Organic Reaction Mechanisms 2012 E-Book
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- Herausgeber: John Wiley & Sons
- Kategorie: Wissenschaft und neue Technologien
- Serie: Organic Reaction Mechanisms
- Sprache: Englisch
Organic Reaction Mechanisms 2012, the 48th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2012. The following classes of organic reaction mechanisms are comprehensively reviewed:
- Reaction of Aldehydes and Ketones and their Derivatives
- Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives
- Oxidation and Reduction
- Carbenes and Nitrenes
- Nucleophilic Aromatic Substitution
- Electrophilic Aromatic Substitution
- Carbocations
- Nucleophilic Aliphatic Substitution
- Carbanions and Electrophilic Aliphatic Substitution
- Elimination Reactions
- Polar Addition Reactions
- Cycloaddition Reactions
- Molecular Rearrangements
An experienced team of authors compiled these reviews, ensuring the quality of selection and presentation.
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Veröffentlichungsjahr: 2015
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Table of Contents
Cover
Title Page
Copyright
Contributors
Preface
Chapter 1: Reactions of Aldehydes and Ketones and their Derivatives
Chapter 2: Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives
Intermolecular Catalysis and Reactions
Intramolecular Catalysis and Neighbouring Group Participation
Association-Prefaced Catalysis
Biologically Significant Reactions
Chapter 3: Oxidation and Reduction
Chapter 4: Carbenes and Nitrenes
Chapter 5: Aromatic Substitution
Chapter 6: Carbocations
Chapter 7: Nucleophilic Aliphatic Substitution
Chapter 8: Carbanions and Electrophilic Aliphatic Substitution
Chapter 9: Elimination Reactions
Chapter 10: Addition Reactions: Polar Addition
Chapter 11: Addition Reactions: Cycloaddition
Chapter 12: Molecular Rearrangements
Author Index
Subject Index
End User License Agreement
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Guide
Cover
Table of Contents
Preface
Begin Reading
List of Illustrations
Scheme 1
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ORGANIC REACTION MECHANISMS · 2012
An annual survey covering the literature dated January to December 2012
Edited by
A. C. Knipe
University of Ulster Northern Ireland
This edition first published 2015
© 2015 John Wiley & Sons, Ltd
Registered office
John Wiley & Sons Ltd, The Atrium, Southern Gate, Chichester, West Sussex, PO19 8SQ, United Kingdom
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The right of the author to be identified as the author of this work has been asserted in accordance with the Copyright, Designs and Patents Act 1988.
All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, except as permitted by the UK Copyright, Designs and Patents Act 1988, without the prior permission of the publisher.
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Designations used by companies to distinguish their products are often claimed as trademarks. All brand names and product names used in this book are trade names, service marks, trademarks or registered trademarks of their respective owners. The publisher is not associated with any product or vendor mentioned in this book.
Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. It is sold on the understanding that the publisher is not engaged in rendering professional services and neither the publisher nor the author shall be liable for damages arising herefrom. If professional advice or other expert assistance is required, the services of a competent professional should be sought.
The advice and strategies contained herein may not be suitable for every situation. In view of ongoing research, equipment modifications, changes in governmental regulations, and the constant flow of information relating to the use of experimental reagents, equipment, and devices, the reader is urged to review and evaluate the information provided in the package insert or instructions for each chemical, piece of equipment, reagent, or device for, among other things, any changes in the instructions or indication of usage and for added warnings and precautions. The fact that an organization or Website is referred to in this work as a citation and/or a potential source of further information does not mean that the author or the publisher endorses the information the organization or Website may provide or recommendations it may make. Further, readers should be aware that Internet Websites listed in this work may have changed or disappeared between when this work was written and when it is read. No warranty may be created or extended by any promotional statements for this work. Neither the publisher nor the author shall be liable for any damages arising herefrom.
Library of Congress Catalog Card Number 66-23143
British Library Cataloguing in Publication Data
A catalogue record for this book is available from the British Library
Print ISBN: 978-1-118-36259-4
Contributors
K. K. BANERJI
Faculty of Science, National Law University, Mandore, Jodhpur 342304, India
C. T. BEDFORD
Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UK
M. L. BIRSA
Faculty of Chemistry, “Al. I. Cuza” University of Iasi, Bd. Carol I, 11, Iasi 700506, Romania
S. CHASSAING
Centre National de la Recherche Scientifique, Université de Toulouse, Toulouse, FranceCentre Pierre Potier, ITAV, Université de Toulouse, F-31106 Toulouse, FranceINSA, F-31400 Toulouse, France
J. M. COXON
Department of Chemistry, University of Canterbury, Christchurch, New Zealand
M. R. CRAMPTON
Department of Chemistry, University of Durham, South Road, Durham, DH1 3LE, UK
N. DENNIS
3 Camphor Laurel Court, Stretton, Brisbane, Queensland 4116, Australia
E. GRAS
Laboratoire de Chimie de Coordination, Centre National de la Recherche Scientifique, Toulouse, France
A. C. KNIPE
Faculty of Life and Health Sciences, University of Ulster, Coleraine, Northern Ireland
P. KOČOVSKÝ
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm SE 10691, SwedenDepartment of Organic Chemistry, Charles University, 12843 Prague 2, Czech Republic
R. A. McCLELLAND
Department of Chemistry, University of Toronto, Toronto, 80 St George Street, Toronto, Ontario M5S 1A1, Canada
K. C. WESTAWAY
Department of Chemistry and Biochemistry, Laurentian University, Sudbury, Ontario P3E 2C6, Canada
Preface
The present volume, the 48th in the series, surveys research on organic reaction mechanisms described in the available literature dated 2012. In order to limit the size of the volume, it is necessary to exclude or restrict overlap with other publications which review specialist areas (e.g., photochemical reactions, biosynthesis, enzymology, electrochemistry, organometallic chemistry, surface chemistry, and heterogeneous catalysis). In order to minimize duplication, while ensuring a comprehensive coverage, the editor conducts a survey of all relevant literature and allocates publications to appropriate chapters. While a particular reference may be allocated to more than one chapter, it is assumed that readers will be aware of the alternative chapters to which a borderline topic of interest may have been preferentially assigned.
In view of the considerable interest in application of stereoselective reactions to organic synthesis, we now provide indication, in the margin, of reactions which occur with significant diastereomeric or enantiomeric excess (de or ee).
We are pleased to have retained for ORM 2012 our current team of experienced authors who have contributed to ORM volumes for periods of 7 to 34 years.
However, it is unfortunate that intervention of the editor to avoid an anticipated delay between title year and publication date for this volume was thwarted by unusually late arrival of a particularly long chapter. Nonetheless, we hope soon to regain our optimum production schedule.
I wish to thank the staff of John Wiley & Sons and our expert contributors for their efforts to ensure that the review standards of this series are sustained, particularly during a period of substantial reorganisation of production procedures.
A. C. K.
Chapter 1Reactions of Aldehydes and Ketones and their Derivatives
A.C. Knipe
Faculty of Life and Health Sciences, University of Ulster, Coleraine, Northern Ireland
Formation and Reactions of Acetals and Related Species
Reactions of Glucosides and Nucleosides
Reactions of Ketenes and Ketenimines
Formation and Reactions of Nitrogen Derivatives
Imines: Synthesis, Tautomerism, and Catalysis
The Mannich and Nitro-Mannich reactions
Addition of organometallics
Other alkenylations, allylations, and arylations of imines
Oxidation and reduction of imines
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