Statistics for Process Control Engineers - Myke King - E-Book

Statistics for Process Control Engineers E-Book

Myke King

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The first statistics guide focussing on practical application to process control design and maintenance Statistics for Process Control Engineers is the only guide to statistics written by and for process control professionals. It takes a wholly practical approach to the subject. Statistics are applied throughout the life of a process control scheme - from assessing its economic benefit, designing inferential properties, identifying dynamic models, monitoring performance and diagnosing faults. This book addresses all of these areas and more. The book begins with an overview of various statistical applications in the field of process control, followed by discussions of data characteristics, probability functions, data presentation, sample size, significance testing and commonly used mathematical functions. It then shows how to select and fit a distribution to data, before moving on to the application of regression analysis and data reconciliation. The book is extensively illustrated throughout with line drawings, tables and equations, and features numerous worked examples. In addition, two appendices include the data used in the examples and an exhaustive catalogue of statistical distributions. The data and a simple-to-use software tool are available for download. The reader can thus reproduce all of the examples and then extend the same statistical techniques to real problems. * Takes a back-to-basics approach with a focus on techniques that have immediate, practical, problem-solving applications for practicing engineers, as well as engineering students * Shows how to avoid the many common errors made by the industry in applying statistics to process control * Describes not only the well-known statistical distributions but also demonstrates the advantages of applying the large number that are less well-known * Inspires engineers to identify new applications of statistical techniques to the design and support of control schemes * Provides a deeper understanding of services and products which control engineers are often tasked with assessing This book is a valuable professional resource for engineers working in the global process industry and engineering companies, as well as students of engineering. It will be of great interest to those in the oil and gas, chemical, pulp and paper, water purification, pharmaceuticals and power generation industries, as well as for design engineers, instrument engineers and process technical support.

