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Addresses materials, technology, and products that could help solve the global environmental crisis once commercialized This multidisciplinary book encompasses state-of-the-art research on the topics of Carbon Capture and Storage (CCS), and complements existing CCS technique publications with the newest research and reviews. It discusses key challenges involved in the CCS materials design, processing, and modeling and provides in-depth coverage of solvent-based carbon capture, sorbent-based carbon capture, membrane-based carbon capture, novel carbon capture methods, computational modeling, carbon capture materials including metal organic frameworks (MOF), electrochemical capture and conversion, membranes and solvents, and geological sequestration. Materials and Processes for CO2 Capture, Conversion and Sequestration offers chapters on: Carbon Capture in Metal-Organic Frameworks; Metal Organic Frameworks Materials for Post-Combustion CO2 Capture; New Progress of Microporous Metal-Organic Frameworks in CO2 Capture and Separation; In Situ Diffraction Studies of Selected Metal-Organic Framework (MOF) Materials for Guest Capture Applications; Electrochemical CO2 Capture and Conversion; Electrochemical Valorization of Carbon Dioxide in Molten Salts; Microstructural and Structural Characterization of Materials for CO2 Storage using Multi-Scale X-Ray Scattering Methods; Contribution of Density Functional Theory to Microporous Materials for Carbon Capture; and Computational Modeling Study of MnO2 Octahedral Molecular Sieves for Carbon Dioxide Capture Applications. * Addresses one of the most pressing concerns of society--that of environmental damage caused by the greenhouse gases emitted as we use fossil fuels * Covers cutting-edge capture technology with a focus on materials and technology rather than regulation and cost * Highlights the common and novel CCS materials that are of greatest interest to industrial researchers * Provides insight into CCS materials design, processing characterization, and computer modeling Materials and Processes for CO2 Capture, Conversion and Sequestration is ideal for materials scientists and engineers, energy scientists and engineers, inorganic chemists, environmental scientists, pollution control scientists, and carbon chemists.

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MATERIALS ANDPROCESSES FOR CO2CAPTURE, CONVERSION,AND SEQUESTRATION

Edited by

Lan Li

Boise State University

Winnie Wong-Ng

National Institute of Standards and Technology

Kevin Huang

University of South Carolina

Lawrence P. Cook

The Catholic University of America

This edition first published 2018© 2018 The American Ceramic Society

All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, except as permitted by law. Advice on how to obtain permission to reuse material from this title is available at http://www.wiley.com/go/permissions.

The rights of Lan Li, Winnie Wong-Ng, Kevin Huang, and Lawrence P. Cook, to be identified as the authors of the editorial material in this work have been asserted in accordance with law.

Registered Office

John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, USA

Editorial Office111 River Street, Hoboken, NJ 07030, USA

For details of our global editorial offices, customer services, and more information about Wiley products visit us at www.wiley.com.

Wiley also publishes its books in a variety of electronic formats and by print-on-demand. Some content that appears in standard print versions of this book may not be available in other formats.

Limit of Liability/Disclaimer of Warranty

In view of ongoing research, equipment modifications, changes in governmental regulations, and the constant flow of information relating to the use of experimental reagents, equipment, and devices, the reader is urged to review and evaluate the information provided in the package insert or instructions for each chemical, piece of equipment, reagent, or device for, among other things, any changes in the instructions or indication of usage and for added warnings and precautions. While the publisher and authors have used their best efforts in preparing this work, they make no representations or warranties with respect to the accuracy or completeness of the contents of this work and specifically disclaim all warranties, including without limitation any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives, written sales materials or promotional statements for this work. The fact that an organization, website, or product is referred to in this work as a citation and/or potential source of further information does not mean that the publisher and authors endorse the information or services the organization, website, or product may provide or recommendations it may make. This work is sold with the understanding that the publisher is not engaged in rendering professional services. The advice and strategies contained herein may not be suitable for your situation. You should consult with a specialist where appropriate. Further, readers should be aware that websites listed in this work may have changed or disappeared between when this work was written and when it is read. Neither the publisher nor authors shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages.

