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From materials to applications, this ready reference covers the entire value chain from fundamentals via processing right up to devices, presenting different approaches to large-area electronics, thus enabling readers to compare materials, properties and performance. Divided into two parts, the first focuses on the materials used for the electronic functionality, covering organic and inorganic semiconductors, including vacuum and solution-processed metal-oxide semiconductors, nanomembranes and nanocrystals, as well as conductors and insulators. The second part reviews the devices and applications of large-area electronics, including flexible and ultra-high-resolution displays, light-emitting transistors, organic and inorganic photovoltaics, large-area imagers and sensors, non-volatile memories and radio-frequency identification tags. With its academic and industrial viewpoints, this volume provides in-depth knowledge for experienced researchers while also serving as a first-stop resource for those entering the field.

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Table of Contents

Cover

Related Titles

Title Page

Copyright

List of Contributors

Overview

Book Structure and Aim

Acknowledgments

References

Part I: Materials

Chapter 1: Polymeric and Small-Molecule Semiconductors for Organic Field-Effect Transistors

1.1 Introduction

1.2 Organic Semiconductor Structural Design

1.3 Thin-Film Transistor Applications

1.4 p-Channel Semiconductors

1.5 n-Channel Semiconductors

1.6 Ambipolar Semiconductors

1.7 Conclusions

References

Chapter 2: Metal-Oxide Thin-Film Transistors for Flexible Electronics

2.1 Introduction

2.2 Metal-Oxide TFTs

2.3 Solution-Processed MO Thin Films

2.4 Low-Temperature-Processed MO TFTs for Flexible Electronics

2.5 Summary

References

Chapter 3: Carbon Nanotube Thin-Film Transistors

3.1 Introduction

3.2 Individual SWCNTs and SWCNT Thin Films

3.3 Chemical Vapor Deposition Growth of SWCNT TFTs

3.4 Solution-Based Methods for SWCNT TFTs

3.5 Inkjet Printing of Flexible SWCNT TFTs

3.6 Fabrication Schemes for High-Performance Inkjet-Printed SWCNT TFTs

3.7 Inkjet Printing of SWCNT CMOS Inverters

3.8 Inkjet Printing of Aligned SWCNT Films

3.9 Conclusion

References

Chapter 4: Organic Single-Crystalline Semiconductors for Flexible Electronics Applications

