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The third volume in a series of handbooks on graphene research and applications Graphene is a valuable nanomaterial used in technology. This handbook is focused on Graphene-Like 2D Materials. The Handbook of Graphene, Volume 3 covers topics that include planar graphene superlattices; magnetic and optical properties of graphene materials with porous defects; and nanoelectronic application of graphyne and its structural derivatives.
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Seitenzahl: 902
Veröffentlichungsjahr: 2019
Cover
Preface
Chapter 1: Proximity-Induced Topological Transition and Strain-Induced Charge Transfer in Graphene/MoS
2
Bilayer Heterostructures
1.1 Introduction
1.2 Results from the DFT Calculations
1.3 Model Hamiltonian and Topological Phase Transitions
1.4 Berry Curvature and Chern Number
1.5 Conclusions
1.6 Future Directions
Acknowledgments
1.7 Computational Details
References
Chapter 2: Planar Graphene Superlattices
2.1 Introduction
2.2 Superlattice Based on Graphene with Modulation of the Bandgap
2.3 Gapless Graphene Superlattice with Alternating Fermi Velocity
2.4 Polytype Superlattice
2.5 Conclusions
Acknowledgments
References
Chapter 3: Magnetic and Optical Properties of Graphene Materials with Porous Defects
3.1 Introduction
3.2 Electronic States of Porous Graphenes
3.3 Extended Porous Graphenes
3.4 Magnetism in the Oxidized or Reduced States
3.5 Negatively Curved Graphitic Materials
3.6 Optical Activities of [7]Circulene
3.7 Conclusion
Acknowledgments
References
Chapter 4: Graphynes: Advanced Carbon Materials with Layered Structure
4.1 Introduction
4.2 Classification System for Graphyne Compounds
4.3 Model Calculation Techniques
4.4 Calculations of L
6
-Graphyne Layers by Semiempirical Quantum–Mechanical Methods
4.5 Calculations of
L
6
-Graphyne Layers by the Method of the Density Functional Theory (DFT-GGA)
4.6 Calculations of
L
4-8
-Graphyne Layers by the Method of the Density Functional Theory (DFT-GGA)
4.7 Results and Discussion
4.8 Conclusion
References
Chapter 5: Nanoelectronic Application of Graphyne and Its Structural Derivatives
5.1 Introduction
5.2 Computational Details
5.3 Results and Discussion
5.4 Conclusions and Perspectives
Acknowledgment
References
Chapter 6: Twisted Bilayer Graphene: Low-Energy Physics, Electronic and Optical Properties
6.1 Introduction
6.2 Basics of Monolayer and Bilayer Graphene
6.3 Twisted Bilayer Graphene
6.4 Optical Response
6.5 Conclusions and Future Work
Acknowledgment
References
Chapter 7: Effects of Charged Coulomb Impurities on Low-Lying Energy Spectra in Graphene Magnetic Dot and Ring
7.1 Introduction
7.2 Formalism for Our Theoretical Studies
7.3 Results for Magnetic Dot/Ring Using the DW Model
7.4. Summary for the Present Study
Acknowledgment
References
Chapter 8: Graphene in Bioelectronics
8.1 Introduction
8.2 Unique Properties of Graphene
8.3 Applications of Graphene
8.4 Graphene in Bioelectronics
8.5 Conclusions and Outlook
References
Chapter 9: Graphene Metamaterial Electron Optics: Excitation Processes and Electro-Optical Modulation
9.1 Linear 2D Electron Waves in Nonuniform Graphene Metamaterials: Solid-State Graphene Metamaterial Electron Optics
9.2. Excitation Processes in Bilayer Graphene
9.3 Graphene Electro-Optical Modulators Operating from Near-Infrared to Visible Spectrum Range
References
Chapter 10: Linear Carbon: From 1D Carbyne to 2D Hybrid
sp-sp
2
Nanostructures Beyond Graphene
10.1 Introduction
10.2 From 1D Carbyne to 2D Hybrid
sp-sp
2
Carbon Nanostructures Beyond Graphene: An Historical Perspective
10.3 Carbyne: Structure and Properties
