Progress in Inorganic Chemistry, Volume 57 E-Book

• Herausgeber: John Wiley & Sons
• Kategorie: Wissenschaft und neue Technologien
• Serie: Progress in Inorganic Chemistry
• Sprache: Englisch

Seitenzahl: 1006

Veröffentlichungsjahr: 2011

Beschreibung

This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 57 continues to report recent advances with a significant, up-to-date selection of contributions from internationally-recognized researchers. The chapters of this volume are devoted to the following topics: Mechanisms of Water Oxidation Catalyzed by Ruthenium Coordination Complexes; Biomimetic and non-biological dinuclear Mx+-complex catalyzed alcoholysis reactions of phosphoryl transfer reactions; Photoactivated DNA Cleavage and Anticancer Activity of 3d-Metal Complexes; and more.

Leseprobe

Contents

Cover

Advisory Board

Title Page

Copyright

Chapter 1: Mechanisms of Water Oxidation Catalyzed by Ruthenium Coordination Complexes

I. Introduction

II. Oxygen–Oxygen Coupling of Coordinated Water

III. Homolytic Cleavage of O−H Bonds: The “Blue Dimer”

IV. Nucleophilic Addition of Water to Electrophilic Ruthenyl Oxo Ligands

V. Expansion of the Coordination Sphere

VI. Medium Effects

VII. Future Directions

VIII. Conspectus

Acknowledgments

Abbreviations

References

Chapter 2: Biomimetic and Nonbiological Dinuclear Mx+ Complex-Catalyzed Alcoholysis Reactions of Phosphoryl Transfer Reactions

I. Introduction

II. Early Studies with Nonbiological Metal Ions

III. Studies of the Cleavage of Phosphate Diesters Promoted by Metal Ion Complexes in Alcohol

IV. Fast Metal Ion Promoted Hydrolysis in Wet Alcohol: 20:ZnII2:(RO−) Promoted Hydrolysis of a DNA Model (21b) in Ethanol

V. Conclusions

Acknowledgments

Abbreviations

References

Chapter 3: Photoactivated DNA Cleavage and Anticancer Activity of 3d Metal Complexes

I. Introduction

II. DNA Binding and Cleavage Modes

III. Photocleavage of DNA: Mechanistic Pathways

IV. A Brief Account on 4d–5d Metal Complexes Showing DNA Photocleavage and Anticancer Activity

V. Photocleavage of DNA and Anticancer Activity of 3d Metal Complexes

VI. Summary and Prospects

Acknowledgments

Abbreviations

References

Chapter 4: Design and Evolution of Artificial Metalloenzymes: Biomimetic Aspects

I. General Aspects of Artificial Metalloenzymes

II. Artificial Metalloenzymes Based on the Biotin–Avidin Technology

III. Progress and Conclusions

Acknowledgments

Abbreviations

References

Chapter 5: Functionalization of Fluorinated Aromatics by Nickel-Mediated C−H and C−F Bond Oxidative Addition: Prospects for the Synthesis of Fluorine-Containing Pharmaceuticals

I. Introduction

II. Nickel C−H Bond Activation and Functionalization

III. Reactivity of C−F Bonds

IV. Reactions of C−F Activation Products

V. Spectroscopic Methods

VI Outlook

Abbreviations

References

Chapter 6: DNA Based Metal Catalysis

I. Introduction

II. DNA Templated Metal Catalysis

III. Asymmetric DNA Based Metal Catalysis

IV. Mechanistic Investigations Into DNA Based Catalysis

V. Conclusion and Perspective

Abbreviations

References

Chapter 7: Metallo-β-lactamases and Their Synthetic Mimics: Structure, Function, and Catalytic Mechanism

I. Zinc and its Biological Importance

II. Metallo-β-Lactamases and Antibiotic Resistance

IV. Structure and Function of Metallo-β-Lactamases

V. Mechanism of Action of Metallo-β-Lactamases

VI. Inhibition of Metallo-β-Lactamases

VII. Functional Mimics of Metallo-β-Lactamases

VIII. Conclusions

Acknowledgments

Abbreviations

References

Chapter 8: A New Class of Nanostructured Inorganic–Organic Hybrid Semiconductors Based on II–VI Binary Compounds

I. Introdution

II. Design, Synthesis, and Crystal Growth

III. Crystal Structures

IV. Properties

V. Concluding Remarks

Acknowledgments

Abbreviations

References

Chapter 9: Oxygen Evolution Reaction Chemistry of Oxide-Based Electrodes

I. Introduction

II. Synthesis and Physical Properties of Oxide-Based Electrodes

III. Heterogeneous Electron-Transfer Theory and Electrode Kinetics

IV. The Oxygen Evolution Reaction Mediated by Metal Oxides

V. Concluding Remarks

Acknowledgments

Abbreviations

References

Subject Index

Cumulative Index

Advisory Board

JACQUELINE K. BARTON

CALIFORNIA INSTITUTE OF TECHNOLOGY, PASADENA, CALIFORNIA

JAMES P. COLLMAN

STANFORD UNIVERSITY, STANFORD, CALIFORNIA

ALAN H. COWLEY

UNIVERSITY OF TEXAS, AUSTIN, TEXAS

RICHARD H. HOLM

HARVARD UNIVERSITY, CAMBRIDGE, MASSACHUSETTS

EIICHI KIMURA

SHIZUOKA UNIVERSITY, SHIZUOKA, JAPAN

NATHAN S. LEWIS

CALIFORNIA INSTITUTE OF TECHNOLOGY, PASADENA, CALIFORNIA

STEPHEN J. LIPPARD

MASSACHUSETTS INSTITUTE OF TECHNOLOGY, CAMBRIDGE, MASSACHUSETTS

TOBIN J. MARKS

NORTHWESTERN UNIVERSITY, EVANSTON, ILLINOIS

KARL WIEGHARDT

MAX-PLANCK-INSTITUT, MÜLHEIM, GERMANY

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Library of Congress Catalog Card Number: 59-13035

ISBN 978-1-118-01063-1

oBook ISBN: 978-1-118-14823-5

ePDF ISBN: 978-1-118-14868-6

ePub ISBN: 978-1-118-14820-4

eMobi ISBN: 978-1-118-14867-9