Nanoscale Ferroelectrics and Multiferroics E-Book

• Herausgeber: John Wiley & Sons
• Kategorie: Fachliteratur
• Sprache: Englisch

Seitenzahl: 2008

Veröffentlichungsjahr: 2016

Beschreibung

This two volume set reviews the key issues in processing and characterization of nanoscale ferroelectrics and multiferroics, and provides a comprehensive description of their properties, with an emphasis in differentiating size effects of extrinsic ones like boundary or interface effects. Recently described nanoscale novel phenomena are also addressed. Organized into three parts it addresses key issues in processing (nanostructuring), characterization (of the nanostructured materials) and nanoscale effects.

Taking full advantage of the synergies between nanoscale ferroelectrics and multiferroics, the text covers materials nanostructured at all levels, from ceramic technologies like ferroelectric nanopowders, bulk nanostructured ceramics and thick films, and magnetoelectric nanocomposites, to thin films, either polycrystalline layer heterostructures or epitaxial  systems, and to nanoscale free standing objects with specific geometries, such as nanowires and tubes at different levels of development.

This set is developed from the high level European scientific knowledge platform built within the COST (European Cooperation in Science and Technology) Action on Single and multiphase ferroics and multiferroics with restricted geometries (SIMUFER, ref. MP0904). Chapter contributors have been carefully selected, and have all made major contributions to knowledge of the respective topics, and overall, they are among most respected scientists in the field.

Leseprobe

Nanoscale Ferroelectrics and Multiferroics

Key Processing and Characterization Issues, and Nanoscale Effects

Edited by MIGUEL ALGUERÓJ. MARTY GREGGLILIANA MITOSERIU

This edition first published 2016© 2016 John Wiley & Sons Ltd

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Library of Congress Cataloging-in-Publication Data

Names: Algueró, Miguel, 1969- editor. | Gregg, J. Marty (John Marty), 1969- editor. | Mitoseriu, Liliana, editor.Title: Nanoscale ferroelectrics and multiferroics : key processing and characterization issues, and nanoscale effects / [compiled by] Miguel Algueró, J. Marty Gregg, Liliana Mitoseriu.Description: Hoboken : John Wiley & Sons, Inc., 2016. | Includes bibliographical references and index.Identifiers: LCCN 2015042479 (print) | LCCN 2015046191 (ebook) | ISBN 9781118935750 (cloth) | ISBN 9781118935675 (ePub) | ISBN 9781118935705 (Adobe PDF)Subjects: LCSH: Ferroelectric devices. | Nanoelectromechanical systems.Classification: LCC TK7872.F44 N36 2016 (print) | LCC TK7872.F44 (ebook) | DDC 621.381–dc23LC record available at http://lccn.loc.gov/2015042479

A catalogue record for this book is available from the British Library.

ISBN: 9781118935750

CONTENTS

VOLUME I

List of contributors

Preface

Introduction: Why Nanoscale Ferroelectrics and Multiferroics?

PART A

Nanostructuring: Bulk

1 Incorporation Mechanism and Functional Properties of Ce-Doped BaTiO

3

Ceramics Derived from Nanopowders Prepared by the Modified Pechini Method

1.1 Why Cerium-Doped BaTiO

3

?

1.2 Sample Preparation, Phase and Nano/Microstructural Characterization

1.3 Dielectric Properties

1.4 Raman Investigation

1.5 Conclusions

Acknowledgments

References

2 Synthesis and Ceramic Nanostructuring of Ferroic and Multiferroic Low-Tolerance-Factor Perovskite Oxides

2.1 Introduction

2.2 Synthesis of Perovskites Oxides

2.3 Processing of Ferroic and Multiferroic Materials:honey From the Ceramic Method to the Current Assisted Methods

2.4 Combination of Mechanosynthesis and Spark Plasma Synthesis:honey The Right Track to the Nanoscale in Ferroic Materials

2.5 Conclusions

Acknowledgments

References

3 Core–Shell Heterostructures:honey From Particle Synthesis to Bulk Dielectric, Ferroelectric, and Multiferroic Composite Materials