4.1 Introduction

4.2 Electronic and Structural Properties of Single Crystals

4.3 Crystallization Techniques

4.4 Single-Crystal Flexible Electronic Devices

4.5 Strategies for Flexible Organic Single-Crystal Device Fabrication

4.6 Conclusions

Acknowledgments

References

Chapter 5: Solution-Processable Quantum Dots

5.1 Introduction

5.2 Optimization of the Colloidal Synthesis of Quantum Dots by Selection of Suitable Solvents, Ligands, and Precursors

5.3 Large-Scale Synthesis of Quantum Dots

5.4 Surface Chemistry of Quantum Dots

5.5 Post-Synthetic Chemical Modification of Nanocrystals

5.6 Conclusions and Outlook

References

Chapter 6: Inorganic Semiconductor Nanomaterials for Flexible Electronics

6.1 Introduction

6.2 Characteristics and Synthesis of Inorganic Semiconducting NMs

6.3 Applications in Flexible Electronics

6.4 Concluding Remarks

References

Chapter 7: Dielectric Materials for Large-Area and Flexible Electronics

7.1 Introduction

7.2 General Polymer Dielectrics

7.3 Cross-Linked Polymer Dielectrics

7.4 High-

k

Polymer Dielectrics

7.5 Electrolyte Gate Dielectrics

7.6 Self-Assembled Molecular Layer Dielectrics

7.7 Hybrid Dielectrics

7.8 Sol–Gel High-

k

Inorganic Dielectrics

7.9 Summary and Outlook

References

Chapter 8: Electrolyte-Gating Organic Thin Film Transistors

8.1 Introduction

8.2 Electrolyte-Gated OTFT Operation Mechanisms

8.3 Electrolyte Materials

8.4 OTFTs Gated with Electrolyte Dielectrics

8.5 Circuits Based on Electrolyte-Gated OTFTs

8.6 Conclusions

References

Chapter 9: Vapor Barrier Films for Flexible Electronics

9.1 Introduction

9.2 Thin-Film Permeation Barrier Layers

9.3 Permeation through Inorganic Thin Films

9.4 Time-Resolved Measurements on Barrier Layers

9.5 Mechanical Limitations of Inorganic Films

9.6 Mechanics of Films on Flexible Substrates

9.7 Summary

References

Chapter 10: Latest Advances in Substrates for Flexible Electronics

10.1 Introduction

10.2 Factors Influencing Film Choice

10.3 Film Property Set

10.4 Summary of Key Properties of Base Substrates

10.5 Planarizing Coatings

10.6 Examples of Film in Use

10.7 Concluding Remarks

Acknowledgments

References

Part II: Devices and Applications

Chapter 11: Inkjet Printing Process for Large Area Electronics

11.1 Introduction

11.2 Dynamics of Jet Formation

11.3 Ink Rheology: Non-Newtonian Liquids

11.4 Dynamics of Drop Impact and Spreading

11.5 Applications of Inkjet Printing for Large-Area Electronics

11.6 Summary

References

Chapter 12: Inkjet-Printed Electronic Circuits Based on Organic Semiconductors

12.1 Printed Organic Electronics

12.2 CMOS Technology

12.3 High-Speed Organic CMOS Circuits

12.4 Conclusions

References

Chapter 13: Large-Area, Printed Organic Circuits for Ambient Electronics

13.1 Introduction

13.2 Manufacturing Process and Electrical Characteristics

13.3 Demonstration

13.4 Future Prospects

Acknowledgments

References

Chapter 14: Polymer and Organic Nonvolatile Memory Devices

14.1 Introduction

14.2 Resistive Switching Memories

14.3 Charge Storage in Transistor Gate Dielectric

14.4 Polymer Ferroelectric Devices

14.5 Conclusions

References

Chapter 15: Flexible Displays

15.1 Introduction

15.2 Flexible Substrates

15.3 Display Mode

15.4 Thin-Film Transistor

15.5 AMOLED Panel with Printing Technology

15.6 Fabrication of the OLED and AMOLED Panel

15.7 Future Prospects

References

Chapter 16: Flexible Organic Solar Cells for Scalable, Low-Cost Photovoltaic Energy Conversion

16.1 Overview of Organic Photovoltaic (OPV) Cells

16.2 Efforts toward Realization of Flexible OSCs

16.3 Flexible OSCs for High-Throughput Production: A Printing-Based Approach to Low-Cost Solar Energy Conversion

16.4 Summary and Outlook

References

Chapter 17: Flexible Inorganic Photovoltaics

17.1 Introduction

17.2 Thin Crystalline Solar Cells Transferred onto Flexible Substrates

17.3 Thin-Film Solar Cells Grown Directly onto Flexible Substrates by Vapor Deposition

17.4 Solution-Processed Thin-Film Solar Cells Deposited Directly onto Flexible Substrates

17.5 Summary

References

Chapter 18: Scalable and Flexible Bioelectronics and Its Applicationsto Medicine

18.1 Biosensing and Bioelectronics: A Fast Growing Field and a Challenging Research Area

18.2 Inorganic and Silicon-Based Flexible Electronics for Biosensing Devices

18.3 EGOFETs for Flexible Biosensing

18.4 OECTs for Biosensing and Biomonitoring

18.5 Conclusions and Outlook

References

Index

EULA

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Guide

Cover

Table of Contents

Part I: Materials

Chapter 1: Polymeric and Small-Molecule Semiconductors for Organic Field-Effect Transistors

