Polymer and Biopolymer Brushes E-Book

• Herausgeber: John Wiley & Sons
• Kategorie: Fachliteratur
• Sprache: Englisch

Seitenzahl: 1378

Veröffentlichungsjahr: 2017

Beschreibung

Serves as a guide for seasoned researchers and students alike, who wish to learn about the cross-fertilization between biology and materials that is driving this emerging area of science This book covers the most relevant topics in basic research and those having potential technological applications for the field of biopolymer brushes. This area has experienced remarkable increase in development of practical applications in nanotechnology and biotechnology over the past decade. In view of the rapidly growing activity and interest in the field, this book covers the introductory features of polymer brushes and presents a unifying and stimulating overview of the theoretical aspects and emerging applications. It immerses readers in the historical perspective and the frontiers of research where our knowledge is increasing steadily--providing them with a feeling of the enormous potential, the multiple applications, and the many up-and-coming trends behind the development of macromolecular interfaces based on the use of polymer brushes. Polymer and Biopolymer Brushes: Fundamentals and Applications in Materials offers chapters on: Functionalization of Surfaces Using Polymer Brushes; Polymer Brushes by ATRP and Surface-Mediated RAFT Polymerization for Biological Functions; Electro-Induced Copper Catalyzed Surface Modification with Monolayer and Polymer Brush; Polymer Brushes on Flat and Curved Substrates; Biomimetic Anchors for Antifouling Polymer Brush Coating; Glycopolymer Brushes Presenting Sugars in Their Natural Form; Smart Surfaces Modified with Phenylboronic Acid-Containing Polymer Brushes; DNA Brushes; Polymer Brushes as Interfacial Materials for Soft Metal Conductors and Electronics; and more. * Presents a comprehensive theory/simulation section that will be valuable for all readers * Includes chapters not only on the biological applications of polymer brushes but also on biological systems that resemble polymer brushes on flat surfaces * Addresses applications in coatings, friction, sensors, microelectromechanical systems, and biomaterials * Devotes particular attention to the functional aspects of hybrid nanomaterials employing polymer brushes as functional units Polymer and Biopolymer Brushes: Fundamentals and Applications in Materials is aimed at both graduate students and researchers new to this subject as well as scientists already engaged in the study and development of polymer brushes.

Leseprobe

Polymer and Biopolymer Brushes

for Materials Science and Biotechnology

Volume 1

Edited by

Omar Azzaroni

Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), CONICET, Universidad Nacional de La Plata, La Plata, Argentina

Igal Szleifer

Department of Biomedical Engineering, Department of Chemistry, and Chemistry of Life Processes Institute, Northwestern University, Evanston, IL, USA

This edition first published 2018 © 2018 by John Wiley & Sons, Inc.

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The right of Omar Azzaroni and Igal Szleifer to be identified as the editors of this work has been asserted in accordance with law.

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Limit of Liability/Disclaimer of WarrantyIn view of ongoing research, equipment modifications, changes in governmental regulations, and the constant flow of information relating to the use of experimental reagents, equipment, and devices, the reader is urged to review and evaluate the information provided in the package insert or instructions for each chemical, piece of equipment, reagent, or device for, among other things, any changes in the instructions or indication of usage and for added warnings and precautions. While the publisher and authors have used their best efforts in preparing this work, they make no representations or warranties with respect to the accuracy or completeness of the contents of this work and specifically disclaim all warranties, including without limitation any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives, written sales materials or promotional statements for this work. The fact that an organization, website, or product is referred to in this work as a citation and/or potential source of further information does not mean that the publisher and authors endorse the information or services the organization, website, or product may provide or recommendations it may make. This work is sold with the understanding that the publisher is not engaged in rendering professional services. The advice and strategies contained herein may not be suitable for your situation. You should consult with a specialist where appropriate. Further, readers should be aware that websites listed in this work may have changed or disappeared between when this work was written and when it is read. Neither the publisher nor authors shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages.

Library of Congress Cataloging-in-Publication Data applied for.