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Table of Contents

Cover

Title Page

Preface

About the Author

Supplementary Material

Part 1: The Basics

1 Introduction

2 Application to Process Control

2.1 Benefit Estimation

2.2 Inferential Properties

2.3 Controller Performance Monitoring

2.4 Event Analysis

2.5 Time Series Analysis

3 Process Examples

3.1 Debutaniser

3.2 De‐ethaniser

3.3 LPG Splitter

3.4 Propane Cargoes

3.5 Diesel Quality

3.6 Fuel Gas Heating Value

3.7 Stock Level

3.8 Batch Blending

4 Characteristics of Data

4.1 Data Types

4.2 Memory

4.3 Use of Historical Data

4.4 Central Value

4.5 Dispersion

4.6 Mode

4.7 Standard Deviation

4.8 Skewness and Kurtosis

4.9 Correlation

4.10 Data Conditioning

5 Probability Density Function

5.1 Uniform Distribution

5.2 Triangular Distribution

5.3 Normal Distribution

5.4 Bivariate Normal Distribution

5.5 Central Limit Theorem

5.6 Generating a Normal Distribution

5.7 Quantile Function

5.8 Location and Scale

5.9 Mixture Distribution

5.10 Combined Distribution

5.11 Compound Distribution

5.12 Generalised Distribution

5.13 Inverse Distribution

5.14 Transformed Distribution

5.15 Truncated Distribution

5.16 Rectified Distribution

5.17 Noncentral Distribution

5.18 Odds

5.19 Entropy

6 Presenting the Data

6.1 Box and Whisker Diagram

6.2 Histogram

6.3 Kernel Density Estimation

6.4 Circular Plots

6.5 Parallel Coordinates

6.6 Pie Chart

6.7 Quantile Plot

7 Sample Size

7.1 Mean

7.2 Standard Deviation

7.3 Skewness and Kurtosis

7.4 Dichotomous Data

7.5 Bootstrapping

8 Significance Testing

8.1 Null Hypothesis

8.2 Confidence Interval

8.3 Six‐Sigma

8.4 Outliers

8.5 Repeatability

8.6 Reproducibility

8.7 Accuracy

8.8 Instrumentation Error

9 Fitting a Distribution

9.1 Accuracy of Mean and Standard Deviation

9.2 Fitting a CDF

9.3 Fitting a QF

9.4 Fitting a PDF

9.5 Fitting to a Histogram

9.6 Choice of Penalty Function

10 Distribution of Dependent Variables

10.1 Addition and Subtraction

10.2 Division and Multiplication

10.3 Reciprocal

10.4 Logarithmic and Exponential Functions

10.5 Root Mean Square

10.6 Trigonometric Functions

11 Commonly Used Functions

11.1 Euler’s Number

11.2 Euler–Mascheroni Constant

11.3 Logit Function

11.4 Logistic Function

11.5 Gamma Function

11.6 Beta Function

11.7 Pochhammer Symbol

11.8 Bessel Function

11.9 Marcum Q‐Function

11.10 Riemann Zeta Function

11.11 Harmonic Number

11.12 Stirling Approximation

11.13 Derivatives

12 Selected Distributions

12.1 Lognormal

12.2 Burr

12.3 Beta

12.4 Hosking

12.5 Student t

12.6 Fisher

12.7 Exponential

12.8 Weibull

12.9 Chi‐Squared

12.10 Gamma

12.11 Binomial

12.12 Poisson

13 Extreme Value Analysis

14 Hazard Function

15 CUSUM

16 Regression Analysis

16.1 F Test

16.2 Adjusted R

16.3 Akaike Information Criterion

16.4 Artificial Neural Networks

16.5 Performance Index

17 Autocorrelation

18 Data Reconciliation

19 Fourier Transform

Part 2: Catalogue of Distributions

20 Normal Distribution

20.1 Skew‐Normal

20.2 Gibrat

20.3 Power Lognormal

20.4 Logit‐Normal

20.5 Folded Normal

20.6 Lévy

20.7 Inverse Gaussian

20.8 Generalised Inverse Gaussian

20.9 Normal Inverse Gaussian

20.10 Reciprocal Inverse Gaussian

20.11 Q‐Gaussian

20.12 Generalised Normal

20.13 Exponentially Modified Gaussian

20.14 Moyal

21 Burr Distribution

21.1 Type I

21.2 Type II

21.3 Type III

21.4 Type IV

21.5 Type V

21.6 Type VI

21.7 Type VII

21.8 Type VIII

21.9 Type IX

21.10 Type X

21.11 Type XI

21.12 Type XII

21.13 Inverse

22 Logistic Distribution

22.1 Logistic

22.2 Half‐Logistic

22.3 Skew‐Logistic

22.4 Log‐Logistic

22.5 Paralogistic

22.6 Inverse Paralogistic

22.7 Generalised Logistic

22.8 Generalised Log‐Logistic

22.9 Exponentiated Kumaraswamy–Dagum

Chapter 23: Pareto Distribution

23.1 Pareto Type I

23.2 Bounded Pareto Type I

23.3 Pareto Type II

23.4 Lomax

23.5 Inverse Pareto

23.6 Pareto Type III

23.7 Pareto Type IV

23.8 Generalised Pareto

23.9 Pareto Principle

24 Stoppa Distribution

