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From materials to applications, this ready reference covers the entire value chain from fundamentals via processing right up to devices, presenting different approaches to large-area electronics, thus enabling readers to compare materials, properties and performance. Divided into two parts, the first focuses on the materials used for the electronic functionality, covering organic and inorganic semiconductors, including vacuum and solution-processed metal-oxide semiconductors, nanomembranes and nanocrystals, as well as conductors and insulators. The second part reviews the devices and applications of large-area electronics, including flexible and ultra-high-resolution displays, light-emitting transistors, organic and inorganic photovoltaics, large-area imagers and sensors, non-volatile memories and radio-frequency identification tags. With its academic and industrial viewpoints, this volume provides in-depth knowledge for experienced researchers while also serving as a first-stop resource for those entering the field.
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Cover
Related Titles
Title Page
Copyright
List of Contributors
Overview
Book Structure and Aim
Acknowledgments
References
Part I: Materials
Chapter 1: Polymeric and Small-Molecule Semiconductors for Organic Field-Effect Transistors
1.1 Introduction
1.2 Organic Semiconductor Structural Design
1.3 Thin-Film Transistor Applications
1.4 p-Channel Semiconductors
1.5 n-Channel Semiconductors
1.6 Ambipolar Semiconductors
1.7 Conclusions
References
Chapter 2: Metal-Oxide Thin-Film Transistors for Flexible Electronics
2.1 Introduction
2.2 Metal-Oxide TFTs
2.3 Solution-Processed MO Thin Films
2.4 Low-Temperature-Processed MO TFTs for Flexible Electronics
2.5 Summary
References
Chapter 3: Carbon Nanotube Thin-Film Transistors
3.1 Introduction
3.2 Individual SWCNTs and SWCNT Thin Films
3.3 Chemical Vapor Deposition Growth of SWCNT TFTs
3.4 Solution-Based Methods for SWCNT TFTs
3.5 Inkjet Printing of Flexible SWCNT TFTs
3.6 Fabrication Schemes for High-Performance Inkjet-Printed SWCNT TFTs
3.7 Inkjet Printing of SWCNT CMOS Inverters
3.8 Inkjet Printing of Aligned SWCNT Films
3.9 Conclusion
References
Chapter 4: Organic Single-Crystalline Semiconductors for Flexible Electronics Applications
4.1 Introduction
4.2 Electronic and Structural Properties of Single Crystals
4.3 Crystallization Techniques
4.4 Single-Crystal Flexible Electronic Devices
4.5 Strategies for Flexible Organic Single-Crystal Device Fabrication
4.6 Conclusions
Acknowledgments
References
Chapter 5: Solution-Processable Quantum Dots
5.1 Introduction
5.2 Optimization of the Colloidal Synthesis of Quantum Dots by Selection of Suitable Solvents, Ligands, and Precursors
5.3 Large-Scale Synthesis of Quantum Dots
5.4 Surface Chemistry of Quantum Dots
5.5 Post-Synthetic Chemical Modification of Nanocrystals
5.6 Conclusions and Outlook
References
Chapter 6: Inorganic Semiconductor Nanomaterials for Flexible Electronics
6.1 Introduction
6.2 Characteristics and Synthesis of Inorganic Semiconducting NMs
6.3 Applications in Flexible Electronics
6.4 Concluding Remarks
References
Chapter 7: Dielectric Materials for Large-Area and Flexible Electronics
7.1 Introduction
7.2 General Polymer Dielectrics
7.3 Cross-Linked Polymer Dielectrics
7.4 High-
k
Polymer Dielectrics