Hardback ISBN: 9781119455011

Cover design by Wiley

This book is dedicated to our families.

Igal Szleifer also wants to dedicate this book to his coauthor Omar Azzaroni, who took over the bulk of the work after Prof. Szleifer suffered a stroke in October 2015. If not for Omar's work and dedication, this book would not have materialized. Igal is truly grateful.

CONTENTS

Volume 1

Preface

List of Contributors

1 Functionalization of Surfaces Using Polymer Brushes: An Overview of Techniques, Strategies, and Approaches

1.1 Introduction: Fundamental Notions and Concepts

1.2 Preparation of Polymer Brushes on Solid Substrates

1.3 Preparation of Polymer Brushes by the “Grafting-To” Method

1.4 Polymer Brushes by the “Grafting-From” Method

1.5 Conclusions

Acknowledgments

References

2 Polymer Brushes by Atom Transfer Radical Polymerization

2.1 Structure of Brushes

2.2 Synthesis of Polymer Brushes

2.3 ATRP Fundamentals

2.4 Molecular Bottlebrushes by ATRP

2.5 ATRP and Flat Surfaces

2.6 ATRP and Nanoparticles

2.7 ATRP and Concave Surfaces

2.8 ATRP and Templates

2.9 Templates from Stars

2.10 Bio-Related Polymer Brushes

2.11 Stimuli-Responsive Polymer Brushes

2.12 Conclusion

Acknowledgments

References

3 Polymer Brushes by Surface-Mediated RAFT Polymerization for Biological Functions

3.1 Introduction

3.2 Polymer Brushes via the Surface-Initiated RAFT Polymerization Process

3.3 Polymer Brushes via the Interface-Mediated RAFT Polymerization Process

3.4 Summary

References

4 Electro-Induced Copper-Catalyzed Surface Modification with Monolayer and Polymer Brush

4.1 Introduction

4.2 “Electro-Click” Chemistry

4.3 Electrochemically Induced Surface-Initiated Atom Transfer Radical Polymerization

4.4 Possible Combination of eATRP and “e-Click” Chemistry on Surface

4.5 Surface Functionality

4.6 Summary

Acknowledgments

References

5 Polymer Brushes on Flat and Curved Substrates: What Can be Learned from Molecular Dynamics Simulations

5.1 Introduction

5.2 Molecular Dynamics Methods: A Short “Primer”

5.3 The Standard Bead Spring Model for Polymer Chains

5.4 Cylindrical and Spherical Polymer Brushes

5.5 Interaction of Brushes with Free Chains

5.6 Summary

Acknowledgments

References

6 Modeling of Chemical Equilibria in Polymer and Polyelectrolyte Brushes

6.1 Introduction

6.2 Theoretical Approach

6.3 Applications of the Molecular Theory

6.4 Summary and Conclusion

Acknowledgments

References

7 Brushes of Linear and Dendritically Branched Polyelectrolytes

7.1 Introduction

7.2 Analytical SCF Theory of Brushes Formed by Linear and Branched Polyions

7.3 Planar Brush of PE Dendrons with an Arbitrary Architecture

7.4 Planar Brush of Star-Like Polyelectrolytes

7.5 Threshold of Dendron Gaussian Elasticity

7.6 Scaling-Type Diagrams of States for Brushes of Linear and Branched Polyions

7.7 Numerical SF-SCF Model of Dendron Brush

7.8 Conclusions

References

8 Vapor Swelling of Hydrophilic Polymer Brushes

8.1 Introduction

8.2 Experimental

8.3 Results and Discussion

8.4 Conclusion

8.A.1 Appendix

Acknowledgments

References

9 Temperature Dependence of the Swelling and Surface Wettability of Dense Polymer Brushes

9.1 Introduction

9.2 The Swelling Coefficient of a Polymer Brush Mirrors Its Volume Hydrophilicity

9.3 The Cosine of the Contact Angle of Water on a

Water-Equilibrated

Polymer Brush Defines Its Surface Hydrophilicity

9.4 Case Study: Temperature-Dependent Surface hydrophilicity of Dense PNIPAM Brushes

9.5 Case Study: Temperature-Dependent Swelling and Volume Hydrophilicity of Dense PNIPAM Brushes

9.6 Thermoresponsive Poly(oligo(ethylene oxide)methacrylate) Copolymer Brushes: Versatile Functional Alternatives to PNIPAM