List of Illustrations

Figure 1

Figure 1.1

Figure 1.2

Figure 1.3

Figure 1.4

Figure 1.5

Figure 1.6

Figure 1.7

Figure 1.8

Figure 1.9

Figure 1.10

Figure 1.11

Figure 1.12

Figure 1.13

Figure 1.14

Figure 1.15

Figure 1.16

Figure 1.17

Figure 1.18

Figure 1.19

Figure 1.20

Figure 1.21

Figure 1.22

Figure 1.23

Figure 1.24

Figure 1.25

Figure 1.26

Figure 1.27

Figure 1.28

Figure 1.29

Figure 1.30

Figure 1.31

Figure 1.32

Figure 1.33

Figure 1.34

Figure 1.35

Figure 1.36

Figure 1.37

Figure 1.38

Figure 1.39

Figure 1.40

Figure 1.41

Figure 1.42

Figure 1.43

Figure 1.44

Figure 1.45

Figure 1.46

Figure 1.47

Figure 2.1

Figure 2.2

Figure 2.3

Figure 2.4

Figure 2.5

Figure 2.6

Figure 2.7

Figure 2.8

Figure 2.9

Figure 3.1

Figure 3.2

Figure 3.3

Figure 3.4

Figure 3.5

Figure 3.6

Figure 3.7

Figure 3.8

Figure 3.9

Figure 3.10

Figure 4.1

Figure 4.2

Figure 4.3

Figure 4.4

Figure 4.5

Figure 4.6

Figure 4.7

Figure 4.8

Figure 4.9

Figure 4.10

Figure 4.11

Figure 4.12

Figure 4.13

Figure 4.14

Figure 4.15

Figure 4.16

Figure 4.17

Figure 4.18

Figure 4.19

Figure 4.20

Figure 4.21

Figure 5.1

Figure 5.2

Figure 5.3

Figure 5.4

Figure 5.5

Figure 5.6

Figure 5.7

Figure 5.8

Figure 5.9

Figure 6.1

Figure 6.2

Figure 6.3

Figure 6.4

Figure 6.5

Figure 6.6

Figure 6.7

Figure 6.8

Figure 6.9

Figure 6.10

Figure 6.11

Figure 6.12

Figure 6.13

Figure 6.14

Figure 6.15

Figure 6.16

Figure 6.17

Figure 7.1

Figure 7.2

Figure 7.3

Figure 7.4

Figure 7.5

Figure 7.6

Figure 7.7

Figure 7.8

Figure 7.9

Figure 7.10

Figure 7.11

Figure 8.1

Figure 8.2

Figure 8.3

Figure 8.4

Figure 8.5

Figure 8.6

Figure 8.7

Figure 9.1

Figure 9.5

Figure 9.2

Figure 9.3

Figure 9.4

Figure 9.6

Figure 9.7

Figure 10.1

Figure 10.2

Figure 10.3

Figure 10.4

Figure 10.5

Figure 10.6

Figure 10.7

Figure 10.8

Figure 10.9

Figure 10.10

Figure 10.11

Figure 10.12

Figure 10.13

Figure 10.14

Figure 10.15

Figure 10.16

Figure 11.1

Figure 11.2

Figure 11.3

Figure 11.4

Figure 11.5

Figure 11.6

Figure 11.7

Figure 11.8

Figure 11.9

Figure 11.10

Figure 11.11

Figure 11.12

Figure 12.1

Figure 12.2

Figure 12.3

Figure 12.4

Figure 12.5

Figure 12.6

Figure 12.7

Figure 12.8

Figure 12.9

Figure 13.1

Figure 13.2

Figure 13.3

Figure 13.4

Figure 13.5

Figure 13.6

Figure 13.7

Figure 14.1

Figure 14.2

Figure 14.3

Figure 14.4

Figure 14.5

Figure 14.6

Figure 14.7

Figure 14.8

Figure 14.9

Figure 14.10

Figure 14.11

Figure 14.12

Figure 14.13

Figure 14.14

Figure 14.15

Figure 14.16

Figure 14.17

Figure 15.1

Figure 15.2

Figure 15.3

Figure 15.4

Figure 15.5

Figure 15.6

Figure 15.7

Figure 15.8

Figure 15.9

Figure 15.10

Figure 15.17

Figure 15.11

Figure 15.12

Figure 15.13

Figure 15.14

Figure 15.15

Figure 15.16

Figure 16.1

Figure 16.2

Figure 16.3

Figure 16.4

Figure 16.5

Figure 16.6

Figure 16.7

Figure 16.8

Figure 16.9

Figure 16.10

Figure 16.11

Figure 16.12

Figure 17.1

Figure 17.2

Figure 17.3

Figure 17.4

Figure 17.5

Figure 17.6

Figure 18.1

Figure 18.2

Figure 18.3

Figure 18.4

Figure 18.5

Figure 18.6

Figure 18.7

Figure 18.8

Figure 18.9

Figure 18.10

Figure 18.11

Figure 18.12

Figure 18.13

Figure 18.14

Figure 18.15

Figure 18.16

Figure 18.17

Figure 18.18

Figure 18.19

Figure 18.20

Figure 18.21

Figure 18.22

Figure 18.23

List of Tables

Table 4.1

Table 4.2

Table 5.1

Table 6.1

Table 6.2

Table 7.1

Table 9.1

Table 10.1

Table 10.2

Table 10.3