7.5 Electrolyte Gate Dielectrics
7.6 Self-Assembled Molecular Layer Dielectrics
7.7 Hybrid Dielectrics
7.8 Sol–Gel High-
k
Inorganic Dielectrics
7.9 Summary and Outlook
References
Chapter 8: Electrolyte-Gating Organic Thin Film Transistors
8.1 Introduction
8.2 Electrolyte-Gated OTFT Operation Mechanisms
8.3 Electrolyte Materials
8.4 OTFTs Gated with Electrolyte Dielectrics
8.5 Circuits Based on Electrolyte-Gated OTFTs
8.6 Conclusions
References
Chapter 9: Vapor Barrier Films for Flexible Electronics
9.1 Introduction
9.2 Thin-Film Permeation Barrier Layers
9.3 Permeation through Inorganic Thin Films
9.4 Time-Resolved Measurements on Barrier Layers
9.5 Mechanical Limitations of Inorganic Films
9.6 Mechanics of Films on Flexible Substrates
9.7 Summary
References
Chapter 10: Latest Advances in Substrates for Flexible Electronics
10.1 Introduction
10.2 Factors Influencing Film Choice
10.3 Film Property Set
10.4 Summary of Key Properties of Base Substrates
10.5 Planarizing Coatings
10.6 Examples of Film in Use
10.7 Concluding Remarks
Acknowledgments
References
Part II: Devices and Applications
Chapter 11: Inkjet Printing Process for Large Area Electronics
11.1 Introduction
11.2 Dynamics of Jet Formation
11.3 Ink Rheology: Non-Newtonian Liquids
11.4 Dynamics of Drop Impact and Spreading
11.5 Applications of Inkjet Printing for Large-Area Electronics
11.6 Summary
References
Chapter 12: Inkjet-Printed Electronic Circuits Based on Organic Semiconductors
12.1 Printed Organic Electronics
12.2 CMOS Technology
12.3 High-Speed Organic CMOS Circuits
12.4 Conclusions
References
Chapter 13: Large-Area, Printed Organic Circuits for Ambient Electronics
13.1 Introduction
13.2 Manufacturing Process and Electrical Characteristics
13.3 Demonstration
13.4 Future Prospects
Acknowledgments
References
Chapter 14: Polymer and Organic Nonvolatile Memory Devices
14.1 Introduction
14.2 Resistive Switching Memories
14.3 Charge Storage in Transistor Gate Dielectric
14.4 Polymer Ferroelectric Devices
14.5 Conclusions
References
Chapter 15: Flexible Displays
15.1 Introduction
15.2 Flexible Substrates
15.3 Display Mode
15.4 Thin-Film Transistor
15.5 AMOLED Panel with Printing Technology
15.6 Fabrication of the OLED and AMOLED Panel
15.7 Future Prospects
References
Chapter 16: Flexible Organic Solar Cells for Scalable, Low-Cost Photovoltaic Energy Conversion
16.1 Overview of Organic Photovoltaic (OPV) Cells
16.2 Efforts toward Realization of Flexible OSCs
16.3 Flexible OSCs for High-Throughput Production: A Printing-Based Approach to Low-Cost Solar Energy Conversion
16.4 Summary and Outlook
References
Chapter 17: Flexible Inorganic Photovoltaics
17.1 Introduction
17.2 Thin Crystalline Solar Cells Transferred onto Flexible Substrates
17.3 Thin-Film Solar Cells Grown Directly onto Flexible Substrates by Vapor Deposition
17.4 Solution-Processed Thin-Film Solar Cells Deposited Directly onto Flexible Substrates
17.5 Summary
References
Chapter 18: Scalable and Flexible Bioelectronics and Its Applicationsto Medicine
18.1 Biosensing and Bioelectronics: A Fast Growing Field and a Challenging Research Area
18.2 Inorganic and Silicon-Based Flexible Electronics for Biosensing Devices
18.3 EGOFETs for Flexible Biosensing
18.4 OECTs for Biosensing and Biomonitoring
18.5 Conclusions and Outlook
References
Index
EULA
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Cover
Table of Contents
Part I: Materials