9.7 Surface and Volume Hydrophilicity of Nonthermoresponsive Poly(oligo(ethylene oxide)methacrylate) Copolymer Brushes

9.8 Conclusions

Acknowledgments

References

10 Functional Biointerfaces Tailored by “Grafting-To” Brushes

10.1 Introduction

10.2 Part I: Polymer Brush Architectures

10.3 Part II: Actuating Biomolecule Interactions with Surfaces

10.4 Conclusion and Outlook

Acknowledgments

References

11 Glycopolymer Brushes Presenting Sugars in Their Natural Form: Synthesis and Applications

11.1 Introduction and Background

11.2 Results and Discussion

11.3 Conclusions

Acknowledgments

References

12 Thermoresponsive Polymer Brushes for Thermally Modulated Cell Adhesion and Detachment

12.1 Introduction

12.2 Thermoresponsive Polymer Hydrogel-Modified Surfaces for Cell Adhesion and Detachment

12.3 Thermoresponsive Polymer Brushes Prepared Using ATRP

12.4 Thermoresponsive Polymer Brushes Prepared by RAFT Polymerization

12.5 Conclusions

Acknowledgments

References

Volume 2

Preface

List of Contributors

13 Biomimetic Anchors for Antifouling Polymer Brush Coatings

13.1 Introduction to Biofouling Management

13.2 Polymer Brushes for Surface Functionalization

13.3 Biomimetic Anchors for Antifouling Polymer Brushes

13.4 Barnacle Cement as Anchor for Antifouling Polymer Brushes

13.5 Conclusion and Outlooks

References

14 Protein Adsorption Process Based on Molecular Interactions at Well-Defined Polymer Brush Surfaces

14.1 Introduction

14.2 Utility of Polymer Brush Layers as Highly Controllable Polymer Surfaces

14.3 Performance of Polymer Brush Surfaces as Antifouling Biointerfaces

14.4 Elucidation of Protein Adsorption Based on Molecular Interaction Forces

14.5 Concluding Remarks

References

15 Are Lubricious Polymer Brushes Antifouling? Are Antifouling Polymer Brushes Lubricious?

15.1 Introduction

15.2 Poly(ethylene glycol) Brushes

15.3 Beyond Simple PEG Brushes

15.4 Conclusion

References

16 Biofunctionalized Brush Surfaces for Biomolecular Sensing

16.1 Introduction

16.2 Biorecognition Units

16.3 Immobilization Strategy

16.4 Microstructure and Morphology of Biobrush Layers

16.5 Transduction Schemes Based upon Grafted Biomolecules

16.6 Conclusions

Acknowledgments

References

17 Phenylboronic Acid and Polymer Brushes: An Attractive Combination with Many Possibilities

17.1 Introduction: Polymer Brushes and Synthesis

17.2 Boronic Acid Brushes

17.3 Affinity Separation

17.4 Sensors

17.5 Biomedical Applications

17.6 Conclusions

References

18 Smart Surfaces Modified with Phenylboronic Acid Containing Polymer Brushes

18.1 Introduction

18.2 Molecular Mechanism of PBA-Based Smart Surfaces

18.3 pH-Responsive Surfaces Modified with PBA Polymer Brush and Their Applications

