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Beschreibung

Organic Reaction Mechanisms 2009, the 45th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2009. The following classes of organic reaction mechanisms are comprehensively reviewed: * Reaction of Aldehydes and Ketones and their Derivatives * Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives * Oxidation and Reduction * Carbenes and Nitrenes * Nucleophilic Aromatic Substitution * Electrophilic Aromatic Substitution * Carbocations * Nucleophilic Aliphatic Substitution * Carbanions and Electrophilic Aliphatic Substitution * Elimination Reactions * Polar Addition Reactions * Cycloaddition Reactions * Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation. This volume includes a 5-year cumulative index.

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Veröffentlichungsjahr: 2011

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Table of Contents

Title Page

Copyright

Contributors

Preface

Chapter 1: Reactions of Aldehydes and Ketones and their Derivatives

References

Chapter 2: Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives

Inter- and Intra-Molecular Catalysis and Reactions

Biologically Significant Reactions

References

Chapter 3: Oxidation and Reduction

References

Chapter 4: Carbenes and Nitrenes

References

Chapter 5: Nucleophilic Aromatic Substitution

References

Chapter 6: Electrophilic Aromatic Substitution

References

Chapter 7: Carbocations

References

Chapter 8: Nucleophilic Aliphatic Substitution

References

Chapter 9: Carbanions and Electrophilic Aliphatic Substitution

References

Chapter 10: Elimination Reactions

References

Chapter 11: Addition Reactions: Polar Addition

References

Chapter 12: Addition Reactions: Cycloaddition

References

Chapter 13: Molecular Rearrangements: Part 1. Pericyclic Molecular Rearrangements

References

Chapter 14: Molecular Rearrangements: Part 2

References

Author Index

Cumulative Subject Index, 2005-2009

This edition first published 2012

© 2012 John Wiley & Sons, Ltd

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The Publisher and the Author make no representations or warranties with respect to the accuracy or completeness of the contents of this work and specifically disclaim all warranties, including without limitation any implied warranties of fitness for a particular purpose. The advice and strategies contained herein may not be suitable for every situation. In view of ongoing research, equipment modifications, changes in governmental regulations, and the constant flow of information relating to the use of experimental reagents, equipment, and devices, the reader is urged to review and evaluate the information provided in the package insert or instructions for each chemical, piece of equipment, reagent, or device for, among other things, any changes in the instructions or indication of usage and for added warnings and precautions. The fact that an organization or Website is referred to in this work as a citation and/or a potential source of further information does not mean that the author or the publisher endorses the information the organization or Website may provide or recommendations it may make. Further, readers should be aware that Internet Websites listed in this work may have changed or disappeared between when this work was written and when it is read. No warranty may be created or extended by any promotional statements for this work. Neither the Publisher nor the Author shall be liable for any damages arising herefrom.

Library of Congress Catalog Card Number 66-23143

British Library Cataloguing in Publication Data

A catalogue record for this book is available from the British Library

Print ISBN: 978-0-470-68594-5

ePDF ISBN: 978-1-119-97248-8

oBook ISBN: 978-1-119-97247-1

ePub ISBN: 978-1-119-96104-8

Mobi ISBN: 978-1-119-96105-5

Contributors

S. K. ARMSTRONGFormerly at the Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, UKC. T. BEDFORDDepartment of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UKM. L. BIRSAFaculty of Chemistry, “Al. I. Cuza” University of Iasi, Bd. Carol I, 11, Iasi 700506, RomaniaR. G. COOMBESDepartment of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UKJ. M. COXONDepartment of Chemistry, University of Canterbury, Christchurch, New ZealandM. R. CRAMPTONDepartment of Chemistry, University of Durham, South Road, Durham, DH1 3LE, UKN. DENNIS3 Camphorlaurel Court, Stretton, Brisbane, Queensland 4116, AustraliaE. GRASLaboratoire de Chimie de Coordination, CNRS, 205 Route de Narbonne, 31077 Toulouse Cedex 4, FranceA. C. KNIPEFaculty of Life and Health Sciences, University of Ulster, Coleraine, Northern IrelandP. KOOVSKÝDepartment of Chemistry, The Joseph Black Building, University of Glasgow, Glasgow G12 8QQ, UKR. A. McCLELLANDDepartment of Chemistry, University of Toronto, 80 St George Street, Toronto, Ontario M5S 1A1, CanadaR. N. MEHROTRAIndra-Kripa, A-85 Saraswati Nagar, Jodhpur 342005, IndiaB. A. MURRAYDepartment of Science, Institute of Technology Tallaght (ITT Dublin), Dublin 24, IrelandK. C. WESTAWAYDepartment of Chemistry and Biochemistry, Laurentian University, Sudbury, Ontario P3E 2C6, Canada

Preface

The present volume, the forty-fifth in the series, surveys research on organic reaction mechanisms described in the available literature dated 2009. In order to limit the size of the volume, it is necessary to exclude or restrict overlap with other publications which review specialist areas (e.g. photochemical reactions, biosynthesis, enzymology, electrochemistry, organometallic chemistry, surface chemistry and heterogeneous catalysis). In order to minimize duplication, while ensuring a comprehensive coverage, the editor conducts a survey of all relevant literature and allocates publications to appropriate chapters. While a particular reference may be allocated to more than one chapter, it is assumed that readers will be aware of the alternative chapters to which a borderline topic of interest may have been preferentially assigned.

In view of the considerable interest in application of stereoselective reactions to organic synthesis, we now provide indication, in the margin, of reactions which occur with significant diastereomeric or enantiomeric excess (de or ee).

Steps taken to reduce progressively the delay between title year and publication date have borne fruit, as evidenced by the publication of recent annual ORM volumes at nine-month intervals. Consequently we hope to regain our optimum production schedule soon.

I wish to thank the staff of John Wiley & Sons and the team of experienced contributors for their efforts to ensure that the review standards of this series are sustained, particularly during a period of substantial reorganization of production procedures.

A. C. K.