Table of Contents
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FOREWORD
PREFACE
ACKNOWLEDGEMENTS
Introduction
Abstract
1. Short History of Steel and Steel Casting
2. DEVELOPMENT OF STEEL TECHNOLOGIES
CONFLICT OF INTEREST
REFERENCES
Fundamentals of Melting Processes
Abstract
1. INTRODUCTION
2. Melting of Steel in an Electric Arc Furnace
2.1. Repair of the Furnace Lining
2.2. Loading the Charge
2.3. Smelting the Charge
2.4. Oxidation Period
Oxidation of Silicon
Oxidation of Manganese
Oxidation of Phosphorus - Dephosphorization
Reversion of Phosphorus into the Molten Steel
Oxidation of Carbon
Oxidation of Chromium
2.5. Refining Period
Desulphurisation
CONFLICT OF INTEREST
REFERENCES
Slags
Abstract
1. INTRODUCTION
Basicity of Slags B
2. Structure of Slags
3. Slag phase Systems
4. Chemical Compositions of Steel Slags
Slags in Basic Electric Arc Furnace
Slags for the Ladle Treatment (Synthetic Slags)
CONFLICT OF INTEREST
REFERENCES
Gases and Non-Metallic Inclusions in Steel Castings
Abstract
1. Introduction
2. The Solubility of Gases in Molten Steel
3. The effect of temperature on the gas content in the solid state
4. Solubility of Hydrogen and Nitrogen in Iron and Steel
Carbon oxide {CO}
5. Inclusions in steel castings
5.1. Conditions for the Formation of Sulphides
5.2. Modification of Sulphides
Sulphides of Ti and Zr
Influence of Calcium
The Effect of Rare Earth (REs) Treatment
5.3. The Influence of Non-Metallic Inclusions on the Properties of Cast Steels
CONFLICT OF INTEREST
REFERENCES
Deoxidation
Abstract
1. Introduction
2. Types of Deoxidation
Diffusion Deoxidation
Precipitation Deoxidation of Steel
3. Deoxidation with Aluminium and Other Elements
Deoxidation with Silicon
Deoxidation with Manganese
Deoxidation by Titanium
Deoxidation by Rare Earths REs
Deoxidation by Complex Deoxidisers
Deoxidation by Ca-Additions
4. Removal Of The Non-Metallic Inclusions From The Molten Steel
5. Deoxidation in Vacuum Conditions
6. Effect Of Deoxidisers On The Mechanical Properties Of Cast Steels
CONFLICT OF INTEREST
REFERENCES
Secondary Metallurgy for Small Ladles
Abstract
1. Introduction
2. Criteria For The Selection Of Secondary Metallurgy Technologies
I. Metallurgical
II. Technological
3. The Choice Of Secondary Metallurgy Process
4. Principles of the Processes and Layout
4.1. AP process
4.2. IP – Injection Processes
Wire Applications
5. Secondary Metallurgical Units Without Vacuum Treatment
6. Vacuum Processes
Evaporation of impurities
VD Process
Technology of the VD Process
The VOD Process
Results Obtained
7. Vacuum Induction Furnaces
Melting and Casting in Vacuum
CONFLICT OF INTEREST
REFERENCES
Cast Steels for Service Conditions
Abstract
1. Introduction
2. Castings of Wall Thickness up to 100 mm
Low-Alloy Manganese Cast Steels
Manganese-Nickel Cast Steel
Manganese-Molybdenum Cast Steels
Chromium and Chromium-Molybdenum Cast Steels
3. CAST STEEL FOR THICK-WALLED CASTINGS
4. HIGH STRENGTH CAST STEEL
4.1. High Strength Low-Alloy Cast Steels
CONFLICT OF INTEREST
REFERENCES
Steel Castings for Low Temperature Application
Abstract
1. INTRODUCTION
2. THE EFFECT OF THE CHEMICAL COMPOSITION ON THE IMPACT TOUGHNESS
3. The Effect Of Deoxidation Of Steel
4. Chemical Composition Of Cast Steels For Operation At Low Temperatures
5. The Influence Of Structure And Heat Treatment
6. The Influence Of Wall Thickness Of The Casting
CONFLICT OF INTEREST
REFERENCES
Corrosion – Resistant Cast Steels
Abstract
1. THERMODYNAMICS OF AQUEOUS CORROSION
2. Types Of Corrosion
3. The Effect of Alloying Elements
4. MICROSTRUCTURE OF CAST STEEL
5. Ferritic – Austenitic, F-A (Duplex) Cast Steels
6. Heat Treatment
CONFLICT OF INTEREST
REFERENCES
Heat – Resistant Cast Steels
Abstract
1. INTRODUCTION
2. OXIDATION - SELECTION OF ALLOYS AND MICROSTRUCTURE
2.1. Kinetics of Oxidation
2.2. The Mechanism of Scale Formation
