Open-Ended Problems - James Patrick Abulencia - E-Book

Open-Ended Problems E-Book

James Patrick Abulencia

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Beschreibung

This is a unique book with nearly 1000 problems and 50 case studies on Open-Ended Problems in every key topic in chemical engineering that helps to better prepare chemical engineers for the future. The term "open-ended problem" basically describes an approach to the solution of a problem and/or situation for which there is not a unique solution. The Introduction to the general subject of Open-Ended Problems is followed by 22 chapters, each of which addresses a traditional chemical engineering or chemical engineering-related topic. Each of these chapters contain a brief overview of the subject matter of concern, e.g., thermodynamics, which is followed by sample Open-Ended Problems that have been solved (by the authors) employing one of the many possible approaches to the solutions. This is then followed by approximately 40-45 Open-Ended Problems with no solutions (although many of the authors' solutions are available for those who adopt the book for classroom or training purposes). A reference section is included with the chapter's contents. Term projects, comprised of 12 additional chapter topics, complement the presentation. This book provides academic, industrial, and research personnel with the material that covers the principles and applications of open-ended chemical engineering problems in a thorough and clear manner. Upon completion of the text, the reader should have acquired not only a working knowledge of the principles of chemical engineering, but also (and more importantly) experience in solving Open-Ended Problems. What many educators have learned is that the applications and implications of Open-Ended Problems are not only changing professions, but also are moving so fast that many have not yet grasped their tremendous impact. The book drives home that the open-ended approach will revolutionize the way chemical engineers will need to operate in the future.