24.1 Type I

24.2 Type II

24.3 Type III

24.4 Type IV

24.5 Type V

25 Beta Distribution

25.1 Arcsine

25.2 Wigner Semicircle

25.3 Balding–Nichols

25.4 Generalised Beta

25.5 Beta Type II

25.6 Generalised Beta Prime

25.7 Beta Type IV

25.8 PERT

25.9 Beta Rectangular

25.10 Kumaraswamy

25.11 Noncentral Beta

26 Johnson Distribution

26.1 SN

26.2 SU

26.3 SL

26.4 SB

26.5 Summary

27 Pearson Distribution

27.1 Type I

27.2 Type II

27.3 Type III

27.4 Type IV

27.5 Type V

27.6 Type VI

27.7 Type VII

27.8 Type VIII

27.9 Type IX

27.10 Type X

27.11 Type XI

27.12 Type XII

28 Exponential Distribution

28.1 Generalised Exponential

28.2 Gompertz–Verhulst

28.3 Hyperexponential

28.4 Hypoexponential

28.5 Double Exponential

28.6 Inverse Exponential

28.7 Maxwell–Jüttner

28.8 Stretched Exponential

28.9 Exponential Logarithmic

28.10 Logistic Exponential

28.11 Q‐Exponential

28.12 Benktander

29 Weibull Distribution

29.1 Nukiyama–Tanasawa

29.2 Q‐Weibull

30 Chi Distribution

30.1 Half‐Normal

30.2 Rayleigh

30.3 Inverse Rayleigh

30.4 Maxwell

30.5 Inverse Chi

30.6 Inverse Chi‐Squared

30.7 Noncentral Chi‐Squared

31 Gamma Distribution

31.1 Inverse Gamma

31.2 Log‐Gamma

31.3 Generalised Gamma

31.4 Q‐Gamma

32 Symmetrical Distributions

32.1 Anglit

32.2 Bates

32.3 Irwin–Hall

32.4 Hyperbolic Secant

32.5 Arctangent

32.6 Kappa

32.7 Laplace

32.8 Raised Cosine

32.9 Cardioid

32.10 Slash

32.11 Tukey Lambda

32.12 Von Mises

33 Asymmetrical Distributions

33.1 Benini

33.2 Birnbaum–Saunders

33.3 Bradford

33.4 Champernowne

33.5 Davis

33.6 Fréchet

33.7 Gompertz

33.8 Shifted Gompertz

33.9 Gompertz–Makeham

33.10 Gamma‐Gompertz

33.11 Hyperbolic

33.12 Asymmetric Laplace

33.13 Log‐Laplace

33.14 Lindley

33.15 Lindley‐Geometric

33.16 Generalised Lindley

33.17 Mielke

33.18 Muth

33.19 Nakagami

33.20 Power

33.21 Two‐Sided Power

33.22 Exponential Power

33.23 Rician

33.24 Topp–Leone

33.25 Generalised Tukey Lambda

33.26 Wakeby

34 Amoroso Distribution

35 Binomial Distribution

35.1 Negative‐Binomial

35.2 Pόlya

35.3 Geometric

35.4 Beta‐Geometric

35.5 Yule–Simon

35.6 Beta‐Binomial

35.7 Beta‐Negative Binomial

35.8 Beta‐Pascal

35.9 Gamma‐Poisson

35.10 Conway–Maxwell–Poisson

35.11 Skellam

36 Other Discrete Distributions

36.1 Benford

36.2 Borel–Tanner

36.3 Consul

36.4 Delaporte

36.5 Flory–Schulz

36.6 Hypergeometric

36.7 Negative Hypergeometric

36.8 Logarithmic

36.9 Discrete Weibull

36.10 Zeta

36.11 Zipf

36.12 Parabolic Fractal

Appendix 1: Data Used in Examples

Appendix 2: Summary of Distributions

References

Index

End User License Agreement

List of Tables

Chapter 04

Table 4.1

Averaging C

4

content of propane cargoes

Table 4.2

Averaging SG of heavy fuel oil cargoes

Table 4.3

Analyses of propane cargoes

Table 4.4

Applying trapezium rule to determine moments

Chapter 09

Table 9.1

Fitting the CDF and quantile function of a normal distribution

Table 9.2

Fitting the PDF of a normal distribution

Table 9.3

Fitting a normal distribution to a histogram

Table 9.4

Kolmogorov–Smirnov test

Chapter 11

Table 11.1

Common derivatives

Chapter 12

Table 12.1

Bounds for the Hosking distribution

Table 12.2

Calculation of

μ, σ, γ

and

κ

for Hosking distribution

Table 12.3

Measured and predicted values for

y

Chapter 16

Table 16.1

LPG splitter data for development of inferential

Table 16.2

Impact of choice of penalty function

Table 16.3

Use of weighted least squares regression

Table 16.4

LPG splitter data collected over wide operating range

Chapter 17

Table 17.1

Initial estimate of coefficients

Table 17.2

Intermediate estimate of coefficients

Table 17.3

Final estimate of coefficients

Chapter 26

Table 26.1

Results of fitting Johnson distributions to C

4

data

Chapter 34

Table 34.1 Distributions represented by the Amoroso distribution

Appendix 01

Table A1.1

Results for vol% C

4

in propane rundown

Table A1.2

Results for vol% C

2

in 100 propane cargoes

Table A1.3

Gasoil 95% distillation points (°C)

