Zinc Catalysis E-Book

• Herausgeber: Wiley-VCH
• Kategorie: Wissenschaft und neue Technologien
• Sprache: Englisch

Seitenzahl: 408

Veröffentlichungsjahr: 2015

Beschreibung

Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.

Leseprobe

Table of Contents

Cover

Related Titles

Title Page

Copyright

List of Contributors

Chapter 1: Introduction: Zinc Catalysts for Organic Transformations

References

Chapter 2: Zinc-Catalyzed Reductions of Unsaturated Compounds

2.1 Introduction

2.2 Hydrosilylation of Unsaturated Compounds

2.3 Hydrogenation

2.4 Transfer Hydrogenation of Unsaturated Compounds

2.5 Concluding Remarks

References

Chapter 3: Zinc-Catalyzed Oxidation Reactions

3.1 Introduction

3.2 Oxidative Transformation of Alkenes

3.3 Oxidative Transformation of Aldehydes

3.4 Oxidative Transformation of C–X Bonds (X = O, N, and S)

3.5 Oxidative Functionalization of sp

3

C–H Bonds

3.6 Other Oxidative Reactions with Redox-Active Ligands

3.7 Summary and Outlook

References

Chapter 4: Zinc-Catalyzed Friedel–Crafts Reactions

4.1 Introduction

4.2 Friedel–Crafts Acylation

4.3 Friedel–Crafts Alkylations

4.4 Conclusions

References

Chapter 5: Zinc-Catalyzed Hydroamination Reactions

5.1 Introduction

5.2 Inorganic Zinc Salts as Catalysts

5.3 Aminotroponiminate Zinc Complexes as Catalysts

5.4 Other Zinc Organometallic Compounds as Catalysts

5.5 Double Metal Cyanide Catalysts

5.6 Summary

References

Chapter 6: Zinc-Catalyzed C–C Bond Formation

6.1 Introduction

6.2 Zinc-Catalyzed Aldol-Type Reactions

6.3 Zinc-Catalyzed Cycloaddition Reactions

6.4 Zinc-Catalyzed Addition of Organometallic Reagents to Carbonyl and Related Compounds

6.5 Zinc-Catalyzed Cross-Coupling Reactions

6.6 Radical Reactions Involving Catalytic Amounts of Zinc

6.7 Zinc-Catalyzed Reactions through Alkyne Activation

6.8 Zinc-Catalyzed Cyclopropanation Reactions

6.9 Other Zinc-Catalyzed Reactions

6.10 Summary and Outlook

References

Chapter 7: Zinc-Catalyzed C–N and C–O Bond Formation Reactions

7.1 Introduction

7.2 Zinc-Catalyzed C–N Bond Formation Reactions

7.3 Zinc-Catalyzed C–O Bond Formation Reactions

7.4 Summary and Conclusion

References

Chapter 8: Zinc-Catalyzed Transformation of Carbon Dioxide

8.1 Introduction

8.2 Zinc Catalysts for the Copolymerization of Epoxides and CO

2

8.3 Zinc-Catalyzed Synthesis of Cyclic Carbonates Utilizing Carbon Dioxide as a Chemical Feedstock

8.4 Summary

References

Chapter 9: Zinc-Catalyzed Depolymerization Reactions

9.1 Introduction

9.2 Zinc-Catalyzed Depolymerization of Polyethers

9.3 Zinc-Catalyzed Depolymerization of Polyesters

9.4 Zinc-Catalyzed Depolymerization of Silicones

9.5 Summary

References

Chapter 10: Applications of Zinc-Promoted Reaction in Total Synthesis

10.1 Introduction

10.2 Zinc-Promoted Reactions without Ligands

10.3 Zinc-Mediated Reactions with Ligands

10.4 Other Zinc-Promoted Reactions

References

Chapter 11: Application of Organozinc Reagents in Oxidative Coupling Reactions