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Contents

Cover

Half Title page

Title page

Copyright page

Dedication

Preface

Acknowledgement

Part I: Introduction to the Open-Ended Problem Approach

Part II: Chemical Engineering Topics

Chapter 1: Materials Science and Engineering

1.1 Overview

1.2 Crystallography of Perfect Crystals (CPC)

1.3 Crystallography of Real Crystals (CRC)

1.4 Materials of Construction

1.5 Resistivity

1.6 Semiconductors

1.7 Illustrative Open-Ended Problems

1.8 Open-Ended Problems

References

Chapter 2: Applied Mathematics

2.1 Overview

2.2 Differentiation and Integration

2.3 Simultaneous Linear Algebraic Equations

2.4 Nonlinear Algebraic Equations

2.5 Ordinary and Partial Differential Equation

2.6 Optimization

2.7 Illustrative Open-Ended Problems

2.8 Open-Ended Problems

References

Chapter 3: Stoichiometry

3.1 Overview

3.2 The Conservation Law

3.3 Conservation of Mass, Energy, and Momentum [1]

3.4 Stoichiometry [1]

3.5 Illustrative Open-Ended Problems

3.6 Open-Ended Problems

References

Chapter 4: Thermodynamics

4.1 Overview

4.2 Enthalpy Effects

4.3 Second Law Calculations [2]

4.4 Phase Equilibrium

4.5 Chemical Reaction Equilibrium

4.6 Illustrative Open-Ended Problems

4.7 Open-Ended Problems

References

Chapter 5: Fluid Flow

5.1 Overview

5.2 Basic Laws

5.3 Key Fluid Flow Equations

5.4 Fluid-Particle Applications

5.5 Illustrative Open-Ended Problems

5.6 Open-Ended Problems

References

Chapter 6: Heat Transfer

6.1 Overview

6.2 Conduction

6.3 Convection

6.4 Radiation

6.5 Condensation, Boiling, Refrigeration, and Cryogenics

6.6 Heat Exchangers

6.7 Illustrative Open-Ended Problems

6.8 Open-Ended Problems

References

Chapter 7: Mass Transfer Operations

7.1 Overview

7.2 Absorption

7.3 Adsorption [3]

7.4 Distillation

7.5 Other Mass Transfer Processes

7.6 Illustrative Open-Ended Problems

7.7 Open-Ended Problems

References

Chapter 8: Chemical Reactors

8.1 Overview

8.2 Chemical Kinetics

8.3 Batch Reactors

8.4 Continuous Stirred Tank Reactors (CSTRs)

8.5 Tubular Flow Reactors

8.6 Catalytic Reactors

8.7 Thermal Effects

8.8 Illustrative Open-Ended Problems

8.9 Open-Ended Problems

References

Chapter 9: Process Control and Instrumentation

9.1 Overview

9.2 Process Control Fundamentals

9.3 Feedback Control

9.4 Feedforward Control

9.5 Cascade Control

9.6 Alarms and Trips

9.7 Illustrative Open-Ended Problems

9.8 Open-Ended Problems

References

Chapter 10: Economics and Finance

10.1 Overview

10.2 Capital Costs

10.3 Operating Costs

10.4 Project Evaluation

10.5 Perturbation Studies in Optimization

10.6 Principles of Accounting

10.7 Illustrative Open-Ended Problems

10.8 Open-Ended Problems

References

Chapter 11: Plant Design

11.1 Overview

11.2 Preliminary Studies

11.3 Process Schematics

11.4 Material and Energy Balances

11.5 Equipment Design

11.6 Instrumentation and Controls

11.7 Design Approach

11.8 The Design Report

11.9 Illustrative Open-Ended Problems

11.10 Open-Ended Problems

References

Chapter 12: Transport Phenomena

12.1 Overview

12.2 Development of Equations

12.3 The Transport Equations

12.4 Boundary and Initial Conditions

12.5 Solution of Equations

12.6 Analogies

12.7 Illustrative Open-Ended Problems

12.8 Open-Ended Problems

References

Chapter 13: Project Management

13.1 Overview

13.2 Managing Project Activities

13.3 Initiating

13.4 Planning/Scheduling [1–4]

13.5 Gantt Charts

13.6 Executing/Implementing [1,4]

13.7 Monitoring/Controlling [1,4]

13.8 Completion/Closing

13.9 Reports

13.10 Illustrative Open-Ended Problems

13.11 Open-Ended Problems

References

Chapter 14: Environmental Management

14.1 Overview

14.2 Environmental Regulations [3]

14.3 Classification, Sources, and Effects Of Pollutants [1,2]

14.4 Multimedia Concerns [1,2]

14.5 ISO 14000 [1–8]

14.6 The Pollution Prevention Concept [1–3,9]

14.7 Green Chemistry and Green Engineering

14.8 Sustainability

14.9 Illustrative Open-Ended Problems

14.10 Open-Ended Problems

References

Chapter 15: Environmental Health and Hazard Risk Assessment

15.1 Overview

15.2 Safety and Accidents

15.3 Regulations

15.4 Emergency Planning and Response

15.5 Introduction to Environmental Risk Assessment

15.6 Health Risk Assessment

15.7 Hazard Risk Assessment

15.8 Illustrative Open-Ended Problems

15.9 Open-Ended Problems

References

Chapter 16: Energy Management

16.1 Overview

16.2 Energy Resources

16.3 Energy Quantity/Availability

16.4 General Conservation Practices in Industry

16.5 General Domestic Conservation Applications

16.6 General Commercial Real Estate Conservation Applications

16.7 Architecture and the Role of Urban Planning [6,7]

16.8 The U.S. Energy Policy/Independence [1,8]

16.9 Illustrative Open-Ended Problems

16.10 Open-Ended Problems

References

Chapter 17: Water Management

17.1 Overview

17.2 Water as a Commodity and as a Human Right

17.3 The Hydrologic Cycle [2]

17.4 Water Usage

17.5 Regulatory Status [5]

17.6 Acid Rain

17.7 Treatment Processes

17.8 Future Concerns

17.9 Illustrative Open-Ended Problems

17.10 Open-Ended Problems

References