3.1 Introduction

3.2 Liquid-Phase Synthesis of Core–Shell Particles

3.3 BaTiO

3

@polymer Particles and Composites

3.4 Inorganic Core–Shell Particles with a Ferroelectric Core

3.5 Multiferroic Core–Shell Particles and Composites

3.6 Conclusions and Outlook

References

4 Modeling of Colloidal Suspensions for the Synthesis of the Ferroelectric Oxides with Complex Chemical Composition

4.1 Introduction

4.2 Solid-State Synthesis

4.3 Colloidal Interactions and Aggregation

4.4 Aggregation in the Three-Component System

4.5 Applying the Modeling Results to Enhance Properties of Ferroelectric Complex Oxides

4.6 Conclusions and Outlook

Acknowledgments

References

5 Self-Assemblage and Patterning of Thin-Film Ferroic Nanostructures

5.1 Introduction

5.2 Short Survey on Classical Top-Down Approaches

5.3 Non-invasive Procedures

5.4 Embedded Ferroelectric Nanograins

5.5 Conclusions

References

6 Thin-Film Porous Ferroic Nanostructures:honey Strategies and Characterization

6.1 (Nano)Microelectronics Considerations

6.2 Ferroics and Nanoferroic Structures

6.3 Meso- and Nanoporosity in Advanced Functional Materials

6.4 Nanoporosity in Ferroelectric Thin Films

6.5 Looking Ahead

Acknowledgments

References

7 Low-Temperature Photochemical Solution Deposition of Ferroelectric and Multiferroic Thin Films

7.1 Introduction

7.2 Low-Temperature Processing of Ferroelectrics and Multiferroics

7.3 Low Environmental Impact Precursor Chemistry

7.4 Aquous Solution–Gel Precursors

7.5 Photosensitive Sol–Gel Precursors

7.6 Photochemical Solution Deposition (PCSD)

7.7 Final Remarks

References

8 Synthesis and Properties of Ferroelectric Nanotubes and Nanowires:honey A Review

8.1 Introduction

8.2 Synthesis of Ferroelectric Nanowires and Nanotubes

8.3 Crystal Structure, Phase Transitions, and Ferroelectric Properties

8.4 Applications

8.5 Summary and Conclusions

References

9 Fabrication of One-Dimensional Ferroelectric Nano- and Microstructures by Different Spinning Techniques and Their Characterization

9.1 Introduction

9.2 Fiber Synthesis

9.3 Investigation of Nanostructure, Microstructure, and Phase Composition

9.4 Investigation of Mechanical Properties

9.5 Ferroelectric Characterization

9.6 Applications

9.7 Summary and Outlook

References

PART B: Characterization (of the Nanostructured Materials): Crystal Structure

10 Structural Characterization of Ferroelectric and Multiferroic Nanostructures by Advanced TEM Techniques

10.1 Introduction:honey Advanced TEM Techniques for the Analysis of Ferroelectric and Multiferroic Materials

10.2 Transmission Electron Microscopy

10.3 HAADF–STEM Structure Determination

10.4 Electron Energy Loss Spectroscopy

10.5 Future and Challenges

References

11 Raman Spectroscopy of Nanostructured Ferroelectric Materials

11.1 Introduction

11.2 Raman Spectroscopy Fundamentals

11.3 Raman Analysis of Relaxors

11.4 Raman Analysis of Nanostructured Ferroelectrics

11.5 Tip-Enhanced Raman Spectroscopy (TERS) of Nanoscale Ferroelectrics

11.6 Summary

Acknowledgments

References

12 Neutron and Synchrotron X-Ray Scattering Studies of Bulk and Nanostructured Multiferroic and Ferroelectric Materials

12.1 Introduction

12.2 Synchrotron X-Ray and Neutron Facilities for Structural Characterization of Ferroelectrics and Multiferroics

12.3 Crystal Structure of NdMn

2

O

5

in Powder and Single Crystalline Forms

12.4 Neutron Total Scattering Investigations of the BaTiO

3

@SiO

2

Nanocomposites

12.5 Concluding Comments

Acknowledgments

References

13 Advanced Characterization of Multiferroic Materials by Scanning Probe Methods and Scanning Electron Microscopy

13.1 SPM-Related Methods in Advanced Materials Research

13.2 Magnetic Force Microscopy (MFM) and Related Methods

13.3 Electrostatic Force Microscopy (EFM) and Piezo Force Microscopy (PFM)

13.4 Scanning Tunneling Microscopy (STM) and Related Methods

13.5 Imaging of Crystallographic Orientations (SEM/EBSD)

13.6 New Developments in the Field of EBSD

References

14 Electrostatic and Kelvin Probe Force Microscopy for Domain Imaging of Ferroic Systems

14.1 Introduction

14.2 Electrostatic Force Microscopy and Kelvin Probe Force Microscopy

14.3 EFM of Ferroelectric Materials

14.4 KPFM of Ferroelectric Materials

14.5 Recent Advances

14.6 Summary and Outlook

Acknowledgments

References

VOLUME II

PART C: Nanoscale Effects: Bulk Properties

15 Nanostructured Barium Titanate Ceramics:honey Intrinsic versus Extrinsic Size Effects

15.1 Introduction

15.2 Applications of BaTiO

3

Ceramics; Actual Demands for Passive Components

15.3 Size-Dependent Phenomena in Ferroelectrics

15.4 Size-Dependent Properties in BaTiO

3

Ceramics:honey Intrinsic versus Extrinsic Size Effects

15.5 Conclusions

Acknowledgments

References

16 The Effects of Ceramic Nanostructuring in High-Sensitivity Piezoelectrics

16.1 Technological Drive for Ceramic Nanostructuring of High-Sensitivity Piezoelectrics

16.2 State of the Art Ferroelectric Materials for Piezoelectric Technologies

16.3 Nanostructuring Effects in Perovskite Systems with PZT-like MPBs

16.4 Nanostructuring Effects in Perovskite Systems with Intrinsic Chemical Inhomogeneity

16.5 Summary and Future Perspectives

16.6 Acknowledgments

References

17 Correlation between Microstructure and Electrical Properties of Ferroelectric Relaxors

17.1 Introduction

17.2 Perovskite Relaxors

17.3 Aurivillius Lead-Free Ferroelectric Relaxors

17.4 Conclusions

References

18 Local Field Engineering Approach for Tuning Dielectric and Ferroelectric Properties in Nanostructured Ferroelectrics and Composites