Chapter 1: Polymeric and Small-Molecule Semiconductors for Organic Field-Effect Transistors
Figure 1
Figure 1.1
Figure 1.2
Figure 1.3
Figure 1.4
Figure 1.5
Figure 1.6
Figure 1.7
Figure 1.8
Figure 1.9
Figure 1.10
Figure 1.11
Figure 1.12
Figure 1.13
Figure 1.14
Figure 1.15
Figure 1.16
Figure 1.17
Figure 1.18
Figure 1.19
Figure 1.20
Figure 1.21
Figure 1.22
Figure 1.23
Figure 1.24
Figure 1.25
Figure 1.26
Figure 1.27
Figure 1.28
Figure 1.29
Figure 1.30
Figure 1.31
Figure 1.32
Figure 1.33
Figure 1.34
Figure 1.35
Figure 1.36
Figure 1.37
Figure 1.38
Figure 1.39
Figure 1.40
Figure 1.41
Figure 1.42
Figure 1.43
Figure 1.44
Figure 1.45
Figure 1.46
Figure 1.47
Figure 2.1
Figure 2.2
Figure 2.3
Figure 2.4
Figure 2.5
Figure 2.6
Figure 2.7
Figure 2.8
Figure 2.9
Figure 3.1
Figure 3.2
Figure 3.3
Figure 3.4
Figure 3.5
Figure 3.6
Figure 3.7
Figure 3.8
Figure 3.9
Figure 3.10
Figure 4.1
Figure 4.2
Figure 4.3
Figure 4.4
Figure 4.5
Figure 4.6
Figure 4.7
Figure 4.8
Figure 4.9
Figure 4.10
Figure 4.11
Figure 4.12
Figure 4.13
Figure 4.14
Figure 4.15
Figure 4.16
Figure 4.17
Figure 4.18
Figure 4.19
Figure 4.20
Figure 4.21
Figure 5.1
Figure 5.2
Figure 5.3
Figure 5.4
Figure 5.5
Figure 5.6
Figure 5.7
Figure 5.8
Figure 5.9
Figure 6.1
Figure 6.2
Figure 6.3
Figure 6.4
Figure 6.5
Figure 6.6
Figure 6.7
Figure 6.8
Figure 6.9
Figure 6.10
Figure 6.11
Figure 6.12
Figure 6.13
Figure 6.14
Figure 6.15
Figure 6.16
Figure 6.17
Figure 7.1
Figure 7.2
Figure 7.3
Figure 7.4
Figure 7.5
Figure 7.6
Figure 7.7
Figure 7.8
Figure 7.9
Figure 7.10
Figure 7.11
Figure 8.1
Figure 8.2
Figure 8.3
Figure 8.4
Figure 8.5
Figure 8.6
Figure 8.7
Figure 9.1
Figure 9.5
Figure 9.2
Figure 9.3
Figure 9.4
Figure 9.6
Figure 9.7
Figure 10.1
Figure 10.2
Figure 10.3
Figure 10.4
Figure 10.5
Figure 10.6
Figure 10.7
Figure 10.8
Figure 10.9
Figure 10.10
Figure 10.11
Figure 10.12
Figure 10.13
Figure 10.14
Figure 10.15
Figure 10.16
Figure 11.1
Figure 11.2
Figure 11.3
Figure 11.4
Figure 11.5
Figure 11.6
Figure 11.7
Figure 11.8
Figure 11.9
Figure 11.10
Figure 11.11
Figure 11.12
Figure 12.1
Figure 12.2
Figure 12.3
Figure 12.4
Figure 12.5
Figure 12.6
Figure 12.7
Figure 12.8
Figure 12.9
Figure 13.1
Figure 13.2
Figure 13.3
Figure 13.4
Figure 13.5
Figure 13.6
Figure 13.7
Figure 14.1
Figure 14.2
Figure 14.3
Figure 14.4
Figure 14.5
Figure 14.6
Figure 14.7
Figure 14.8
Figure 14.9
Figure 14.10
Figure 14.11
Figure 14.12
Figure 14.13
Figure 14.14
Figure 14.15
Figure 14.16
Figure 14.17
Figure 15.1
Figure 15.2
Figure 15.3
Figure 15.4
Figure 15.5
Figure 15.6
Figure 15.7
Figure 15.8
Figure 15.9
Figure 15.10
Figure 15.17
Figure 15.11
Figure 15.12
Figure 15.13
Figure 15.14
Figure 15.15
Figure 15.16
Figure 16.1
Figure 16.2
Figure 16.3
Figure 16.4
Figure 16.5
Figure 16.6
Figure 16.7
Figure 16.8
Figure 16.9
Figure 16.10
Figure 16.11
Figure 16.12
Figure 17.1
Figure 17.2
Figure 17.3
Figure 17.4
Figure 17.5
Figure 17.6
Figure 18.1
Figure 18.2
Figure 18.3
Figure 18.4
Figure 18.5
Figure 18.6
Figure 18.7
Figure 18.8
Figure 18.9
Figure 18.10
Figure 18.11
Figure 18.12
Figure 18.13
Figure 18.14
Figure 18.15
Figure 18.16
Figure 18.17
Figure 18.18
Figure 18.19
Figure 18.20
Figure 18.21
Figure 18.22
Figure 18.23
Table 4.1
Table 4.2
Table 5.1
Table 6.1
Table 6.2
Table 7.1
Table 9.1
Table 10.1
Table 10.2
Table 10.3
Table 11.1
Table 11.2
Table 12.1
Table 14.1
Table 14.2
Table 14.3
Table 15.1
Table 15.2
Table 15.3
Table 16.1
Table 18.1
Someya, T. (ed.)