Chapter 18: Biochemical Engineering

18.1 Overview

18.2 Enzyme and Microbial Kinetics [4]

18.3 Enzyme Reaction Mechanisms

18.4 Effectiveness Factor [4]

18.5 Design Procedures

18.6 Illustrative Open-Ended Problems

18.7 Open-Ended Problems

References

Chapter 19: Probability and Statistics

19.1 Overview

19.2 Probability Definitions and Interpretations [2,3]

19.3 Introduction to Probability Distributions [2,3]

19.4 Discrete and Continuous Probability Distributions [2,3]

19.5 Contemporary Statistics

19.6 Regression Analysis (3)

19.7 Analysis of Variance

19.8 Illustrative Open-Ended Problems

19.9 Open-Ended Problems

References

Chapter 20: Nanotechnology

20.1 Overview

20.2 Early History [3]

20.3 Fundamentals and Basic Principles

20.4 Nanomaterials

20.5 Production Methods

20.6 Current Applications

20.7 Environmental Concerns [9,10]

20.8 Future Prospects [6,8,20,21]

20.9 Illustrative Open-Ended Problems

20.10 Open-Ended Problems

References

Chapter 21: Legal Considerations

21.1 Overview

21.2 Intellectual Property Law

21.3 Contract Law

21.4 Tort Law

21.5 Patents

21.6 Infringement and Interferences

21.7 Copyrights

21.8 Trademarks

21.9 The Engineering Professional Licensing Process

21.10 Illustrative Open-Ended Problems

21.11 Open-Ended Problems

References

Chapter 22: Ethics

22.1 Overview

22.2 The Present State

22.3 Moral Issues

22.4 Engineering Ethics [3,7]

22.5 Environmental Justice

22.6 Illustrative Open-Ended Problems

22.7 Open-Ended Problems

References

Part III: Term Projects

Chapter 23: Term Projects (2): Applied Mathematics

Term Project 23.1 Simplified Procedure for Solving Differential Equations

Term Project 23.2 The Weighted Sum Method of Analysis

References

Chapter 24: Term Projects (2): Stoichiometry

Term Project 24.1 A Vapor Pressure Equation

Term Project 24.2 Chemical Plant Solid Waste

Reference

Chapter 25: Term Projects (2): Thermodynamics

Term Project 25.1 Estimating Combustion Temperatures

Term Project 25.2 Generating Entropy Data

References

Chapter 26: Term Projects (6): Fluid Flow

Term Project 26.1 Pressure Drop – Velocity – Mesh Size Correlation

Term Project 26.2 Fanning’s Friction Factor: Equation Form

Term Project 26.3 An Improved Pressure Drop and Flooding Correlation

Term Project 26.4 Ventilation Model I

Term Project 26.5 Ventilation Model II

Term Project 26.6 Two – Phase Flow

References

Chapter 27: Term Projects (4): Heat Transfer

Term Project 27.1 Wilson’s Method

Term Project 27.2 Heat Exchanger Network I

Term Project 27.3 Heat Exchanger Network II

Term Project 27.4 Heat Exchanger Network III

References

Chapter 28: Term Projects (5): Mass Transfer Operations

Term Project 28.1 An Improved Absorber Design Procedure

Term Project 28.2 An Improved Adsorber Design Procedure

Term Project 28.3 Multicomponent Distillation Calculations

Term Project 28.4 A New Liquid-Liquid Extraction Process

Term Project 28.5 Designing and Predicting the Performance of Cooling Towers

References

Chapter 29: Term Projects (2): Chemical Reactors

Term Project 29.1 Minimizing Volume Requirements for CSTRs in Series I

Term Project 29.2 Minimizing Volume Requirements for CSTRs in Series II

References

Chapter 30: Term Projects (4): Plant Design

Term Project 30.1 Chemical Plant Shipping Facilities

Term Project 30.2 Plant Tank Farms

Term Project 30.3 Chemical Plant Storage Requirements

Term Project 30.4 Inside Battery Limits (ISBL) and Process Flow Approach

References

Chapter 31: Term Projects (4): Environmental Management

Term Project 31.1 Dissolve The USEPA

Term Project 31.2 Solving Your Town’s Sludge Problem

Term Project 31.3 Benzene Underground Storage Tank Leak

Term Project 31.4 An Improved MSDS Sheet

References

Chapter 32: Term Projects (4): Health and Hazard Risk Assessment

Term Project 32.1 Nuclear Waste Management

Term Project 32.2 An Improved Risk Management Program

Term Project 32.3 Bridge Rail Accident: Fault and Event Tree Analysis

Term Project 32.4 HAZOP: Tank Car Loading Facility

References

Chapter 33: Term Projects (3): Unit Operations Laboratory Design Projects

Term Project 33.1 Hand Pump

Term Project 33.2 Rooftop Garden Bed

Term Project 33.3 Hydration Station Counter

Reference

Chapter 34: Term Projects (4): Miscellaneous Topics

Term Project 34.1 Standardizing Project Management

Term Project 34.2 Monte Carlo Simulation: Bus Section Failures in Electrostatic Precipitators

Term Project 34.3 Hurricane and Flooding Concerns

Term Project 34.4 Meteorites

References

Index

Open-Ended Problems

Copyright © 2015 by Scrivener Publishing LLC. All rights reserved.

Co-published by John Wiley & Sons, Inc. Hoboken, New Jersey, and Scrivener Publishing LLC, Salem, Massachusetts.Published simultaneously in Canada.

No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/permission.

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Library of Congress Cataloging-in-Publication Data:

ISBN 978-1-118-94604-6

To

Nicole, who signed up for a lifetime of addressing open-ended problems with me

(J.P.A.)

To

My two long-standing Manhattan College colleagues

Dr. John Jeris

Dr. Wally Matystik

(L.T.)