18.1 Introduction

18.2 Finite Element Method

18.3 The Role of Local Electric Field Inhomogeneity on Tunability Properties

18.4 Switching Properties in Inhomogeneous Ferroelectrics

18.5 Conclusions

18.6 Acknowledgments

References

19 Ferroelectric Phase Transitions in Epitaxial Perovskite Films

19.1 Introduction

19.2 Experimental Study of Phase Transition

19.3 Dielectric Permittivity in Thin Films

19.4 Phase Transitions in Epitaxial Films

19.5 Concluding Remarks

19.6 Acknowledgments

References

20 Interfaces in Epitaxial Ferroelectric Layers/Multilayers and Their Effect on the Macroscopic Electrical Properties

20.1 Introduction

20.2 Electrode Interfaces in Ferroelectric Capacitors

20.3 Interfaces in Complex Structures

20.4 Conclusions

Acknowledgments

References

21 Electric Field Control of Magnetism Based on Elastically Coupled Ferromagnetic and Ferroelectric Domains

21.1 Introduction

21.2 Domain Pattern Transfer

21.3 Elastic Coupling Between Magnetic and Ferroelectric Domain Walls

21.4 Domain Size Scaling of Pattern Transfer

21.5 Electric Field Control of Ferromagnetic Domains

21.6 Electric Field Driven Magnetic Domain Wall Motion

21.7 Summary and Outlook

Acknowledgments

References

22 Ferroelectric Vortices and Related Configurations

22.1 Insights from Simulations and Theory

22.2 Insights from Experiments

Acknowledgments

References

23 Reentrant Phenomena in Relaxors

23.1 Introduction

23.2 Reentrant Phases in Condensed Matter

23.3 Relaxor Ferroelectrics

23.4 Reentrant Relaxor Behavior in Ferroelectrics

23.5 Transverse Glassy Freezing and Canonical Relaxors

23.6 Reentrant Dipolar Glass State in Quantum Paraelectrics Doped with Dipolar Impurities

23.7 Summary and Concluding Remarks

Acknowledgments

References

24 Functional Twin Boundaries:honey Multiferroicity in Confined Spaces

24.1 Introduction

24.2 Ferroelectric Twin Boundaries

24.3 Conducting Twin Boundaries

24.4 Thermal Conductivity

24.5 Landau Theory of Coupled Order Parameters in Domain Walls

24.6 Chiral Twin Walls

24.7 High Wall Densities

24.8 Summary

Acknowledgment

References

25 Novel Approaches for Genuine Single-Phase Room Temperature Magnetoelectric Multiferroics

25.1 Introduction to Single-Phase Multiferroic Materials

25.2 Aurivillius Phase Materials – Candidate Single-Phase Multiferroics?

25.3 Magnetoelectric Coupling in Multiferroic Bi

6

Ti

x

Fe

y

Mn

z

O

18

Systems at Room Temperature

25.4 Confidence Level Assessment of Genuine Single-Phase Multiferroicity

25.5 Potential Devices/Applications Based on Single-Phase Magnetoelectric Multiferroics

25.6 Summary and Conclusions

References

26 Semiconducting and Photovoltaic Ferroelectrics

26.1 Introduction

26.2 Basic Principles of Photovoltaic Effect in Ferroelectrics

26.3 Experimental Evidence of the Bulk Photovoltaic Effect in Ferroelectrics

26.4 The Role of the Schottky Barrier and Depletion Layer

26.5 Photovoltaic Effect Mediated by Ferroelectric Domain Walls

26.6 Ferroelectric Solid Solutions:honey Chemical Tuning of Band-Gap

26.7 Conclusions

Acknowledgment

References

Index

EULA

List of Tables

Chapter 1

Table 1.1

Table 1.2

Table 1.3

Chapter 2

Table 2.1

Table 2.2

Table 2.3

Table 2.4

Chapter 3

Table 3.1

Table 3.2

Chapter 6

Table 6.1

Chapter 7

Table 7.1

Chapter 9

Table 9.1

Table 9.2

Table 9.3

Table 9.4

Table 9.5

Table 9.6

Table 9.7

Table 9.8

Table 9.9

Table 9.10

Chapter 11

Table 11.1

Table 11.2

Chapter 12

Table 12.1

Table 12.2

Table 12.3

Table 12.4

Table 12.5

Chapter 17

Table 17.1

Table 17.2

Table 17.3

Chapter 25

Table 25.1