Stretchable Electronics
2013
Print ISBN: 978-3-527-32978-6, also available in digital formats
Brütting, W., Adachi, C. (eds.)
Physics of Organic Semiconductors
2nd Edition
2012
Print ISBN: 978-3-527-41053-8, also available in digital formats
Klauk, H. (ed.)
Organic Electronics II
More Materials and Applications
2012
Print ISBN: 978-3-527-32647-1, also available in digital formats
Barquinha, P.P., Martins, R.R., Pereira, L.M., Fortunato, E.E.
Transparent Oxide Electronics - From Materials to Devices
2012
Print ISBN: 978-0-470-68373-6, also available in digital formats
Chujo, Y. (ed.)
Conjugated Polymer Synthesis
Methods and Reactions
2011
Print ISBN: 978-3-527-32267-1, also available in digital formats
Marks, T.T., Facchetti, A.A. (eds.)
Transparent Electronics - From Synthesis to Applications
2010
Print ISBN: 978-0-470-99077-3, also available in digital formats
Leclerc, M., Morin, J. (eds.)
Design and Synthesis of Conjugated Polymers
2010
Print ISBN: 978-3-527-32474-3, also available in digital formats
Edited by Mario Caironi and Yong-Young Noh
The Editors
Dr. Mario Caironi
Center for Nano Science and Technology @PoliMi
Istituto Italiano di Tecnologia
Via Pascoli, 70/3
20133 Milano
Italy
Prof. Yong-Young Noh
Dongguk University
Dept of Energy and Materials Engineering
26, Pil-dong, 3-ga, Jung-gu
100-715 Seoul
Republic of Korea
All books published by Wiley-VCH are carefully produced. Nevertheless, authors, editors, and publisher do not warrant the information contained in these books, including this book, to be free of errors. Readers are advised to keep in mind that statements, data, illustrations, procedural details or other items may inadvertently be inaccurate.
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The Deutsche Nationalbibliothek lists this publication in the Deutsche Nationalbibliografie; detailed bibliographic data are available on the Internet at <http://dnb.d-nb.de>.
© 2015 Wiley-VCH Verlag GmbH & Co. KGaA,
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Print ISBN: 978-3-527-33639-5
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List of Contributors
Jong-Hyun Ahn
Yonsei University
School of Electrical and Electronic Engineering
Yonsei-ro
Seodaemun-gu
Seoul, 120-749
Republic of Korea
Kang-Jun Baeg
Nano Carbon Materials Research Group
Korea Electrotechnology Research Institute (KERI)
Bulmosan-ro 10beon-gil
Seongsan-gu, Changwon
Gyeongsangnam-do, 642-120
Republic of Korea
Alejandro L. Briseno
University of Massachusetts
Department of Polymer Science and Engineering
Conte Research Center
Governors Drive
Amherst
MA 01003
USA
Mario Caironi
Istituto Italiano di Tecnologia
Center for Nano Science and Technology @PoliMi
Via Pascoli 70/3
Milano
Italy
Zhuoying Chen
ESPCI/CNRS/Université Pierre et Marie Curie
Laboratoire de Physique et d'Etude des Matériaux
Rue Vauquelin
Paris
France
Jeong Ho Cho
Sungkyunkwan University
Advanced Institute Nanotechnology (SAINT)
Suwon 440746
Republic of Korea
Nicholas S. Colella
University of Massachusetts
Department of Polymer Science and Engineering
Conte Research Center
Governors Drive
Amherst
MA 01003
USA
Pasquale D'Angelo
IMEM-CNR Institute of Materials for Electronics and
Magnetism – National Research Council
Parco Area delle Scienze 37/A
Parma
Italy
Antonio Facchetti
Polyera Corporation
Lamon Avenue
STE 140
Skokie
IL 60077-5318
USA
and
Northwestern University
Department of Chemistry and the Materials Research Center
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