Preface

Chemical engineering is one of the fundamental disciplines of engineering, and contains many practical concepts that have been utilized in the past in countless real-world industrial applications. However, the profession is changing. Therefore, the authors considered writing a text that highlighted open-ended material since chemical engineers in the future will have to be innovative and creative in order to succeed in their careers. One approach to developing the chemical engineer’s ability to solve unique problems is by employing open-ended problems. Although the term “open-ended problem” has come to mean different things to different people, it describes an approach to the solution of a problem and/or situation where there is usually not a unique solution. The authors of this text have applied this approach by including numerous open-ended problems in several of their courses. Although the literature is inundated with texts emphasizing theory and theoretical derivations, the goal of this book is to present the subject of open-ended problems from a pragmatic point-of-view in order to better prepare chemical engineers for the future.

This book is the result of much effort from the authors, and has gone through classroom testing. It was difficult to decide what material to include and what to omit, and every attempt was made to offer sufficient chemical engineering course material at a level that could enable chemical engineers to better cope with original and unique problems that will be encountered later in practice. It should be noted that the authors cannot claim sole authorship to all of the essay material in this text. Although much of the material has been derived from sources that both of the authors have been directly involved, every effort has been made to acknowledge material drawn from other sources.

The book opens with an Introduction (Part I) to the general subject of open-ended problems. This is followed by 22 chapters (Part II), each of which addresses a traditional chemical engineering (or chemical engineering related) topic. Each of these chapters contain a brief overview of the subject matter of concern, e.g., thermodynamics, which is followed by three open-ended problems that have been solved by the authors, employing one of the many potential possible approaches to the solution. This is then followed by approximately 30-40 open-ended problems with no solutions. A reference section complements the chapter’s contents. Part III is concerned with term projects. Twelve chapter topics, including a total of 42 projects, are provided.

It is hoped that the book will describe the principles and applications of open-ended chemical engineering problems in a thorough and clear manner for academic, industrial, and government personnel. Upon completion of the text, the reader should have acquired not only a working knowledge of the principles of chemical engineering, but also (and more importantly) experience in solving open-ended problems. The authors strongly believe that, while understanding the traditional basic concepts is of paramount importance, this knowledge may be rendered virtually useless to future engineers if he/she cannot apply these concepts to unique real-world situations.

Last, but not least, the authors believe that this modest work will help the majority of individuals working and/or studying in the field of engineering to obtain a more complete understanding of chemical engineering. If you have come this far and read through the Preface, you have more than just a passing interest in this subject. The authors strongly suggest that you take advantage of the material available in this book and believe that it will be a worthwhile experience.

January 2015J. Patrick AbulenciaBronx, NY

Louis TheodoreEast Williston, NY

Acknowledgements

The authors were assisted during the preparation of this book by several individuals that we wish to acknowledge. Rita D’Aquino served as our executive editor, and spent many days proofing the manuscript and preparing the index. Colleen Kavanagh and Xi Chu are two Manhattan College students who assisted with preparing the manuscript and figures. The authors are sincerely grateful for all of your contributions.

Part I

INTRODUCTION TO THE OPEN-ENDED PROBLEM APPROACH

This part is a stand-alone portion of the book, which serves the sole purpose of introducing the reader to open-ended problems and the open-ended problem approach.

The reader is constantly reminded of the need for change in the chemical engineering curriculum and, there is a need to change. The key word in the new chemical engineering curriculum will be innovation. It must be innovation if the profession is to survive. Presenting problems with “discrete” solutions thwarts the preparation of students by constraining their vitality, energy, and intellectual capabilities, and will minimize their impact on the future marketplace. Thus, failure to develop the innovative skills of future chemical engineers will adversely affect their careers. Bottom line: creativity, imagination, and (once again) innovation will be a requisite for success in the future.

Finally, the reader should note that a good part of the material presented in this Part was adapted from the earlier work by Theodore titled Chemical Engineering: The Essential Reference, Chapter 30 Open-Ended Problems, McGraw-Hill, New York City, NY, 2014. [1]

Overview

The phrase for success at the turn of the 20th century was: work hard and you will succeed. What was heard during the careers of both authors as educators and practitioners was the phrase: work intelligently and you will succeed. However, the key phrase for the 21st century is: be innovative and you will succeed. This will be the theme for the engineers and scientists of tomorrow; and, more than any other profession, it will become the key to success for future chemical engineers. For success to follow, the education of chemical engineers, in terms of the curriculum, will have to change if they are to succeed.

As noted earlier, the key word in the new chemical engineering curriculum will be innovation. It must be innovation if the profession is to survive. It will require more than possessing traditional problem-solving skills in order for the chemical engineering workforce to be appropriately educated. The authors have always advocated that one of the most important jobs of an educator is to anticipate the future.