11.1 Introduction

11.2 Oxidative Coupling between Zinc Reagents and C(sp) Nucleophiles

11.3 Oxidative Coupling between Organozinc Reagents and C(sp

2

) Nucleophiles

11.4 Oxidative Coupling between Organozinc Reagents and C(sp

3

)-Nucleophiles

11.5 Oxidative Coupling between Organozinc Reagents and Heteroatom Nucleophiles

11.6 Conclusion

References

Index

End User License Agreement

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Guide

Cover

Table of Contents

Begin Reading

List of Illustrations

Figure 1.1

Figure 1.2

Scheme 2.1

Scheme 2.2

Scheme 2.3

Scheme 2.4

Scheme 2.5

Scheme 2.6

Scheme 2.7

Scheme 2.8

Scheme 2.9

Scheme 2.10

Scheme 2.11

Scheme 2.12

Scheme 2.13

Scheme 2.14

Scheme 2.15

Scheme 2.16

Scheme 2.17

Scheme 2.18

Scheme 2.19

Scheme 2.20

Scheme 2.21

Scheme 2.22

Scheme 2.23

Scheme 2.24

Scheme 2.25

Scheme 2.26

Scheme 2.27

Scheme 2.28

Scheme 2.29

Scheme 2.30

Scheme 2.31

Scheme 2.32

Scheme 3.1

Scheme 3.2

Scheme 3.3

Scheme 3.4

Scheme 3.5

Scheme 3.6

Scheme 3.7

Scheme 3.8

Scheme 3.9

Scheme 3.10

Scheme 3.11

Scheme 3.12

Scheme 3.13

Scheme 3.14

Scheme 3.15

Scheme 3.16

Scheme 3.17

Scheme 3.18

Scheme 3.19

Scheme 3.20

Scheme 3.21

Scheme 3.22

Scheme 3.23

Scheme 3.24

Scheme 3.25

Scheme 3.26

Scheme 3.27

Scheme 4.1

Figure 4.1

Scheme 4.2

Figure 4.2

Scheme 4.3

Figure 4.3

Figure 4.4

Scheme 4.4

Scheme 4.5

Scheme 4.6

Scheme 4.7

Scheme 4.8

Scheme 4.9

Scheme 4.10

Figure 4.5

Scheme 4.11

Scheme 4.12

Scheme 4.13

Scheme 4.14

Scheme 4.15

Scheme 4.16

Figure 4.6

Scheme 4.17

Scheme 4.18

Scheme 4.19

Scheme 4.20

Scheme 4.21

Scheme 4.22

Scheme 4.23

Scheme 4.24

Scheme 5.1

Scheme 5.2

Scheme 5.3

Scheme 5.4

Scheme 5.5

Scheme 5.6

Scheme 5.7

Scheme 5.8

Scheme 5.9

Scheme 5.10

Scheme 5.11

Scheme 5.12

Scheme 5.13

Scheme 5.14

Scheme 5.15

Figure 5.1

Figure 5.2

Scheme 5.16

Scheme 5.17

Scheme 5.18

Scheme 5.19

Scheme 5.20

Figure 5.3

Scheme 5.21

Scheme 5.22

Scheme 5.23

Scheme 5.24

Figure 5.4

Scheme 5.25

Scheme 5.26

Scheme 5.27

Scheme 6.1

Scheme 6.2

Scheme 6.3

Scheme 6.4

Scheme 6.5

Scheme 6.6

Scheme 6.7

Scheme 6.8

Scheme 6.9

Scheme 6.10

Scheme 6.11

Scheme 6.12

Scheme 6.13

Scheme 6.14

Scheme 6.15

Scheme 6.16

Scheme 6.17

Scheme 6.18

Scheme 6.19

Scheme 6.20

Scheme 6.21

Scheme 6.22

Scheme 6.23

Scheme 6.24

Scheme 6.25

Scheme 6.26

Scheme 6.27

Scheme 6.28

Scheme 6.29

Scheme 6.30

Scheme 6.31

Scheme 6.32

Scheme 6.33

Scheme 6.34

Scheme 6.35

Scheme 6.36

Scheme 6.37

Scheme 6.38

Scheme 6.39

Scheme 6.40

Scheme 6.41

Scheme 6.42

Scheme 6.43

Scheme 6.44

Scheme 6.45

Scheme 6.46

Scheme 6.47

Scheme 7.1

Scheme 7.2

Scheme 7.3

Scheme 7.4

Scheme 7.5

Scheme 7.6

Scheme 7.7

Scheme 7.8

Scheme 7.9

Scheme 7.10

Scheme 7.11

Scheme 7.12

Scheme 7.13

Scheme 7.14

Scheme 7.15

Scheme 7.16

Scheme 7.17

Scheme 7.18

Scheme 7.19

Scheme 7.20

Scheme 7.21

Scheme 7.22

Scheme 7.23

Scheme 7.24

Scheme 7.25

Scheme 7.26

Scheme 7.27