Table A1.4

Results for fuel gas NHV (MJ/sm

3

)

Table A1.5

Fuel gas analyses (mol %)

Table A1.6

Stock levels

Table A1.7

Results for batch blending (including trim blends)

Table A1.8

Two‐tailed confidence intervals

Table A1.9

One‐tailed confidence intervals

Appendix 02

Table A2.1

Summary of continuous distributions

Table A2.2

Summary of discrete distributions

List of Illustrations

Chapter 02

Figure 2.1

Same percentage rule

Figure 2.2

Properly fitting a distribution

Chapter 03

Figure 3.1

Variation in LPG splitter reflux

Figure 3.2

Distribution of reflux flow

Figure 3.3

Distribution of high reflux events

Figure 3.4

Distribution of intervals between reflux events

Figure 3.5

Laboratory results for C

4

content of propane

Figure 3.6

Skewed distribution of C

4

results

Figure 3.7

Changes in C

4

content

Figure 3.8

Comparison between analyser and inferential

Figure 3.9

Scatter plot of inferential against analyser

Figure 3.10

Actual distribution very different from normal

Figure 3.11

Laboratory results for gasoil 95% distillation point

Figure 3.12

Variation in site’s fuel gas heating value

Figure 3.13

Disturbances to heating value

Figure 3.14

Small tails compared to normal distribution

Figure 3.15

Variation in stock level

Figure 3.16

Skewed distribution of stock levels

Figure 3.17

Variation in blend property

Chapter 04

Figure 4.1

Centroid of propane composition

Figure 4.2

Multimodal distributions

Figure 4.3

Skewness

Figure 4.4

Increasing kurtosis

Figure 4.5

Decreasing variance

Figure 4.6

Comparison between kurtosis and variance

Figure 4.7

Normal distribution

Figure 4.8

Convergence of calculations of moments

Chapter 05

Figure 5.1

Expected frequency of total score from two dice

Figure 5.2

Expected distribution

Figure 5.3

Cumulative probability

Figure 5.4

Examples of PDF

Figure 5.5

Examples of CDF

Figure 5.6

Development of the triangular distribution

Figure 5.7

PDF of continuous triangular distribution

Figure 5.8

CDF of continuous triangular distribution

Figure 5.9

Effect of varying

μ

and

σ

on PDF of normal distribution

Figure 5.10

Error function

Figure 5.11

Effect of varying

μ

and

σ

on CDF of normal distribution

Figure 5.12

Plot of bivariate PDF

Figure 5.13

Effect of CH

4

content on distribution of H

2

content

Figure 5.14

Effect of H

2

content on distribution of CH

4

content

Figure 5.15

Plot of bivariate CDF

Figure 5.16

Frequency distribution of the score from a single dice

Figure 5.17

Frequency distribution of the total score from two dice

Figure 5.18

Frequency distribution of the total score from five dice

Figure 5.19

Frequency distribution of the score from a single modified dice

Figure 5.20

Frequency distribution of the total score from seven modified dice

Figure 5.21

Probability distribution of the product of three dice throws

Figure 5.22

Probability distribution of the logarithm of the product of three dice throws

Figure 5.23

Uniform probability distribution

Figure 5.24

Quantile function for normal distribution N(0,1)