Career paths in chemical engineering are now undergoing a change—a drastic change in the authors’ opinion. The days of the need for massive numbers of chemical engineers required to size pumps, design heat exchangers, predict the performance of multi-component distillations columns is now a distinct memory. Handbook solutions are being replaced with creative, innovative action; hard work is being replaced by the need to understand software, etc. The conversion process will take time; educating and cultivating this intellectual approval for the new breed of engineers will not come overnight. But the time to start is NOW.

In terms of introduction, the cliché of the creative individual has unfortunately been aptly described throughout history- the Einsteinian wild hair, being locked in a room for days at a time, mumbling to one’s self, eating sporadically, lost in a fog of conflicting thoughts, not paying attention to one’s hygiene, working diligently until that times when the “light goes on” moment of discovery, etc. This chapter will provide (among other things) specific suggestions on how to develop and improve one’s critical thinking abilities. [2]

Engineering is one of the noblest of professions, and the authors are extremely proud to be part of it. They are fortunate to have served as chemical engineering educators during their careers. A good part of this effort was directed to improving critical thinking skills of students in recent years. Check any engineering school’s web-site and locate its mission statement. Many of these will carry the phrase “fosters creativity and innovation” among its students. But do they really? The authors hope so. But then again, how does one teach it? [2]

As a chemical engineering educator, one is required to teach traditional basic scientific and technical principles in courses like thermodynamics, heat transfer, reaction kinetics, etc., but, along with the lectures, one should include an emphasis on creativity, problem solving and failure(s). These three terms are definitely interrelated. Finding solutions to problems is a creative activity. Failure comes into play since there are often solutions with high uncertainty and many or no correct answers. [2]

The remainder of this part addresses a host of topics involved with open-ended problems and approaches. The following sections are addressed:

1. General Thoughts
2. The Authors’ Approach
3. Earlier Experiences
4. Developing Students’ Power of Critical Thinking
5. Creativity and Brainstorming
6. Inquiring Minds
7. Final Thoughts

General Thoughts

Here are a baker’s dozen general thoughts regarding the open-ended problem approach drawn from the files of one of the authors. [3]

1. Abstract reasoning is the ability to analyze information and solve problems on a complex, thought-based level.
2. Software will become increasingly more important.
3. In order to create an individual’s intellectual capabilities, one has to nurture and cultivate while educating, which may take decades of effort.
4. To reach the upper levels of science and technology, one needs creativity, imagination, and innovation, which at present is not being nurtured.
5. Wealth will be generated from technological innovations.
6. The labor market is undergoing a historic change, and individuals in the future should exploit this.
7. Everything is possible for the individual who doesn’t have to do it.
8. It’s okay for a scheme not to work, i.e., it’s okay to fail.
9. Chemical engineers in the future will be judged and rewarded by their ability to predict evolving situations and formulate concrete strategies.
10. An important part of success will be to anticipate future situations, evaluate possible outcomes, and set appropriate goals.
11. Many of the old blue-collar factory jobs will disappear.
12. The chemical engineer has to be educated to meet the challenges of this century, and this will require activities that involve creativity, artistic ability, innovation, leadership, and analysis.
13. The chemical engineer who develops good habits of problem solving early in his/her career will save considerable time and avoid many frustrations later in life.

The Authors’ Approach

Here is what the authors have stressed to their students in terms of developing problem-solving skills and other creative thinking.

1. Carefully define the problem at hand.
2. Obtain all pertinent data and information.
3. Initially, generate an answer or solution.
4. Examine and evaluate as many alternatives as possible, employing “what if” scenarios [1].
5. Reflect on the above over time.
6. Consider returning to step 1 and repeat/expand the process.

The traditional methodology of solving problems has been described for decades with the following broad stepwise manner:

1. Understand the problem.
2. Devise a plan.
3. Carry out the plan.
4. Look back and (possibly) revise.

Many now believe creative thinking should be part of every student’s education. Here are some ways that have proven to nudge the creative process along:

1. Break out of the one-and-only answer rut.
2. Use creative thinking techniques and games.
3. Foster creativity with assignments and projects.
4. Be careful not to punish creativity.

The above-suggested activities will ultimately help develop a critical thinker that:

1. Raises important questions and problems, formulating them clearly and precisely.
2. Gathers and assesses relevant information, using abstract ideas to interpret it effectively.
3. Comes to well-reasoned conclusions and solutions, testing them against relevant criteria and standards.
4. Thinks open mindedly within alternative systems of thought, recognizing and assessing, as need be, their assumptions, implications, and practical consequences.
5. Communicates effectively with others in figuring out solutions to complex problems.

The analysis aspect of a problem remains. It essentially has not changed.

The analysis of a new problem in chemical process engineering can still be divided into four steps.

1. Consideration of the process in question.
2. Mathematical description of the process, if applicable.
3. Solution of any mathematical relationships to provide a solution.
4. Verification of the solution.