Scheme 7.28

Scheme 7.29

Scheme 7.30

Scheme 7.31

Scheme 7.32

Scheme 7.33

Scheme 7.34

Scheme 7.35

Scheme 7.36

Scheme 7.37

Scheme 7.38

Scheme 7.39

Scheme 7.40

Scheme 7.41

Scheme 7.42

Scheme 7.43

Scheme 7.44

Scheme 7.45

Figure 8.1

Figure 8.2

Figure 8.3

Figure 8.4

Figure 8.5

Figure 8.6

Figure 8.7

Figure 8.8

Figure 8.9

Figure 8.10

Figure 8.11

Figure 8.12

Figure 8.13

Figure 8.14

Figure 8.15

Figure 8.16

Figure 8.17

Figure 8.18

Figure 8.19

Figure 8.20

Figure 8.21

Figure 8.22

Figure 8.23

Figure 8.24

Scheme 9.1

Scheme 9.2

Scheme 9.3

Scheme 9.4

Scheme 9.5

Scheme 9.6

Scheme 9.7

Scheme 9.8

Scheme 9.9

Scheme 9.10

Scheme 9.11

Scheme 9.12

Scheme 9.13

Scheme 9.14

Scheme 10.1

Scheme 10.2

Scheme 10.3

Scheme 10.4

Scheme 10.5

Scheme 10.6

Scheme 10.7

Scheme 10.8

Scheme 10.9

Scheme 10.10

Scheme 10.11

Scheme 10.12

Scheme 10.13

Scheme 10.14

Scheme 10.15

Scheme 10.16

Scheme 10.17

Scheme 10.18

Scheme 10.19

Scheme 10.20

Scheme 10.21

Scheme 10.22

Scheme 10.23

Scheme 10.24

Scheme 10.25

Scheme 10.26

Scheme 10.27

Scheme 10.28

Scheme 10.29

Scheme 10.30

Scheme 10.31

Scheme 10.32

Scheme 10.33

Scheme 10.34

Scheme 10.35

Scheme 10.36

Scheme 10.37

Scheme 10.38

Scheme 10.39

Scheme 10.40

Scheme 10.41

Scheme 10.42

Scheme 10.43

Scheme 10.44

Scheme 10.45

Scheme 10.46

Scheme 10.47

Scheme 10.48

Scheme 10.49

Scheme 10.50

Scheme 10.51

Scheme 10.52

Scheme 10.53

Scheme 10.54

Scheme 10.55

Scheme 10.56

Scheme 10.57

Scheme 10.58

Scheme 10.59

Scheme 10.60

Scheme 10.61

Scheme 10.62

Scheme 10.63

Scheme 10.64

Scheme 10.65

Scheme 10.66

Scheme 10.67

Scheme 10.68

Scheme 10.69

Scheme 10.70

Scheme 10.71

Scheme 10.72

Scheme 10.73

Scheme 10.74

Scheme 10.75

Scheme 10.76

Scheme 10.77

Scheme 10.78

Scheme 10.79

Scheme 10.80

Scheme 10.81

Scheme 10.82

Scheme 11.1

Scheme 11.2

Scheme 11.3

Scheme 11.4

Scheme 11.5

Scheme 11.6

Scheme 11.7

Scheme 11.8

Scheme 11.9

Scheme 11.10

Scheme 11.11

Scheme 11.12

Scheme 11.13

Scheme 11.14

Scheme 11.15

Scheme 11.16

Scheme 11.17

Scheme 11.18

Scheme 11.19

Scheme 11.20

Scheme 11.21

Scheme 11.22

Scheme 11.23

Scheme 11.24

Scheme 11.25

Scheme 11.26

Scheme 11.27

Scheme 11.28

Scheme 11.29

Scheme 11.30

Scheme 11.31

Scheme 11.32

Scheme 11.33

Scheme 11.34

Scheme 11.35

List of Tables

Table 3.1

Table 4.1

Table 5.1

Table 5.2

Table 5.3

Table 5.4

Table 5.5

Table 5.6

Table 5.7

Table 5.8

Table 5.9

Table 5.10

Table 5.11

Table 5.12

Table 5.13

Table 5.14

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Edited by Stephan Enthaler and Xiao-Feng Wu

Zinc Catalysis

Applications in Organic Synthesis

The Editors

Dr. Stephan Enthaler

Technische Universität Berlin

Institut für Chemie

Straße des 17. Juni 135

Gebäude C, 272

10623 Berlin

Germany

Dr. Xiao-Feng Wu

Leibniz-Institut für Katalyse

an der Universität Rostock e.V.

Albert-Einstein-Straße 29a

18059 Rostock

Germany

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