2.3. The Rate of Oxidation
Linear (Fig. 4)
Parabolic
3. Heat-Resistant Cast Steels
4. Microstructure Of Heat-Resistant Cast Steels
5. The Effect Of Technological Factors On The Improvement Of Heat Resistance
6. Sulphur Corrosion
7. Castings Working Under Carburising Conditions
CONFLICT OF INTEREST
REFERENCES
Wear – Resistant Cast Steels
Abstract
1. INTRODUCTION
2. DEFINITION AND GENERAL CHARACTERISTICS OF WEAR
2.1. Structural Factors
2.2. Operating Conditions
2.3. Factors Characterising the Mechanism of Interaction
2.4. Types of Tribology Wear
3. WEAR-RESISTANT CAST STEELS
Carbon Cast Steel - Group 1
Low-Alloy Cast Steel - Group 2
Cast Steel Containing 12% Chromium
4. HIGH MANGANESE CAST STEELS
CONFLICT OF INTEREST
References
Pouring Systems and Rising
Abstract
1. INTRODUCTION
Construction of Gating Systems
2. CALCULATION OF GATING SYSTEM
Calculation of the Diameter of the Tap Hole in the Ladle
Calculation of Area of Ingates Fingate
3. Types of Risers and their Calculation
3.1. Feeding of Hot Spots
4. RISER CALCULATIONS
The Modulus Method
5. Computer Methods
CONFLICT OF INTEREST
References
Heat Treatment of Steel Castings
Abstract
1. INTRODUCTION
2. MICROSTRUCTURES OF CARBON CAST STEELS IN AS-CAST CONDITIONS
Normalisation
Annealing
Stress Relief Annealing
Spheroidisation Annealing
Solution Annealing (Treatment)
3. QUENCHING OF CAST STEELS
Stress-Relief Annealing
4. Hardening Processes
CONFLICT OF INTEREST
References
Metallurgy and Technology of
Steel Castings
Authored by
Jan Głownia
AGH – University of Science and Technology,Cracow, Poland
BENTHAM SCIENCE PUBLISHERS LTD.
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FOREWORD
Decades of work in the field of cast steel technology and material engineering allowed me to gather a number of materials, experiences and examples for engineers and students. I used them every day and I did not think about bringing them together and presenting them in the form of a book. Only an e-mail from Bentham Science Publishers encouraged me to prepare this work.
The intention of the presented material is to indicate guidelines for use in steel foundries and for teaching future engineers. In most of the examples, I based on experimental casting works, projects or co-operation with the industry. On this basis, the structure of the e-book provides the use of cast steel for working conditions of castings, such as subzero temperatures, corrosion, abrasion and heat resistance. Such an approach is a useful material for practitioners and it allows avoiding a lot of defects in castings and prevents their formation.
The problem of producing steel castings requires knowledge in various fields of science, starting from chemistry, metallurgy, and ending with the typical technological issues - pouring steel into foundry moulds, knowledge of cast steel shrinkage or heat treatment of castings. Therefore, the sequence of chapters covers:
preparation of liquid steel
The quality of steel castings is dependent on the quality of liquid steel smelted mostly in the arc furnace. Not only the chemical composition of steel is important for this issue when tapping metal into the ladle, but also the degree of its deoxidation, morphology of non-metallic inclusions and the content of gases;
the significance of casting wall thickness parts of machines (which are castings) require a uniform structure and properties on the cross-section of the whole casting wall. Under the existing stresses, the problem is gaining importance.working conditions of castings.
typical areas of the application of cast steel concern the mineral processing industry (abrasion), the marine industry (corrosion, low temperatures), the petrochemical industry (heat resistance, high temperature corrosion), technological processes improving the quality of castings (heat treatment).