Figure 5.25

Probability density of MFI results

Figure 5.26

Truncated PDF

Figure 5.27

Truncated CDF

Figure 5.28

Rectified PDF

Figure 5.29

Variation of predictability of coin toss

Chapter 06

Figure 6.1

Box and whisker diagram

Figure 6.2

Bins too wide

Figure 6.3

Bins too narrow

Figure 6.4

Using

Figure 6.5

Use of Surge’s formula to select number of bins

Figure 6.6

Poor choice of starting value for first bin

Figure 6.7

Use of Scott’s normal reference rule to select bin width

Figure 6.8

Optimised bin width

Figure 6.9

Conversion to probability density

Figure 6.10

Cumulative probability plot

Figure 6.11

Construction of kernel density plot

Figure 6.12

Effect of smoothing factor

Figure 6.13

Result of applying Silverman’s rule of thumb

Figure 6.14

Result of selecting Epanechnikov kernel

Figure 6.15

P–P plot demonstrating accuracy of fit

Figure 6.16

Distribution of C4 content of propane rundown

Figure 6.17

Comparison between kernel density and fitted normal distribution

Figure 6.18

Frequency–frequency plot demonstrating very poor fit

Figure 6.19

Use of radar plot to show days of off‐grade production

Figure 6.20

Use of radar plot to display MPC behaviour

Figure 6.21

Circular plot based on polar coordinates

Figure 6.22

Parallel coordinates

Figure 6.23

Use of pie chart to highlight quality control problem

Figure 6.24

Cumulative distribution of gasoil 95% with normal distribution fitted

Figure 6.25

P–P plot for gasoil 95%

Figure 6.26

Q–Q plot for gasoil 95%

Figure 6.27

Ranked versus paired points comparing inferential to on‐stream analyser

Figure 6.28

Procedure for adding missing quantiles

Figure 6.29

Q–Q plot including missing quantiles

Chapter 07

Figure 7.1

Impact of sample size on accuracy of skewness and kurtosis

Figure 7.2

Sample size necessary for estimating probability over a year

Figure 7.3

Application of Wald method for all future blends

Figure 7.4

Application of Agresti–Coull method for all future blends

Figure 7.5

Use of bootstrapping to determine confidence in estimating

μ

Chapter 08

Figure 8.1

Probability density of the number of heads from 100 tosses

Figure 8.2

Cumulative probability distribution of the number of heads

Figure 8.3

Confidence that coin is unbiased if it lands 60 (or 40) heads from 100 tosses

Figure 8.4

PDF showing probability of being within one standard deviation of the mean

Figure 8.5

CDF showing probability of being within one standard deviation of the mean

Figure 8.6

Confidence interval as a function of the number of standard deviations

Figure 8.7

Significance level versus confidence interval

Figure 8.8

Horwitz’s curve

Chapter 09

Figure 9.1

Error in estimating

σ

arising from error in estimating

μ

Figure 9.2

Empirical distribution function

Figure 9.3

Comparison between fitted and calculated distributions

Figure 9.4

P–P plots of fitted and calculated distributions

Figure 9.5

Impact of fixing

F(x

1

), F(x

n

) or F(x

n/

2

)

Figure 9.6

Including

F(x

1

)

among the parameters adjusted during fitting

Figure 9.7

P–P plot from fitting the PDF

Figure 9.8

Data presented as a histogram

Figure 9.9

Comparing derived probability distribution to histogram

Figure 9.10

P–P plot from fitting to the histogram

Figure 9.11

Anderson–Darling weighting factor

Figure 9.12

Kolmogorov–Smirnov penalty function

Figure 9.13

Impact of choice of penalty function

Chapter 10

Figure 10.1

Distribution of the ratio of two values selected from U(0,1)

Figure 10.2

Normal distribution fitted to reflux and distillate flows on LPG splitter

Figure 10.3

Variation of LPG splitter reflux ratio over time

Figure 10.4

Fitting normal and lognormal distributions to LPG splitter reflux ratio

Figure 10.5

Normal distribution fitted to reflux and distillate flows on debutaniser

Figure 10.6

Fitting the normal distribution to debutaniser reflux ratio

Figure 10.7

Distribution of the product of two values selected from U(0,1)

