conclusions
Acknowledgements
References
Chapter 8: Vibrational and Fluorescence Spectroscopy
8.1 Vibrational Spectroscopy
8.1.1 Introduction
8.1.2 Instrumentation and Software
8.1.3 Applications of Vibrational Spectroscopy in Food Authenticity
8.1.4 Concluding Remarks and Future Perspectives
References
8.2 Fluorescence Spectroscopy
8.2.1 Fluorescence
8.2.2 Chemometrics
8.2.3 Applications in Foods and Drinks
8.2.4 Conclusions and Perspectives
References
Chapter 9: Molecular Techniques – Genomics and Proteomics
9.1 Introduction
9.2 DNA-Based Methods
9.3 Proteomics for Species and Geographical Origin Authentication
9.4 Future Trends
References
Chapter 10: Immunological Techniques
10.1
Introduction
10.2
Immunoassays
10.3
Meat Speciation
10.4
Fish and Shellfish Authentication
10.5
Fruit Juices
10.6
Botanical Origin of Honey
10.7
Irradiated and Genetically Modified Foods
10.8
Conclusions
References
Chapter 11: Sensory Analysis
11.1 Introduction
11.2 Organoleptic Evaluation and Food Quality
11.3 Human Sensory Panels: Response and Subjectivity
11.4 Instrumental Sensory Analysis
11.5 Future Trends
References
Chapter 12: MALDI Mass Spectrometry: A Promising Non-Chromatographic Technique
12.1 Introduction
12.2 MALDI MS Principles
12.3 MALDI-TOF-MS for Food Proteins and Peptides Analysis
12.4 MALDI-TOF-MS for Lipids Analysis
12.5 MALDI-TOF-MS for Illegal Mixture Detection
12.6 MALDI-TOF-MS for Microbial Contamination Detection
Acknowledgements
References
Chapter 13: Detection of Food Processing Techniques
13.1 Introduction
13.2 Freezing–Thawing
13.3 Irradiation
13.4 Heating Techniques
13.5 Conclusion
References
Chapter 14: Adulteration Stories
14.1 Introduction
14.2 A Flashback
14.3 Food Fraud Incidents
14.4 Conclusions
References
Chapter 15: Organic Foods
15.1 Introduction
15.2 Biochemical Markers and Analytical Platforms
15.3 Sampling
15.4 Sample Preparation and Extraction
15.5 Instrumental Analysis
15.6 Data Analysis
15.7 Conclusions and Future Trends
References
Chapter 16: Screening and High-Throughput Multi-Contaminants Methods
16.1 Introduction
16.2 Sample Preparation
16.3 Separation and Detection
16.4 Conclusions
References
Chapter 17: Chemometrics – Bioinformatics
17.1 The Role of Chemometrics in Food Authentication
17.2 Methodology
References
Chapter 18: Conclusions and Prospects
References
Index
End User License Agreement
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cover
Table of Contents
Preface
Part A: Introduction and Status
Begin Reading
Chapter 3: The Concept of Authenticity and its Relevance to Consumers: Country and Place Branding in the Context of Food Authenticity
Table 3.1 Research areas on COO effect
Table 3.2 Means, standard deviations and statistically significant differences of clusters, CET-SCALE (
n
=274).
Table 3.4 Mediterranean diet (Rockefeller Foundation 1948, adapted from Helsing 1995). Sources of calories consumed (%) in Crete
a
and the US
b
1948
Table 3.5 Conjoint factors and factor levels per country.
Table 3.6 Sample's purchasing frequencies (selection), %,
N
=997
Table 3.7 Cluster's quality food purchasing pattern (%),
N
=997. Bold font: highest value; italics font: lowest value
Table 3.8 Cluster's quality food purchasing profiles (products with statistically significant difference among the clusters), %.
Table 3.9 Product categorisation and observed performance measures.
Table 3.10 DMD (attribute) and BBD (attribute level) polarisation
ϕ
v. market share.
Chapter 4: Elemental Fingerprinting
Table 4.1 Common ICP-MS interferences.
Table 4.2 ICP-MS comparison with other spectroscopic techniques
Table 8.2.1 List of food-fluorophores.
Chapter 9: Molecular Techniques – Genomics and Proteomics
Table 9.1 Summary of the DNA-based methods applied to food authentication.
Table 9.2 Summary of the proteomics-based methods applied to food authentication.
