Progress in Inorganic Chemistry, Volume 59 E-Book

• Herausgeber: John Wiley & Sons
• Kategorie: Wissenschaft und neue Technologien
• Serie: Progress in Inorganic Chemistry
• Sprache: Englisch

Seitenzahl: 874

Veröffentlichungsjahr: 2014

Beschreibung

This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 59 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers.

The chapters of this volume are devoted to the following topics:
• Iron Catalysis in Synthetic Chemistry
• A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive Sites
• Selective Binding of Zn2+ Complexes to Non-Canonical Thymine or Uracil in DNA or RNA.
• Progress Toward the Electrocatalytic Production of Liquid Fuels from Carbon Dioxide
• Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity
• Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals
• Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging Oxidative Transformations

Leseprobe

CONTENTS

Cover

Advisory Board

Title Page

Copyright

Chapter 1: Iron Catalysis in Synthetic Chemistry

I. Introduction

II. Addition Reactions

III. The C–C Bond Formations VIA C–H Functionalization

IV. The C–H Bond Oxidation

V. Cross-Coupling Reactions

VI. Direct C–N Bond Formation VIA C–H Oxidation

VII. Iron-Catalyzed Amination

VIII. Sulfoxidations and Synthesis of Sulfoximines, Sulfimides, and Sulfoximides

IX. Reduction Reactions

X. Trifluoromethylation

XI. Conclusion

Acknowledgments

Abbreviations

References

Chapter 2: A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive Sites

I. Introduction

II. Photodynamic Therapy

III. Platinum and Rhodium Centers as Bioactive Sites

IV. Supramolecular Complexes as DNA Photomodification Agents

V. Conclusions

Acknowledgments

Abbreviations

References

Chapter 3: Selective Binding of Zn2+ Complexes to Non-Canonical Thymine or Uracil in DNA or RNA

I. Introduction

II. Interaction OF Zn2+ Macrocyclic Complexes with Nucleosides and Single-Stranded Oligonucleotides

III. Interaction of Zn2+ Macrocyclic Complexes with Double-Stranded Nucleic Acids

IV. Recognition of Thymine or Uracil Bulges and Other Non-Canonical Structures

V. Energetic Factors in DNA Binding: Toward More Selective Zn2+ Recognition Agents

VI. Summary

Acknowledgments

Abbreviations

References

Chapter 4: Progress Toward the Electrocatalytic Production of Liquid Fuels from Carbon Dioxide

I. Introduction

II. Electrocatalytic Reduction of CO2

III. Metal Complexes Supported by Macrocycles

IV. Metal Polypyridyl Complexes

V. Metal Phosphine Complexes

VI. Future Development of CO2 Reduction Catalysts: Nature as Inspiration

VII. Summary and Conclusions

Acknowledgments

Abbreviations

References

Chapter 5: Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity

I. Introduction

II. Anionic Dinitrosyl Iron Complexes

III. Cationic Dinitrosyl Iron Complexes

IV. Neutral Dinitrosyl Iron Complexes

V. Summary and Perspective

Acknowledgments

Abbreviations

References

Chapter 6: Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals

I. Introduction

II. Nitrosoalkanes and Nitrosoarenes

III. Nitrosamines

IV. Nitrosothiols

V. Alkyl Nitrites

VI. Outlook

Acknowledgments

Abbreviations

References

Chapter 7: Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging Oxidative Transformations