10.4 From Carbyne to Nanostructures: Carbon Atomic Wires
10.5 Toward 2D Hybrid
sp-sp
2
Carbon Systems
10.6 Synthesis of CAWs and
sp-sp
2
Carbon Systems
10.7 Raman Spectroscopy of sp-Carbon
10.8 Potential Applications
Acknowledgments
References
Chapter 11: Band Structure Modifications in Beyond Graphene Materials
11.1 Introduction
11.2 Materials Beyond Graphene
11.3 Transition Metal Dichalcogenides
11.4 Hall Effect in TMDs
11.5 Concluding Remarks
References
Chapter 12: Chemically Modified 2D Materials: Production and Applications
12.1 Introduction
12.2 2D Materials Production
12.3 Chemical Modification of 2D
12.4 Relevant Applications of 2D Materials
12.5 Outlook and Conclusions
Acknowledgments
References
Chapter 13: Black Phosphorus Saturable Absorber for Passive Mode-Locking Pulses Generation
13.1 Introduction
13.2 Saturable Absorber Mechanism
13.3 Black Phosphorus (BP)
13.4 Fabrication of BP Thin Flakes
13.5 BP Thin Flakes Characterization
13.6 Measurement of Pulsed Laser Performances
13.7 Mode-Locked Erbium-Doped Fiber Laser (EDFL) at 1.55-Micron Region
13.8 Mode-Locked Ytterbium-Doped Fiber Laser (YDFL) at 1-Micron Region
13.9 Mode-Locked Thulium-Doped Fiber Laser (TDFL) at 2-Micron Region
13.10 Mode-Locked Thulium Holmium Co-Doped Fiber Laser (THDFL) at 2-Micron Region
13.11 Conclusion
References
Chapter 14: Search for Fundamental Physics on Table Top Experiments with Dirac–Weyl Materials
14.1 Introduction
14.2 Low Energy Dirac–Weyl Semi-Metals
14.3 Lagrangian of Quantum Electrodynamics
14.4 Dirac Lagrangian
14.5 Maxwell Lagrangian
14.6 QED
3
Lagrangian
14.7 Dirac Lagrangian
14.8 Maxwell Lagrangian
14.9 Chern–Simons Lagrangian
14.10 QED
3
Lagrangian
14.11 Reduced QED
14.12 Generation of Masses
14.13 SDE Framework
14.14 Gap Equation in QED
3
14.15 Mass Generation in QED
3
Plus Chern–Simons
14.16 Mass Generation in RQED
14.17 Including Vacuum Polarization Effects
14.18 Conserved Currents in Weyl Materials
14.19 The Chiral Anomaly
14.20 The Chiral Magnetic Effect
14.21 The Pseudo-Chiral Magnetic Effect
14.22 Concluding Remarks
Acknowledgments
References
Index
End User License Agreement
Cover
Table of Contents
Begin Reading
Chapter 3
Table 3.1
Summary of spin gaps for 16
2+
, 16
2–
, 17
2+
…
Table 3.2
Summary of spin gaps for 18
3+
, 18
3
−
,…
Chapter 4
Table 4.1
Values of the Wells ring parameters (Rng), characterizing the atoms positions in…
Table 4.2
Lengths of C–C interatomic bonds
L
i
(Å) in the…
Table 4.3
Parameters of graphynes with C atoms in the two- and three-coordinated states…
Table 4.4
Sublimation energy (kcal/mole) of carbon layers, consisting of carbon atoms in the…
Table 4.5
Numerical values of the graphyne structural parameters (Hex — hexagonal,…
Table 4.6
Lengths of C-C interatomic bonds and the angles between interatomic bonds in the…
Table 4.7
Lengths of C–C interatomic bonds L
ij
and their orders χ in…
Table 4.8
The structural parameters of the graphene and graphynes of the basic polymorphs,…
Chapter 5
Table 5.1
Calculated lattice constant, bond length of
C
ring
–…
Table 5.2
Obtained lattice constant; interlayer distance, binding energy, and energy band…
Table 5.3
Calculated lattice vectors, magnetic moment and cohesive energy of boron and…
Chapter 7
Table 7.1
Comparison between Schrodinger model and DW model in the presence of uniform…
Chapter 9
Table 9.1
Normalizing, scales, and orders of magnitudes for the electron waves in graphene…
Chapter 10
Table 10.1
sp
/
sp
2
ratio, carbon atoms per unit cell and layer…
Table 10.2
Properties of carbyne or carbon atom wires resulting either from theoretical…
Chapter 13
Table 13.1
Pulse characterization.