Chapter 10: Immunological Techniques
Table 10.1 Immunoassays for meat species identification.
Chapter 12: MALDI Mass Spectrometry: A Promising Non-Chromatographic Technique
Table 12.1 List of some common used UV-MALDI matrices.
Chapter 13: Detection of Food Processing Techniques
Table 13.1 Standardized EU analytical methods for the detection of irradiated foodstuffs.
Chapter 15: Organic Foods
Table 15.1 Selected examples of analytical platform discriminating between organic and conventional.
Chapter 16: Screening and High-Throughput Multi-Contaminants Methods
Table 16.1 Recent advances in MRMs methods (NA: not available)
Edited by Constantinos A. Georgiou and Georgios P. Danezis
Agricultural University of Athens, Greece
This edition first published 2017 © 2017 John Wiley & Sons Ltd
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Library of Congress Cataloging-in-Publication Data:
Names: Georgiou, Constantinos A.; Danezis, Georgios P., editors.
Title: Food authentication : management, analysis and regulation / [edited by] Constantinos A. Georgiou.
Description: Chichester, UK ; Hoboken, NJ : John Wiley & Sons, 2017. | Includes bibliographical references and index.
Identifiers: LCCN 2016055351| ISBN 9781118810262 (cloth) | ISBN 9781118810255 (epub)
Subjects: LCSH: Food industry and trade-Safety measures. | Food supply-Management. | Food-Quality control.
Classification: LCC TP373.5 .F6635 2017 | DDC 363.19/26-dc23 LC record available at https://lccn.loc.gov/2016055351
Cover Images: (Background) 97/Gettyimages; (Circles: Top to bottom) Hurst Photo/Shutterstock; nevodka/Shutterstock; Pannonia/Gettyimages
Cover Design: Wiley
Laura Aceña
Department of Analytical Chemistry and Organic Chemistry
Universitat Rovira i Virgili
Tarragona
Spain
Jorge Barros-Velázquez
Department of Analytical Chemistry Nutrition and Food ScienceSchool of Veterinary Sciences/College of Biotechnology
University of Santiago de Compostela
Lugo
Spain
Lucia Bertacchini
Department of Chemical and Geological SciencesUniversity of Modena and Reggio Emilia
Modena
Italy
Karola Böhme
International Iberian Nanotechnology Laboratory (INL)
Braga
Portugal
Ricard Boqué
Department of Analytical Chemistry and Organic Chemistry
Universitat Rovira i Virgili
Tarragona
Spain
Olga Busto
Department of Analytical Chemistry and Organic Chemistry
Universitat Rovira i Virgili
Tarragona
Spain
Pilar Calo-Mata
Department of Analytical Chemistry Nutrition and Food ScienceSchool of Veterinary Sciences/College of Biotechnology
University of Santiago de Compostela
Lugo
Spain
Cosima D. Calvano
Dipartimento di ChimicaUniversità degli Studi di Bari Aldo Moro
Bari
Italy
Donatella Capitani
Laboratorio di Risonanza Magnetica “Annalaura Segre”
Istituto di Metodologie Chimiche CNR Area della Ricerca di Roma
Rome
Italy
Marina Cocchi
Department of Chemical and Geological Sciences
University of Modena and Reggio Emilia
Modena
Italy
Marta Corzo-Martínez
Instituto de Investigación en Ciencias de la Alimentación, CIAL (CSIC-UAM)
Madrid
Spain
Daniel Cozzolino
Central Queensland UniversitySchool of Medical and Applied Sciences
Central Queensland Innovation and Research Precinct
Rockhampton
Australia
Gabriela Cristea
National Institute for Research and Development of Isotopic and Molecular Technologies
Cluj-Napoca
Romania
Georgios P. Danezis
Chemistry Laboratory, Department of Food Science and Human Nutrition
Agricultural University of Athens
Athens
Greece
Caterina Durante
Department of Chemical and Geological Sciences
University of Modena and Reggio Emilia
Modena
Italy
Constantinos A. Georgiou
Chemistry Laboratory, Department of Food Science and Human Nutrition
Agricultural University of Athens
Athens
Greece
Yun-Hwa Peggy Hsieh
Department of Nutrition, Food and Exercise Sciences
Florida State University
Florida
USA
Natasa P. Kalogiouri
Laboratory of Analytical Chemistry Department of Chemistry
National and KapodistrianUniversity of Athens
Athens
Greece
Athanasios Krystallis