I. Aminopyridine Iron Complexes as Molecular Catalysts for Hydrocarbon Oxidations

II. Aminopyridine Manganese Complexes as Molecular Catalysts For Hydrocarbon Oxidations

III. Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Water Oxidation

IV. Conclusion

Acknowledgments

Abbreviations

References

Subject Index

Cumulative Index

End User License Agreement

List of Tables

Table I

Table II

Table III

Table IV

Table V

Table VI

Table VII

Table VIII

Table IX

Table X

Table XI

Table XII

Table XIII

Table XIV

Table XV

Table XVI

Table XVII

Table XVIII

Table XIX

Table XX

Table XXI

Table XXII

Table XXIII

Table XXIV

Table XXV

Table XXVI

Table XXVII

Table XXVIII

Table XXIX

Table XXX

Table XXXI

Table XXXII

Table XXXIII

Table XXXIV

Table XXXV

Table XXXVI

Table XXXVII

Table XXXVIII

Table XXXIX

Table XL

Table XLI

Table XLII

Table XLIII

Table XLIV

Table XLV

Table XLVI

Table XLVII

Table XLVIII

Table XLIX

Table L

Table LI

Table LII

Table LIII

Table LIV

Table LV

Table LVI

Table LVII

Table LVIII

Table LIX

Table LX

Table LXI

Table LXII

Table LXIII

Table LXIV

Table I

Table I

Table II

Table III

Table I

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Table II

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Table IV

Table V

Table VI

Table I

Table II

Table III

Table IV

Table V

Table VI

List of Illustrations

Figure 1

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Scheme 1

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Chart 1

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Guide

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Advisory Board

JACQUELINE K. BARTON

CALIFORNIA INSTITUTE OF TECHNOLOGY, PASADENA, CALIFORNIA

SHUNICHI FUKUZUMI

OSAKA UNIVERSITY, OSAKA, JAPAN

CLARK R. LANDIS

UNIVERSITY OF WISCONSIN, MADISON, WISCONSIN

NATHAN S. LEWIS

CALIFORNIA INSTITUTE OF TECHNOLOGY, PASADENA, CALIFORNIA

STEPHEN J. LIPPARD

MASSACHUSETTS INSTITUTE OF TECHNOLOGY, CAMBRIDGE, MASSACHUSETTS

JEFFREY R. LONG

UNIVERSITY OF CALIFORNIA, BERKELEY, CALIFORNIA

THOMAS E. MALLOUK

PENNSYLVANIA STATE UNIVERSITY, UNIVERSITY PARK, PENNSYLVANIA

TOBIN J. MARKS

NORTHWESTERN UNIVERSITY, EVANSTON, ILLINOIS

JAMES M. MAYER

YALE UNIVERSITY, NEW HAVEN, CONNECTICUT

DAVID MILSTEIN

WEIZMANN INSTITUTE OF SCIENCE, REHOVOT, ISRAEL

WONWOO NAM

EWHA WOMANS UNIVERSITY, SEOUL, KOREA

VIVIAN W. W. YAM

UNIVERSITY OF HONG KONG, HONG KONG

Progress in Inorganic Chemistry

Volume 59

Edited by

Kenneth D. Karlin

Department of ChemistryJohns Hopkins UniversityBaltimore, Maryland

Cover Design: Wiley

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Library of Congress Cataloging-in-Publication Data is available.

Library of Congress Catalog Number: 59013035

ISBN: 978-1-118-87016-7

Iron Catalysis in Synthetic Chemistry

Sujoy Rana, Atanu Modak, Soham Maity, Tuhin Patra, and Debabrata Maiti

Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, India

CONTENTS

I. Introduction

II. Addition Reactions

A. Cycloadditions

1. The [2 + 2] Cycloaddition

2. The [3 + 2] Cycloaddition

3. The [2 + 2 + 2] Cycloaddition

4. The [4 + 2] Cycloaddition

B. Cyclopropanation

C. Aziridination and Aziridine Ring-Opening Reactions

D. Carbometalation of C—C Unsaturated Bond

E. Michael Addition

F. Barbier-Type Reaction

G. Kharasch Reaction

III. The C—C Bond Formations VIA C—H Functionalization

A. The C—H Arylation

1. Direct Arylation With Organometallic Reagents

2. Direct Arylation With Aryl Halides

B. The C—C Bond Formation Via Cross-Dehydrogenative Coupling

1. The CDC Between Two sp

3

C—H Bonds

2. The CDC Between sp

3

and sp

2

C—H Bonds

3. The CDC Between sp

3

and sp C—H Bonds

C. The C—C Bond Formation via Cross-Decarboxylative Coupling

D. The C—C Bond Formation via Alkene Insertion

E. Oxidative Coupling of Two C—H Bonds