Earlier Experiences[1,4,5]

The educational literature provides frequent references to individuals, particularly engineers, and other technical fields, that have different learning styles, and in order to successfully draw on these different styles, a variety of approaches can be employed. One such approach for educators involves the use of open-ended problems.

The term open-ended has come to mean different things to different people in industry and academia. It basically describes an approach to the solution of a problem and/or situation for which there is usually not a unique solution. Three literature sources[6–8] provide sample problems that can be used when this educational tool is employed.

One of the authors of this book has applied this somewhat unique approach and has included numerous open-ended problems in several chemical engineering course offerings at Manhattan College. Student comments for a general engineering graduate course “Accident and Emergency Management” were tabulated. Student responses to the question “What aspects of this course were most beneficial to you?” are listed below:

1. “The open-ended questions gave engineers a creative license. We don’t come across many of these opportunities.”
2. “Open-ended questions allowed for candid discussions and viewpoints that the class may not have been otherwise exposed to.”
3. “The open-ended questions gave us an opportunity to apply what we were learning in class with subjects we have already learned and gave us a better understanding of the course.”
4. “Much of the knowledge that was learned in this course is applicable to everyday situations and our professional lives.”
5. “Open-ended problems made me sit down and research the problem to come up with ways to solve them.”
6. “I thought the open-ended problems were inventive and made me think about problems in a better way.”
7. “I felt that the open-ended problems were challenging. I, like most engineers, am more comfortable with quantitative problems than qualitative.”

In effect, the approach requires asking questions, to not always accept things at face value, and to select a methodology that provides the most effective and efficient solution. Those who conquer this topic have probably taken first step toward someday residing in an executive suite.

Developing Students’ Power of Critical Thinking[1,9]

It has often been noted that chemical engineers are living in the middle of an information revolution. Since the term of the century, that revolution has had an effect on teaching and learning. Educators are hard-pressed to keep up with the advances in their fields. Often their attempts to keep the students informed are limited by the difficulty of making new material available.

The basic need of both educator and student is to have useful information readily accessible. Then comes the problem of how to use this information properly. The objectives of both teaching and studying such information are: to assure comprehension of the material and to integrate it with the basic tenets of the field it represents; and, to use the comprehension of the material as a vehicle for critical thinking and effective argument.

Information is valueless unless it is put to use; otherwise, it becomes mere data. For information to be used most effectively, it should be taken as an instrument for understanding. The process of this utilization works on a number of incremental levels. Information can be absorbed, comprehended; discussed, argued in reasoned fashion, written about, and integrated with similar and contrasting information.

The development of critical and analytical thinking is key to the understanding and use of information. It is what allows the student to discuss, and argue points of opinion and points of fact. It is the basis for the student’s formation and development of independent ideas. Once formed, these ideas can be written about and integrated with both similar and contrasting information.

Creativity and Brainstorming

Chemical engineers bring mathematics and other sciences to bear on practical problems and applications, molding materials and harnessing technology for human benefit. Creativity is often a key component in this synthesis; it is the spark, motivating efforts to devise solutions to novel problems, design new products, and improve existing practices. In the competitive marketplace, it is a crucial asset in the bid to win the race to build better machines, decrease product delivery times, and anticipate the needs of future generations.[1,9]

One of the keys to the success of a chemical engineer or a scientist is to generate fresh approaches, process and products, i.e., they need to be creative. Gibney[9] has detailed how some schools and institutions are attempting to use certain methods that essentially share the same objective: open students’ minds to their own creative potential.

Gibney [9] provides information on “The Art of Problem Definition” developed by the Rensselaer Polytechnic Institute. To stress critical thinking, they teach a seven-step methodology for creative problem development. These steps are provided below: [9]

1. Define the problem.
2. State objective.
3. Establish functions.
4. Develop specifications.
5. Generate multiple alternatives.
6. Evaluate alternatives.
7. Build.

In addition, Gibney [9] identified the phases of the creative process set forth by psychologists. They essentially break the process down into five basic stages:

1. Immersion.
2. Incubation.
3. Insight.
4. Evaluation.
5. Elaboration.

Psychologists have ultimately described the creative process as recursive. At any one of these stages, a person can double back, revise ideas, or gain new knowledge that reshapes his or her understanding. For this reason, being creative requires patience, discipline, and hard work.

Delia Femina [10] outlined five “secrets” regarding the creative process:

1. Creativity is ageless.
2. You don’t have to be Einstein.
3. Creativity is not an eight hour job.
4. Failure is the mother of all creativity.
5. Dead men don’t create.