Figure 10.8

Normal distribution fitted to heat exchanger flow

Figure 10.9

Normal distribution fitted to heat exchanger temperature difference

Figure 10.10

Fitting normal and lognormal distributions to exchanger duty

Figure 10.11

Distribution of reciprocal of propane flow from LPG splitter

Figure 10.12

Normal distributions fitted to heat exchanger temperatures

Figure 10.13

Fitting normal and lognormal distributions to LMTD

Figure 10.14

Normal distribution fitted to LPG splitter pressure

Figure 10.15

Normal distribution fitted to LPG splitter tray temperature target

Figure 10.16

Close approximation to linearity between temperature and pressure

Figure 10.17

Impact of feed composition (

HK

f

) on distillate composition (

HK

d

)

Figure 10.18

Regressed relationship between distillate and feed compositions

Figure 10.19

Distribution of

HK

d

arising from normally distributed

HK

f

Figure 10.20

Normal distribution fitted to variation in viscosity blending number

Figure 10.21

Fitting normal and lognormal distributions to viscosities

Figure 10.22

Close approximation to linearity between VBN and viscosity

Figure 10.23

Normal distribution fitted to reactor temperature

Figure 10.24

Fitting normal and lognormal distributions to % converted

Figure 10.25

Fitting normal and lognormal distributions to % unconverted

Figure 10.26

Nonlinear relationship between conversion and reactor temperature

Figure 10.27

Distribution of root mean square of two values selected from N(0,1)

Figure 10.28

Fitting normal and lognormal distributions to root mean square flow

Chapter 11

Figure 11.1

Convergence to powers of Euler’s number

Figure 11.2

Euler–Mascheroni constant

Figure 11.3

Logit function

Figure 11.4

Logistic function

Figure 11.5

Gamma function

Figure 11.6

Log‐gamma function

Figure 11.7

Gamma function for negative values

Figure 11.8

Derivative of gamma function

Figure 11.9

Pochhammer ascending factorial

Figure 11.10

Pochhammer descending factorial

Figure 11.11

Modified Bessel function of the first kind

Figure 11.12

Convergence of Bessel function

Figure 11.13

Number of terms required to achieve 0.01% accuracy

Figure 11.14

Bessel function (of the first kind) restricted to integer orders

Figure 11.15

Modified Bessel function of the second kind

Figure 11.16

Bessel function (of the second kind) restricted to integer orders

Figure 11.17

Convergence of zeta function

Figure 11.18

Zeta function

Figure 11.19

Harmonic number

Figure 11.20

Accuracy of Stirling approximation

Chapter 12

Figure 12.1

Lognormal: Effect of

σ

on shape

Figure 12.2

Lognormal: Improved fit to the C

4

in propane data

Figure 12.3

Lognormal: P–P plot showing improved fit

Figure 12.4

Lognormal: PDF fitted to histogram of C

4

in propane data

Figure 12.5

Lognormal: Feasible combinations of

γ

and

κ

Figure 12.6

Burr‐XII: Fitted to the C

4

in propane data

Figure 12.7

Burr‐XII: Feasible combinations of

γ

and

κ

Figure 12.8

Burr‐XII: Fitted to the NHV disturbance data

Figure 12.9

Beta‐I: Effect of

δ

1

and δ

2

on shape

Figure 12.10

Beta‐I: Symmetric‐beta

1

 = δ

2

)

Figure 12.11

Beta‐I: Effect of

δ

1

and

δ

2

on skewness

Figure 12.12

Beta‐I: Effect of

δ

1

and

δ

2

on kurtosis

Figure 12.13

Beta‐I: Conditions for zero kurtosis

Figure 12.14

Beta‐I: Impact of choice of range

Figure 12.15

Hosking: Impact of improved control of C

4

content of propane

Figure 12.16

Hosking: Fitted to the NHV disturbance data

Figure 12.17

Hosking: Fitted to absolute changes in NHV

Figure 12.18

Hosking: Exponential distributions as special case

Figure 12.19

Hosking: Generalised Pareto distribution as special case

Figure 12.20

Hosking: Generalised extreme value distribution as special case

Figure 12.21

Hosking: Other special cases

Figure 12.22

Gumbel: Effect of

α

and

β

on shape

Figure 12.23

Hosking: Unnamed distribution as special case

Figure 12.24

Hosking: Summary of distributions represented

Figure 12.25

Student: Probability density compared to normal distribution

Figure 12.26

Student: Effect of

f

on cumulative distribution

Figure 12.27

Student: Detail of effect of

f

on cumulative distribution

Figure 12.28

Fisher: Effect of

f

1

on shape (

f

2

 = 1)