18.4 Sugar-Responsive Surfaces Modified with PBA Polymer Brush and Their Applications

18.5 PBA Polymer Brush–Based pH/Sugar Dual-Responsive OR Logic Gates and Their Applications

18.6 PBA Polymer Brush-Based pH/Sugar Dual-Responsive AND Logic Gates and Their Applications

18.7 PBA-Based Smart Systems beyond Polymer Brush and Their Applications

18.8 Conclusion and Perspective

References

19 Polymer Brushes and Microorganisms

19.1 Introduction

19.2 Brushes and Microbes

19.3 Conclusions and Future Perspectives

Acknowledgments

References

20 Design of Polymer Brushes for Cell Culture and Cellular Delivery

Abbreviations

20.1 Introduction

20.2 Protein-Resistant Polymer Brushes for Tissue Engineering and

In Vitro

Assays

20.3 Designing Brush Chemistry to Control Cell Adhesion and Proliferation

20.4 Biofunctionalized Polymer Brushes to Regulate Cell Phenotype

20.5 Polymer Brushes for Drug and Gene Delivery Applications

20.6 Summary

Acknowledgments

References

21 DNA Brushes: Self-Assembly, Physicochemical Properties, and Applications

21.1 Introduction

21.2 Applications

21.3 Preparation

21.4 Physicochemical Properties of DNA Brushes

21.5 Hybridization in DNA Brushes

21.6 Other Bioprocesses in DNA Brushes

21.7 Perspective

Acknowledgments

References

22 DNA Brushes: Advances in Synthesis and Applications

22.1 Introduction

22.2 Synthesis of DNA Brushes

22.3 Properties and Applications of DNA Brushes

22.4 Conclusion and Outlook

References

23 Membrane Materials Form Polymer Brush Nanoparticles

23.1 Introduction

23.2 Colloidal Membranes Pore-Filled with Polymer Brushes

23.3 Self-Assembled PBNPs Membranes

23.4 Summary

References

24 Responsive Polymer Networks and Brushes for Active Plasmonics

24.1 Introduction

24.2 Tuning Spectrum of Surface Plasmon Modes

24.3 Polymers Used for Actuating of Plasmonic Structures

24.4 Imprinted Thermoresponsive Hydrogel Nanopillars

24.5 Thermoresponsive Hydrogel Nanogratings Fabricated by UV Laser Interference Lithography

24.6 Electrochemically Responsive Hydrogel Microgratings Prepared by UV Photolithography

24.7 Conclusions

Acknowledgments

References

25 Polymer Brushes as Interfacial Materials for Soft Metal Conductors and Electronics

25.1 Introduction

25.2 Mechanisms of Polymer-Assisted Metal Deposition

25.3 Role of Polymer Brushes

25.4 Selection Criterion of Polymer Brushes Enabling PAMD

25.5 Strategies to Fabricate Patterned Metal Conductors

25.6 PAMD on Different Substrates and Their Applications in Soft Electronics

25.7 Conclusion, Prospects, and Challenges

References

26 Nanoarchitectonic Design of Complex Materials Using Polymer Brushes as Structural and Functional Units

26.1 Introduction

26.2 Nanoparticles at Spherical Polymer Brushes: Hierarchical Nanoarchitectonic Construction of Complex Functional Materials

26.3 Nanotube and Nanowire Forests Bearing Polymer Brushes

26.4 Fabrication of Free-Standing “Soft” Micro- and Nanoobjects Using Polymer Brushes

26.5 Solid-State Polymer Electrolytes Based on Polymer Brush–Modified Colloidal Crystals

26.6 Proton-Conducting Membranes with Enhanced Properties Using Polymer Brushes

26.7 Hybrid Architectures Combining Mesoporous Materials and Responsive Polymer Brushes: Gated Molecular Transport Systems and Controlled Delivery Vehicles

26.8 Ensembles of Metal Nanoparticles Modified with Polymer Brushes

26.9 Conclusions

Acknowledgments

References

Index

EULA

List of Tables

Chapter 7

Table 7.1

Chapter 11

Table 11.1

Table 11.2

Table 11.3

Table 11.4

Chapter 14

Table 14.1

Chapter 17

Table 17.1

Table 17.2

Table 17.3

Chapter 19

Table 19.1

Table 19.2

Table 19.3

Table 19.4

Chapter 23

Table 23.1