Panitz [11] has demonstrated how brainstorming strategies can help engineering students generate an outpouring of ideas. Brainstorming guidelines include:

1. Carefully defining the problem upfront.
2. Allow individuals to consider the problem before the group tackles it.
3. Create a comfortable environment.
4. Record all suggestions.
5. Appoint a group member to serve as a facilitator.
6. Keep brainstorming groups small.

A checklist for change was also provided, as detailed below:

1. Adapt
2. Modify.
3. Magnify.
4. Minify.
5. Put to other uses.
6. Substitute.
7. Rearrange.
8. Reverse.
9. Combine.

Inquiring Minds

In an exceptional well-written article by Lih [12] entitled “Inquiring Minds”, he commented on inquiring minds by saying “You can’t transfer knowledge without them.” His thoughts (which have been edited) on the inquiring or questioning process follow:

1. Inquiry is an attitude—a very important one when it comes to learning. It has a great deal to do with curiosity, dissatisfaction with the status quo, a desire to dig deeper, and having doubts about what one has been told.
2. Questioning often leads to believing—there is a saying that has been attributed to Confucius: “Tell me, I forget. Show me, I remember. Involve me, I understand.” It might also be fair to add: “Answer me, I believe.”
3. Effective inquiry requires determination to get to the bottom of things.
4. Effective inquire requires wisdom and judgment. This is especially true for a long-range intellectual pursuit that is at the forefront of knowledge.
5. Inquiry is the key to successful life-long learning. If one masters the art of questioning, independent learning is a breeze.
6. Questioning is good for the questionee as well. It can help clarify issues, uncover holes in an argument, correct factual and/or conceptual errors, and eventually lead to a more thoughtful outcome.
7. Teachers and leaders should model the importance of inquiry. The teacher leader must allow and encourage questions and demonstrate a personal thirst for knowledge.

Ultimately, the degree to which one succeeds (or fails) is often based in part on one’s state of mind or attitude. As President Lincoln once said: “Most people are about as happy as they make their minds to be.” William Jones once wrote: “The greatest discovery of my generation is that human beings can alter their lives by altering their attitude of mind.” So, no matter what one does, it is in the hands of that individual to make it a meaningful, pleasurable, and positive experience. This experience will almost definitely bring success.

Final Thoughts

One of the authors [13], prior of retiring, sought consulting jobs when he was told, “We just can’t figure out how to solve the problem.” For example, should a heat exchanger be heated with atmospheric or superheated steam? Obviously, it would appear to be better to employ atmospheric steam. But, that may not always be the “best” approach. Tackling and solving these class of problems will only come with experience. And then there is the option of ordering a chemical reactor in assembled form rather than in sections. One would normally select the assembled option, but once again, it might require eliminating walls and/or enlarging small openings. The choice is not clear and analysis is warranted.

The traditional chemical engineering curriculum cannot be totally abandoned. It must still include material to describe the behavior of processes and the ability to design equipment. If the process or problem is complex, he/she must also be able to use approximate methods. Unfortunately, many systems with which the chemical engineer will deal with in the future do not fit simple theory.

The development of the future chemical engineer can be compared to the development of a good basketball player [14]. A basketball player must learn how to dribble and shoot. He must also develop an ability to play hard-nose defense, and he must learn the meaning of teamwork. He must also learn to take orders from his coaches. All these can be worked on and perfected individually, but the complete basketball player does not manifest until all the individual parts are put together to function as a smooth, complete unit. [14] Just as the basketball player needs to work on the individual parts of his skill, the chemical engineer still needs to study the separate operations involved in his field. Chemical engineers must study and understand the basic laws of chemistry and physics. They must know the various types of equipment and the economics involved in the over-all plant process. They must understand the unit operations of fluid flow, heat transfer and mass transfer operations, and other peripheral topics.

What about the chemical engineer sustaining his/her career? MacLean [15] recently provided some career advice that is generally universally recognized. Here is a summary of his baker’s dozen (the authors have added three to his 10) pointers:

1. Pick a rigorous college.
2. Pick a future viable career path, not the current popular one.
3. EQ (emotional quotient) is as important as IQ.
4. Be really nice to everyone.
5. Choose your battles very carefully.
6. Be patient and hold your tongue.
7. Do not expect to be rewarded for hard work.
8. Understand your “customer” needs.
9. Do your fair share.
10. Maintain contact.
11. Provide praise (if appropriate) to others.
12. Luck rules; increase your odds.
13. Most importantly, develop an ability to communicate orally and in writing.

Some of the suggestions might be a good fit for some chemical engineers, and some may not apply over their entire career. Think it through.