Cover
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Scrivener Publishing100 Cummings Center, Suite 541JBeverly, MA 01915-6106
Publishers at ScrivenerMartin Scrivener ([email protected])Phillip Carmical ([email protected])
Handbook of Graphene comprises 8 volumes:
Volume 1: Growth, Synthesis, and FunctionalizationEdited by Edvige Celasco and Alexander ChaikaISBN 978-1-119-46855-4
Volume 2: Physics, Chemistry, and BiologyEdited by Tobias StauberISBN 978-1-119-46959-9
Volume 3: Graphene-Like 2D MaterialsEdited by Mei ZhangISBN 978-1-119-46965-0
Volume 4: CompositesEdited by Cengiz OzkanISBN 978-1-119-46968-1
Volume 5: Energy, Healthcare, and Environmental ApplicationsEdited by Cengiz Ozkan and Umit OzkanISBN 978-1-119-46971-1
Volume 6: Biosensors and Advanced SensorsEdited by Barbara PalysISBN 978-1-119-46974-2
Volume 7: BiomaterialsEdited by Sulaiman Wadi HarunISBN 978-1-119-46977-3
Volume 8: Technology and InnovationEdited by Sulaiman Wadi HarunISBN 978-1-119-46980-3
Edited by Mei Zhang
High-Performance Materials Institute,Florida State University,Tallahassee, Florida, USA
This edition first published 2019 by John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, USA and Scrivener Publishing LLC, 100 Cummings Center, Suite 541J, Beverly, MA 01915, USA © 2019 Scrivener Publishing LLC For more information about Scrivener publications please visit www.scrivenerpublishing.com.
All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, except as permitted by law. Advice on how to obtain permission to reuse material from this title is available at http://www.wiley.com/go/permissions.
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For details of our global editorial offices, customer services, and more information about Wiley products visit us at www.wiley.com.
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Library of Congress Cataloging-in-Publication Data
ISBN 978-1-119-46965-0
Despite being just a one-atom-thick sheet of carbon, graphene is one of the most valuable nanomaterials. Initially discovered through scotch-tape-based mechanical exfoliation, graphene can now be synthesized in bulk using various chemical techniques. Counted among the contrasting properties of this remarkable material are its lightweight, thinness, flexibility, transparency, strength, and resistance, along with superior electrical, thermal, mechanical, and optical properties. Due to these novel traits, graphene has attracted attention for use in cutting-edge applications in almost every area of technology, which are projected to change the world.
The Handbook of Graphene is presented in a unique eight-volume format covering all aspects relating to graphene—its development, synthesis, application techniques, and integration methods; its modification and functionalization; its characterization tools and related 2D materials; physical, chemical, and biological studies of graphene and related 2D materials; graphene composites; use of graphene in energy, healthcare, and environmental applications (electronics, photonics, spintronics, bioelectronics and optoelectronics, photovoltaics, energy storage, fuel cells and hydrogen storage, and graphene-based devices); its large-scale production and characterization; as well as graphene-related 2D material innovations and their commercialization.
This third volume of the handbook is solely focused on Graphene-Like 2D Materials. Some of the important topics include but are not limited to proximity-induced topological transition and strain-induced charge transfer in graphene/MoS2 bilayer heterostructures; planar graphene superlattices; magnetic and optical properties of graphene materials with porous defects; graphynes: advanced carbon materials with layered structure; nanoelectronic application of graphyne and its structural derivatives; twisted bilayer graphene: low-energy physics, electronic, and optical properties; effects of charged coulomb impurities on low-lying energy spectra in graphene magnetic dot and ring; graphene in bioelectronics; graphene metamaterial electron optics: excitation processes and electro-optical modulation; linear carbon: from 1D carbyne to 2D hybrid sp–sp2 nanostructures beyond graphene; band structure modifications in beyond graphene materials; chemically modified 2D materials: production and applications; black phosphorus saturable absorber for passive mode-locking pulses generation; and search for fundamental physics on table-top experiments with Dirac–Weyl materials.
In conclusion, thank you to all the authors whose expertise in their respective fields have contributed to this book as well as a sincere appreciation to the International Association of Advanced Materials.
