Interface / Interphase in Polymer Nanocomposites E-Book
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- Herausgeber: John Wiley & Sons
- Kategorie: Fachliteratur
- Serie: Adhesion and Adhesives - Fundamental and Applied Aspects
- Sprache: Englisch
Significant research has been done in polymeric nanocomposites and progress has been made in understanding nanofiller-polymer interface and interphase and their relation to nanocomposite properties. However, the information is scattered in many different publication media. This is the first book that consolidates the current knowledge on understanding, characterization and tailoring interfacial interactions between nanofillers and polymers by bringing together leading researchers and experts in this field to present their cutting edge research. Eleven chapters authored by senior subject specialists cover topics including: * Thermodynamic mechanisms governing nanofiller dispersion, engineering of interphase with nanofillers * Role of interphase in governing the mechanical, electrical, thermal and other functional properties of nanocomposites, characterization and modelling of the interphase * Effects of crystallization on the interface, chemical and physical techniques for surface modification of nanocellulose reinforcements * Electro-micromechanical and nanoindentation techniques for interface evaluation, molecular dynamics (MD) simulations to quantify filler-matrix adhesion and nanocomposite mechanical properties.
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Seitenzahl: 711
Veröffentlichungsjahr: 2016
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Contents
Cover
Title page
Copyright page
Preface
Part 1: Nanocomposite Interfaces/Interphases
Chapter 1: Polymer Nanocomposite Interfaces: The Hidden Lever for Optimizing Performance in Spherical Nanofilled Polymers
1.1 Introduction
1.2 Dispersion Control through Interfacial Modification
1.3 Interface Structure
1.4 Interface Properties and Characterization Techniques
1.5 Summary
Acknowledgements
References
Chapter 2: Interphase Engineering with Nanofillers in Fiber-Reinforced Polymer Composites
2.1 Introduction
2.2 Interphase Tailoring for Stress Transfer
2.3 Interphase Tailoring for Functionality
2.4 Outlook and Future Trends
2.5 Summary
Acknowledgements
Nomenclature
References
Chapter 3: Formation and Functionality of Interphase in Polymer Nanocomposites
3.1 Introduction
3.2 Formation of Interphase in Polymer Nanocomposites
3.3 Functionality of Interphase in Polymer Nanocomposites
3.4 Summary and Prospects
Acknowledgements
References
Chapter 4: Impact of Crystallization on the Interface in Polymer Nanocomposites
4.1 Introduction
4.2 Thermodynamics of Crystallization
4.3 Nylon Nanocomposites
4.4 PET Nanocomposites
4.5 PEN Nanocomposites
4.6 Summary
Acknowledgements
References
Chapter 5: Improved Nanofiller-Matrix Bonding and Distribution in GnP-reinforced Polymer Nanocomposites by Surface Plasma Treatments of GnP
5.1 Introduction
5.2 Experimental
5.3 Results
5.4 Conclusions
Acknowledgement
References
Chapter 6: Interfacial Effects in Polymer Nanocomposites Studied by Thermal and Dielectric Techniques
6.1 Introduction
6.2 Experimental Techniques
6.3 Evaluation in Terms of Interfacial Characteristics
6.4 Examples
6.5 Prospects
6.6 Summary
Abbreviations
Symbols
Greek Symbols
Acknowledgements
References
Part 2: Techniques to Characterize/Control Nanoadhesion
Chapter 7: Investigation of Interfacial Interactions between Nanofillers and Polymer Matrices Using a Variety of Techniques
7.1 Introduction
7.2 Observation of Interfacial Layer in Nanostructured Carbon Materials-based Nanocomposites
7.3 Interfacial Properties between Nanofiller and Polymer Matrix
7.4 Summary
Acknowledgements
References
Chapter 8: Chemical and Physical Techniques for Surface Modification of Nanocellulose Reinforcements
8.1 Introduction
8.2 Chemical Surface Modification
8.3 Physical Surface Modification
8.4 Summary
Acknowledgments
References
Chapter 9: Nondestructive Sensing of Interface/Interphase Damage in Fiber/Matrix Nanocomposites
9.1 Introduction
9.2 Experimental Specimens and Methods
9.3 Damage Sensing Using Electrical Resistance Measurements
9.4 Summary
References
Chapter 10: Development of Polymeric Biocomposites: Particulate Incorporation, Interphase Generation and Evaluation by Nanoindentation
10.1 Introduction
10.2 The Definitions of Composite and its Constituents
10.3 Physical and Chemical Structures of Bio–based Reinforcements
10.4 Particulate and Short Fibre Composites
10.5 Nanoindentation Technique to Determine Interphase and Composite Properties
10.6 Concluding Remarks
References
Chapter 11: Perspectives on the Use of Molecular Dynamics Simulations to Characterize Filler-Matrix Adhesion and Nanocomposite Mechanical Properties
11.1 Introduction
11.2 Overview of Molecular Dynamics (MD) Simulations
11.3 Characterization of Interfacial Adhesion with MD Simulations
11.4 Characterization of Mechanical Properties with MD Simulations
11.5 Prospects
11.6 Summary
Acknowledgements
References
Index
End User License Agreement
Guide
Cover
Copyright
Contents
Begin Reading
List of Tables
Chapter 3
Table 3.1
Comparison of number and total surface area of particles in composites reinforced by various carbon-based particles.