Table 11.1

Table 11.2

Table 12.1

Table 14.1

Table 14.2

Table 14.3

Table 15.1

Table 15.2

Table 15.3

Table 16.1

Table 18.1

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Edited by Mario Caironi and Yong-Young Noh

Large Area and Flexible Electronics

The Editors

 

Dr. Mario Caironi

Center for Nano Science and Technology @PoliMi

Istituto Italiano di Tecnologia

Via Pascoli, 70/3

20133 Milano

Italy

 

Prof. Yong-Young Noh

Dongguk University

Dept of Energy and Materials Engineering

26, Pil-dong, 3-ga, Jung-gu

100-715 Seoul

Republic of Korea

 

All books published by Wiley-VCH are carefully produced. Nevertheless, authors, editors, and publisher do not warrant the information contained in these books, including this book, to be free of errors. Readers are advised to keep in mind that statements, data, illustrations, procedural details or other items may inadvertently be inaccurate.

 

Library of Congress Card No.: applied for

 

British Library Cataloguing-in-Publication Data

A catalogue record for this book is available from the British Library.

 

Bibliographic information published by the Deutsche Nationalbibliothek

The Deutsche Nationalbibliothek lists this publication in the Deutsche Nationalbibliografie; detailed bibliographic data are available on the Internet at <http://dnb.d-nb.de>.

 

© 2015 Wiley-VCH Verlag GmbH & Co. KGaA,

Boschstr. 12, 69469 Weinheim, Germany

 

All rights reserved (including those of translation into other languages). No part of this book may be reproduced in any form – by photoprinting, microfilm, or any other means – nor transmitted or translated into a machine language without written permission from the publishers. Registered names, trademarks, etc. used in this book, even when not specifically marked as such, are not to be considered unprotected by law.

 

Print ISBN: 978-3-527-33639-5

ePDF ISBN: 978-3-527-68000-9

ePub ISBN: 978-3-527-67999-7

Mobi ISBN: 978-3-527-67998-0

oBook ISBN: 978-3-527-67997-3

List of Contributors

Jong-Hyun Ahn

Yonsei University

School of Electrical and Electronic Engineering

Yonsei-ro

Seodaemun-gu

Seoul, 120-749

Republic of Korea

Kang-Jun Baeg

Nano Carbon Materials Research Group

Korea Electrotechnology Research Institute (KERI)

Bulmosan-ro 10beon-gil

Seongsan-gu, Changwon

Gyeongsangnam-do, 642-120

Republic of Korea

Alejandro L. Briseno

University of Massachusetts

Department of Polymer Science and Engineering

Conte Research Center

Governors Drive

Amherst

MA 01003

USA

Mario Caironi

Istituto Italiano di Tecnologia

Center for Nano Science and Technology @PoliMi

Via Pascoli 70/3

Milano

Italy

Zhuoying Chen

ESPCI/CNRS/Université Pierre et Marie Curie

Laboratoire de Physique et d'Etude des Matériaux

Rue Vauquelin

Paris

France

Jeong Ho Cho

Sungkyunkwan University

Advanced Institute Nanotechnology (SAINT)

Suwon 440746

Republic of Korea

Nicholas S. Colella

University of Massachusetts

Department of Polymer Science and Engineering

Conte Research Center

Governors Drive

Amherst

MA 01003

USA

Pasquale D'Angelo

IMEM-CNR Institute of Materials for Electronics and

Magnetism – National Research Council

Parco Area delle Scienze 37/A

Parma

Italy

Antonio Facchetti

Polyera Corporation

Lamon Avenue

STE 140

Skokie

IL 60077-5318

USA

and

Northwestern University

Department of Chemistry and the Materials Research Center

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