References

1. Adapted from, L. Theodore, Chemical Engineering: The Essential Reference, McGraw-Hill, New York City, NY, 2014.

2. L. Theodore, On Creative Thinking II, Discovery, East Williston, NY, August 13, 2004.

3. Personal Notes, L. Theodore, East Williston, NY, 1995.

4. J.P. Abulencia and L. Theodore, Fluid Flow for the Practicing Chemical Engineer, John Wiley & Sons, Hoboken, NJ, 2009.

5. A. Flynn and L. Theodore, An Air Pollution Control Equipment Design Course for Chemical and Environmental Engineering Students Using and Open-Ended Problem Approach, ASEE Meeting, Rowan University, NJ, 2001.

6. A. Flynn, J. Reynolds, and L. Theodore, Courses for Chemical and Environmental Engineering Students Using an Open-Ended Problem Approach, AWMA Meeting, San Diego, CA, 2003.

7. L. Theodore, class notes, 1999-2003.

8. Manhattan College Center for Teaching, Developing Students’ Power of Critical Thinking, Bronx, NY, January 1989.

9. K. Gibney, Awakening Creativity, ASEE Promo, Washington, DC March 1988.

10. J. Delia Femina, Jerry’s Rules, Modern Maturity, location unknown March-April 2000.

11. B. Panitz, Brain Storms, ASEE Promo, Washington, DC March 1998.

12. M. Lih, Inquiring Minds, ASEE Promo, Washington, DC December 1998.

13. Personal notes, L. Theodore, East Williston, NY, 2010.

14. L. Theodore, Basketball Coaching 101, in preparation, East Williston, NY, 2014.

15. R. Maclean, Sustaining Your Career, EM, Pittsburgh, PA, July 2012.

Part II

CHEMICAL ENGINEERING TOPICS

Part II is concerned with subject matter of interest and concern to the practicing chemical engineer. Topics reviewed include (with accompanying Chapter Number);

1. Material Science and Engineering

2. Applied Mathematics

3. Stoichiometry

4. Thermodynamics

5. Fluid Flow

6. Heat Transfer

7. Mass Transfer Operations

8. Chemical Reactors

9. Process Control

10. Economics and Finance

11. Plant Design

12. Transport Phenomena

13. Project Management

14. Environmental Management

15. Environmental Health and Hazard Risk Assessment

16. Energy Management

17. Water Management

18. Biochemical Engineering

19. Probability and Statistics

20. Legal Considerations

21. Nanotechnology

22. Ethics

Each chapter contains three sections. The first section provides a broad (but brief) overview of the subject matter of concern. Several sections then address technical subject matter related to the topic of concern. This in turn is followed with a section that contains three solved open-ended problems. The chapter concludes with approximately 35-40 open-ended problems—some solutions of which are available to those who adopt the book for classroom or training purposes. A reference page compliments the presentation.

Additional details for each chapter topic is available in Theodore’s “Chemical Engineering: The Essential Reference”; an extensive and comprehensive treatment of most topics is provided in Perry’s “Chemical Engineers’ Handbook”, 8th edition (both of McGraw-Hill).

Chapter 1

Materials Science and Engineering

This chapter is concerned with Materials Science and Engineering (MSE). As with all the chapters in Part II, there are sereval sections: overview several specific technical topics illustrative open-ended problems, and-open ended problems. The purpose of the first section is to introduce the reader to the subject of MSE. As one might suppose, a comprehensive treatment is not provided, although numerous references are included. The second section contains three open-ended problems; the authors’ solution (there may be other solutions) is also provided. The third (and final) section contains 35 problems; no solutions are provided here.

1.1 Overview

This overview section is concerned—as can be noted from its title—with Materials Science and Engineering (MSE). As one might suppose, it was not possible to address all topics directly or indirectly related to MSE. Because of space limitations, only the subject of crystallography of perfect crystals (CPC) is primarily addressed. However, additional details may be obtained from the references at the end of the chapter.

Note: Those readers already familiar with the details associated with MSE may choose to bypass this Overview.

The title, Materials Science and Engineering, implies a double focus—one geared toward a fundamental study of the materials and their properties, and the other towards the production and use of materials for the benefit of society. This chapter is primarily concerned with the former focus.

The terms Materials denotes a vast areas of compiled knowledge. There is very little in all of engineering and science that does not involve materials. Obviously, the first task in preparing an abbreviated chapter in the study of materials must be the application of limits on the subject matter to be covered—a focus on specific types of materials. It is generally understood that covers only the solid state of matter; liquids are considered only in certain cases where solid-liquid equilibrium is involved. There are many types of solids, however, and further focusing is required.

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