Library of Congress Cataloging-in-Publication Data

Names: Li, Lan (Materials scientist), editor. | Wong-Ng, W. (Winnie), editor.    | Huang, Kevin, editor. | Cook, L. P., editor.Title: Materials and processes for CO2 capture, conversion, and sequestration    / edited by Lan (Samantha) Li, Winnie Wong-Ng, Kevin Huang, Lawrence P.    Cook.Description: Hoboken, NJ : John Wiley & Sons, 2018. | Includes    bibliographical references and index. | Identifiers: LCCN 2018003941 (print) | LCCN 2018006054 (ebook) | ISBN    9781119231066 (pdf) | ISBN 9781119231080 (epub) | ISBN 9781119231035    (cloth)Subjects: LCSH: Carbon sequestration. | Carbon dioxide mitigation.Classification: LCC TD885.5.C3 (ebook) | LCC TD885.5.C3 M38 2018 (print) |    DDC 628.5/32—dc23LC record available at https://lccn.loc.gov/2018003941

Cover image: Courtesy of Lan Li, Winnie Wong-Ng, Kevin Huang, and Lawrence P. CookCover design by Wiley

CONTENTS

Preface

List of Contributors

1 Carbon Capture in Metal–Organic Frameworks

1.1 Introduction

1.2 Understanding the Adsorption Properties of MOFs

1.3 MOFs for Post-combustion Capture

1.4 MOFs for Pre-combustion Capture

1.5 MOFs for Oxy-Fuel Combustion Capture

1.6 Future Perspectives and Outlook

Acknowledgments

References

2 Metal–Organic Frameworks Materials for Post-Combustion CO

2

Capture

2.1 Introduction: The Importance of Carbon Capture and Storage Technologies

2.2 Metal–Organic Frameworks as Sorbents

2.3 Metal–Organic Framework Membranes for CCS

2.4 Summary

References

3 New Progress of Microporous Metal–Organic Frameworks in CO

2

Capture and Separation

3.1 Introduction

3.2 Survey of Typical MOF Adsorbents

3.3 Zeolite Adsorbents in Comparison with MOFs

3.4 MOFs Membrane for CCS

3.5 Summary and Outlook

Acknowledgments

References

4

In Situ

Diffraction Studies of Selected Metal–Organic Framework Materials for Guest Capture/Exchange Applications

4.1 Introduction

4.2 Apparatus for

In Situ

Diffraction Studies

4.3

In Situ

Single-Crystal Diffraction Studies of MOFs

4.4 Powder Diffraction Studies of MOFs

4.5 Conclusion

References

Note

5 Electrochemical CO

2

Capture and Conversion

5.1 Introduction

5.2 Current Electrochemical Methods for Carbon Capture and Conversion

5.3 Development of High-Temperature Permeation Membranes for Electrochemical CO

2

Capture and Conversion

5.4 Summary and Outlook

Acknowledgments

References

6 Electrochemical Valorization of Carbon Dioxide in Molten Salts

6.1 Introduction

6.2 Thermodynamic Analysis of Molten Salt Electrolytes

6.3 Electrochemistry of Cathode and Anode

6.4 Applications of Electrolytic Products

6.5 Conclusion and Prospects

Acknowledgments

References

7 Microstructural and Structural Characterization of Materials for CO

2

Storage Using Multi-Scale X-Ray Scattering Methods

7.1 Introduction

7.2 Experimental Investigations of Subsurface CO

2

Trapping Mechanisms

7.3 Comparison of Material Measurements Techniques for Microstructure Characterization

7.4 Usaxs/Saxs Instrumentation

7.5 Analyses of Ultrasmall- and Small-Angle Scattering Data

7.6 Usaxs/Saxs/Waxs Characterization of CO

2

Interactions with Na-Montmorillonite

7.7 Summary

Acknowledgments

References

Notes

8 Contribution of Density Functional Theory to Microporous Materials for Carbon Capture

8.1 Microporous Solids

8.2 Overview of DFT

8.3 DFT: Applications

8.4 Conclusions and Recommendations

References

9 Computational Modeling Study of MnO

2

Octahedral Molecular Sieves for Carbon Dioxide–Capture Applications

9.1 Introduction

9.2 Atomic Structure Versus Magnetic Ordering

9.3 Pore Size and Dimensionality

9.4 CO

2

Sorption Behavior

9.5 Comparison of Cation Dopant Types

9.6 OMS-5

9.7 Summary

References

Index

End User License Agreement

List of Tables

1

Table 1.1

Table 1.2

2

Table 2.1

3

Table 3.1

Table 3.2

Table 3.3

Table 3.4

5

Table 5.1

Table 5.2

6

Table 6.1

Table 6.2

8

Table 8.1

Table 8.2

Guide

Cover

Table of Contents

Preface

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