Metal-Organic Framework Materials E-Book

• Herausgeber: John Wiley & Sons
• Kategorie: Wissenschaft und neue Technologien
• Serie: EIC Books
• Sprache: Englisch

Seitenzahl: 1602

Veröffentlichungsjahr: 2014

Beschreibung

Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis.  Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. 

Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. 

Leseprobe

Table of Contents

Cover

EIBC Books

Title Page

Copyright

Encyclopedia of Inorganic and Bioinorganic Chemistry

Contributors

Series Preface

Volume Preface

Periodic Table of the Elements

PART 1: Design and Synthesis

Porous Coordination Polymer Nanoparticles and Macrostructures

Nanoscale Metal-Organic Frameworks

Mesoporous Metal-Organic Frameworks

Porphyrinic Metal-Organic Frameworks

Fluorinated Metal-Organic Frameworks (FMOFs): Concept, Construction, and Properties

Synthesis and Structures of Aluminum-Based Metal-Organic Frameworks

Polyrotaxane Metal-Organic Frameworks

Photoreactive Metal-Organic Frameworks

Edible Metal-Organic Frameworks

Mechanochemical Approaches to Metal-Organic Frameworks

PART 2: Post-Modification

Postsynthetic Modification of Metal-Organic Frameworks

PART 3: Properties and Applications

Functional Magnetic Materials Based on Metal Formate Frameworks

Metal-Organic Frameworks from Single-Molecule Magnets

Open Metal Sites in Metal-Organic-Frameworks

Gas Storage in Metal-Organic Frameworks

Metal-Organic Frameworks for Removal of Harmful Gases

Adsorption of Hydrocarbons and Alcohols in Metal-Organic Framework Materials

Metal Uptake in Metal-Organic Frameworks

Photoreactive Properties Hosted in Metal-Organic Frameworks

Semiconducting Metal-Organic Frameworks

Patterning Techniques for Metal-Organic Frameworks

Metal-Organic Frameworks in Mixed-Matrix Membranes

Electrochemical Properties of Metal-Organic Frameworks

Applications of Metal-Organic Frameworks to Analytical Chemistry

Recent Solid-State NMR Studies of Quadrupolar Nuclei in Metal-Organic Frameworks

PART 4: Nets

Single-Crystal to Single-Crystal Transformations in Metal-Organic Frameworks

Interpenetration and Entanglement in Coordination Polymers

Index

Abbrevations and Acronyms used in this Volume

End User License Agreement

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Guide

Cover

Table of Contents

PART 1: Design and Synthesis

Porous Coordination Polymer Nanoparticles and Macrostructures

List of Illustrations

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List of Tables

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Table 1

EIBC Books

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Edited by Robert A. Scott and Charles M. Lukehart

ISBN 978-0-470-03217-6

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ISBN 978-0-470-69997-3

Radionuclides in the Environment

Edited by David A. Atwood

ISBN 978-0-470-71434-8

Energy Production and Storage: Inorganic Chemical Strategies for a Warming World

Edited by Robert H. Crabtree

ISBN 978-0-470-74986-9

The Rare Earth Elements: Fundamentals and Applications

Edited by David A. Atwood

ISBN 978-1-119-95097-4

Metals in Cells

Edited by Valeria Culotta and Robert A. Scott

ISBN 978-1-119-95323-4

Metal-Organic Framework Materials

Edited by Leonard R. MacGillivray and Charles M. Lukehart

ISBN 978-1-119-95289-3

Forthcoming

The Lightest Metals: Science and Technology from Lithium to Calcium

Edited by Timothy P. Hanusa

ISBN 978-1-11870328-1

Sustainable Inorganic Chemistry

Edited by David A. Atwood

ISBN 978-1-11870342-7

Encyclopedia of Inorganic and Bioinorganic Chemistry

The Encyclopedia of Inorganic and Bioinorganic Chemistry (EIBC) was created as an online reference in 2012 by merging the Encyclopedia of Inorganic Chemistry and the Handbook of Metalloproteins. The resulting combination proves to be the defining reference work in the field of inorganic and bioinorganic chemistry. The online edition is regularly updated and expanded. For information see:

www.wileyonlinelibrary.com/ref/eibc

METAL-ORGANIC FRAMEWORK MATERIALS

Editors

Leonard R. MacGillivray

University of Iowa, Iowa City, IA, USA

Charles M. Lukehart

Vanderbilt University, Nashville, TN, USA

This edition first published 2014

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Library of Congress Cataloging-in-Publication Data

Metal-organic framework materials / editors, Leonard R. MacGillivray, Charles M. Lukehart.

pages cm

Includes bibliographical references and index.

ISBN 978-1-119-95289-3 (cloth)

1. Nanocomposites (Materials) 2. Organometallic compounds. 3. Metallic composites. 4. Polymeric composites. I. MacGillivray, Leonard R., editor. II. Lukehart, Charles M., 1946- editor.

TA418.9.N35M5245 2014

620.1'18–dc23

2014027085

A catalogue record for this book is available from the British Library.

ISBN-13: 978-1-119-95289-3

Set in 10/12pt TimesNewRomanMTStd by Laserwords (Private) Limited, Chennai, India

Printed and bound in Singapore by Markono Print Media Pte Ltd.

Encyclopedia of Inorganic and Bioinorganic Chemistry

Editorial Board

Editor-in-Chief

Robert A. Scott

University of Georgia, Athens, GA, USA

Section Editors

David A. Atwood

University of Kentucky, Lexington, KY, USA

Timothy P. Hanusa

Vanderbilt University, Nashville, TN, USA

Charles M. Lukehart

Vanderbilt University, Nashville, TN, USA

Albrecht Messerschmidt

Max-Planck-Institute für Biochemie, Martinsried, Germany

Robert A. Scott

University of Georgia, Athens, GA, USA

Editors-in-Chief Emeritus & Senior Advisors

Robert H. Crabtree

Yale University, New Haven, CT, USA

R. Bruce King

University of Georgia, Athens, GA, USA

International Advisory Board

Michael Bruce

Adelaide, Australia

Tristram Chivers

Calgary, Canada

Valeria Culotta

MD, USA

Mirek Cygler

Saskatchewan, Canada

Marcetta Darensbourg

TX, USA

Michel Ephritikhine

Gif-sur-Yvette, France

Robert Huber

Martinsried, Germany

Susumu Kitagawa

Kyoto, Japan

Leonard R. MacGillivray

IA, USA

Thomas Poulos

CA, USA

David Schubert

CO, USA

Edward I. Solomon

CA, USA

Katherine Thompson

Vancouver, Canada

T. Don Tilley

CA, USA

Karl E. Wieghardt

Mülheim an der Ruhr, Germany

Vivian Yam

Hong Kong

Contributors

Debasis Banerjee

Rutgers University, Piscataway, NJ, USA

• Adsorption of Hydrocarbons and Alcohols in Metal-Organic Framework Materials