I hope that the presented materials will not only be of help in solving the current problems for engineers, but will lead to an increased interest in the problems of cast steel engineering and will be an inspiration for the development of new, modern solutions.
PREFACE
This work is intended for engineers operating in industries, which apply steel castings in their products. This does not only concern pure castings, but also: machine building (trans-portation, earthmoving equipment, mining, military machinery), power industry (gas and oil exploration, power generation), chemical industry (refineries, chemical plants), food and medical processing. Foundries produce part of the machines intended for these applications considering their working conditions: temperature (from minus 120 oC to plus 700 – 800 oC), stresses, strength or yield strength and resistance to the environment (corrosion, abrasion). To meet the requirements of casting users, their production process should ensure the appropriate quality of liquid metal, correctness of the technological process (among others: smelting, pouring, solidification and heat treatment) and technical control of each sub-process.
Engineers who produce steel castings for the mentioned working conditions receive the basis in smelting of carbon and alloy steel, significance of the deoxidation process and modification of steel for castings (compared to wrought steel) and the properties of various types of cast steel operating e.g. in areas of sub-zero temperatures or corrosion. This knowledge is also useful for engineers in other specialties and working in the field of material engineering, metallurgy and manufacturing processes.
This presentation is based on publications, own co-operations with foundries and institutes, and industrial practices provided in the last decades. The intention of this book is to draw the reader's attention to the possible difficulties in obtaining an appropriate quality of castings as well as to indicate sources where more information on each subject of foundry engineering can be found.
This book is also addressed to students who wish to obtain an overall knowledge of the steel castings technology.
Jan Głownia
AGH – University of Science and Technology,
Cracow, Poland
ACKNOWLEDGEMENTS
Jan GłowniaIt is a great pleasure for me and I am particularly grateful to my wife Jane for her patience, care and indulgence during these long months of writing and staying outside our home. I am very grateful to my son Maciej, daughter Joanna (who spent a lot hours with the pictures) and grandchildren: Justine and Jędrzej.
Many thanks to my colleagues at my Alma Mater – AGH-University of Science and Techno-logy in Cracow:
Dr Barbara Kalandyk, Dr Renata Zapała, Dr Sebastian Sobula, Dr Grzegorz Tęcza, Antoni Dzieja for many years of co-operation, for their help and valuable suggestions;many friends, co-workers from Foundry Engineering Faculty and other Faculties of my University and to the following foundries and factories for the numerous, collective works:Metalodlew S.A. Cracow,Huta Małapanew in Ozimek,Pioma S.A. in Piotrków Trybunalski,Zabrzańska Fabryka Maszyn in Zabrze, AS Ferro-Term in Łódź,National Centre for Research and Development in Poland,Foundry Research Institute in Cracow,
I would like to specially thanks to the Translation Teams: JUNIQUE Agnieszka and Justin Nnorom and Dogadamycie for the translation of the entire text. I feel grateful MSc Grażyna Konieczko and Marcin Wasiak for preparation all figures to their proper conditions before printing.
Introduction
Jan Głownia
Abstract
The history of steel castings is associated with previously developed technologies for obtaining castings of bronze, copper and cast iron. These formed the basis for the improvement and development of casting technology of metal with a higher melting temperature and higher mechanical properties, and then - better utility properties (corrosion resistance, impact toughness at low temperatures and finally - smelting in a vacuum). The development of steel smelting technology and methods of obtaining steel castings have been presented against the background of extremely extensive literature on bronze casting in ancient times.
Keywords: Ancient castings, Converters, Electric arc furnace, History of steel castings, Lost wax technique, Vacuum technologies.
CONFLICT OF INTEREST
The author (editor) declares no conflict of interest, financial or otherwise.
REFERENCES
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Fundamentals of Melting Processes
Jan Głownia
Abstract
The primary technology of steel making in the foundry is a basic step to obtain a good quality of molten steel: with proper deoxidation, with low gases quantity and the control of non-metallic inclusions. These processes are discussed in detail through oxidation of elements and then during deoxidation in reduction period and in the ladle.
Keywords: Basic arc furnace, Ellingham-Richardson diagram, Furnaces in steel foundry, Melting processes, Reactions in oxidation and refining periods.