Table 3.2
Issues addressing the formation of interphases in polymer nano composites reinforced by carbon-based nanofillers.
Chapter 4
Table 4.1
DSC results of nylon and nanocomposites in the first heating [22].
Table 4.2
DSC results of nylon and nanocomposites in the first cooling [22].
Table 4.3
DSC results of nylon and nanocomposites in the second heating [22].
Table 4.4
DSC results of nylon and nanocomposites in the second cooling [22].
Table 4.5
DSC data analysis of the results of PET and nanocomposites in the first heating.
Table 4.6
DSC data analysis of the results of PET and nanocomposites in the first cooling.
Table 4.7
DSC data analysis of the results of PET and nanocomposites in the second heating.
Table 4.8
DSC data analysis of the results of PET and nanocomposites in the second cooling.
Table 4.9
DSC data analysis results of PEN and nanocomposites in the first heating.
Table 4.10
DSC data analysis results of PEN and nanocomposites in the first heating for cold crystallization peak.
Table 4.11
DSC data analysis results of PEN and nanocomposites in the first cooling.
Table 4.12
DSC data analysis results of PEN and nanocomposites in the second heating.
Table 4.13
DSC data analysis results of PEN and nanocomposites in the second cooling.
Table 4.14
Helium permeability of PEN and nanocomposites.
Chapter 5
Table 5.1
Elemental compositions of functionalized GnPs shown in atomic %.
Table 5.2
Comparison of XPS data showing functional group distributions for untreated (raw) GnP, standard plasma treated O
2
-GnP, and extended plasma treated O
2
-GnP specimens.
Table 5.3
Tensile strength of epoxy composites fabricated using raw (untreated GnP), standard O
2
-GnP, and extended O
2
-GnP as a function of loading concentration of GnP.
Table 5.4
Tensile modulus of epoxy composites manufactured using raw (untreated GnP), standard O
2
-GnP, and extended O
2
-GnP as a function of loading concentration of GnP.
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Scrivener Publishing100 Cummings Center, Suite 541JBeverly, MA 01915-6106
Adhesion and Adhesives: Fundamental and Applied Aspects
The topics to be covered include, but not limited to, basic and theoretical aspects of adhesion; modeling of adhesion phenomena; mechanisms of adhesion; surface and interfacial analysis and characterization; unraveling of events at interfaces; characterization of interphases; adhesion of thin films and coatings; adhesion aspects in reinforced composites; formation, characterization and durability of adhesive joints; surface preparation methods; polymer surface modification; biological adhesion; particle adhesion; adhesion of metallized plastics; adhesion of diamond-like films; adhesion promoters; contact angle, wettability and adhesion; superhydrophobicity and superhydrophilicity. With regards to adhesives, the Series will include, but not limited to, green adhesives; novel and high-performance adhesives; and medical adhesive applications.
Series Editor: Dr. K.L. Mittal 1983 Route 52, P. O. Box 1280, Hopewell Junction, NY 12533, USA Email: [email protected]
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