MAPP Centre
Aarhus University
Aarhus
Denmark
Mario Li Vigni
Department of Chemical and Geological Sciences
University of Modena and Reggio Emilia
Modena
Italy
Dana Alina Magdas
National Institute for Research and Development of Isotopic and Molecular Technologies
Cluj-Napoca
Romania
Luisa Mannina
Dipartimento di Chimica e Tecnologie del Farmaco
Sapienza Università di Roma
Rome
Italyand
Laboratorio di Risonanza Magnetica
“Annalaura Segre”Istituto di Metodologie ChimicheCNR Area della Ricerca di Roma
Rome
Italy
Andrea Marchetti
Department of Chemical and Geological SciencesUniversity of Modena and Reggio Emilia
Modena
Italy
Fotini Mellou
Institute of Theoretical and Physical Chemistry
National Hellenic Research Foundation
Athens
Greece
Montserrat Mestres
Department of Analytical Chemistry and Organic Chemistry
Universitat Rovira i Virgili
Tarragona
Spain
Antonio Monopoli
Dipartimento di Chimica
Università degli Studi di Bari Aldo Moro
Bari
Italy
F. Javier Moreno
Instituto de Investigación en Ciencias de la Alimentación
CIAL (CSIC-UAM)
Madrid
Spain
Georgios Mousdis
Institute of Theoretical and Physical Chemistry
National Hellenic Research Foundation
Athens
Greece
Jack Appiah Ofori
Department of Nutrition, Food and Exercise Sciences
Florida State University
Florida
USA
M. Beatriz P.P. Oliveira
REQUIMTE, Chemical Sciences Department, Faculty of Pharmacy
University of Porto
Porto
Portugal
Ignacio Ortea
Department of Food Chemistry
Institute for Marine Research Spanish National Research Council
Vigo
Spain
and
Institute for Reference Materials and Measurements (EC-JRC-IRMM)
Geel
Belgium
Constantinos A. Papachristidis
Chemistry Laboratory, Department of Food Science and Human Nutrition
Agricultural University of Athens
Athens
Greece
Yolanda Picó
Environmental and Food Safety Research Group (SAMA-UV)Desertification Research Centre (CIDE) UV-GV-CSIC and Department of Medicine PreventiveFaculty of Pharmacy
University of València
València
Spain
Ana I. Ruiz-Matute
Instituto de Química Orgánica General (CSIC)
Madrid
Spain
Joana Santos
REQUIMTE, Chemical Sciences Department, Faculty of Pharmacy
University of Porto
Porto
Portugal
M. Luz Sanz
Instituto de Química Orgánica General (CSIC)
Madrid
Spain
Anatoly P. Sobolev
Laboratorio di Risonanza Magnetica “Annalaura Segre”
Istituto di Metodologie Chimiche CNR Area della Ricerca di Roma
Rome
Italy
Demetrios G. Sotirchos
Chemistry Laboratory, Department of Food Science and Human Nutrition
Agricultural University of AthensAthens
Greece
Nikolaos S. Thomaidis
Laboratory of Analytical Chemistry Department of ChemistryNational and Kapodistrian
University of Athens
Athens
Greece
Aristidis S. Tsagkaris
Chemistry Laboratory, Department of Food Science and Human Nutrition
Agricultural University of Athens
Athens
Greece
Carlo G. Zambonin
Dipartimento di ChimicaUniversità degli Studi di Bari Aldo Moro
Bari
Italy
Food Authentication: Management, Analysis and Regulation has been written by an international group of peers with high academic and research credentials. As well as providing a reference for researchers working in food authentication, it will serve as an essential source of information for analytical and food scientists in the field in who have an interest in analytical approaches. The book is also a companion for under- and postgraduate students in their study of food authentication, and aims to be useful to researchers in universities and research institutions.
We would like to acknowledge the generous contribution of all the chapter authors. The remarkable effort of the contributors that are leading scientists in their field is greatly appreciated. Further, we acknowledge Wiley staff for their helpful assistance through the development of this project. It has been a pleasure to work with all of you. Last, but not least, we thank our families for their support.
To our families,
Constantinos A. Georgiouand Georgios P. DanezisAgricultural University of Athens, GreeceDecember 2016