Figure 12.29

Fisher: Effect of

f

1

on shape (

f

2

 = 3)

Figure 12.30

Fisher: Effect of

f

1

on shape (

f

2

 = 100

)

Figure 12.31

Fisher: Feasible combinations of

γ

and

κ

Figure 12.32

Exponential: Application to WECO rules and stock level example

Figure 12.33

Exponential: Fitted to interval between high reflux flow events

Figure 12.34

Weibull‐I: Effect of

δ

on shape

Figure 12.35

Weibull‐II: Effect of

δ

and

β

on shape

Figure 12.36

Weibull‐II: Alternative method of fitting to changes in C

4

content of propane

Figure 12.37

Weibull: Feasible combinations of

γ

and

κ

Figure 12.38

Weibull‐II: Method of fitting to stock level data

Figure 12.39

Weibull‐II: Result of fitting to stock level data

Figure 12.40

Chi‐squared: Probability density for

f = 

1 and

f = 

2

Figure 12.41

Chi‐squared: Probability density for

f ≥ 

3

Figure 12.42

Chi‐squared: Cumulative probability

Figure 12.43

Chi‐squared: Assessing reliability of predicted values

Figure 12.44

Gamma: Effect of

k

and

β

on shape

Figure 12.45

Gamma: Feasible combinations of

γ

and

κ

Figure 12.46

Gamma: Cumulative distribution

Figure 12.47

Gamma: Probability distribution of time to produce a batch

Figure 12.48

Gamma: Probability distribution of required inventory

Figure 12.49

Binomial: Fitting a normal distribution to the number of sixes from 12 throws

Figure 12.50

Binomial: Minimum number of trials for normal distribution to be applicable

Figure 12.51

Binomial: Demonstration that normal distribution can be used for

n = 

36

Figure 12.52

Binomial: Likely failure rate for an inferential

Figure 12.53

Binomial: Reducing the average number of off‐grade results for diesel

Figure 12.54

Binomial: Estimating the reduction in the likely number of off‐grade results

Figure 12.55

Poisson: Effect of

λ

on probability distribution

Figure 12.56

Poisson: Effect of

λ

on cumulative probability distribution

Chapter 13

Figure 13.1

Frequency distribution of extreme reflux flow (24‐hour maxima)

Figure 13.2

Fit of GEV distribution to 24‐hour maxima

Figure 13.3

Frequency distribution of reflux flow (48‐hour maxima)

Figure 13.4

Fit of GEV and extreme value distributions to 48‐hour maxima

Figure 13.5

Frequency distribution of reflux exceedances (>66.5)

Figure 13.6

Fit of generalised Pareto distribution to exceedances (>66.5)

Figure 13.7

Frequency distribution of reflux exceedances (>75.8)

Figure 13.8

Fit of generalised Pareto distribution to exceedances (>75.8)

Figure 13.9

Frequency distribution of reflux flow (72‐hour minima)

Figure 13.10

Fit of GEV distribution to 72‐hour minima

Figure 13.11

Frequency distribution of reflux exceedances (<34.2)

Figure 13.12

Fit of generalised Pareto distribution to exceedances (<34.2)

Chapter 14

Figure 14.1

Hazard function derived from EL distribution

Figure 14.2

Cumulative hazard function derived from EL distribution

Figure 14.3

Distribution of intervals between high reflux flow events

Figure 14.4

Fit of EL distribution to intervals between high reflux flow events

Figure 14.5

Reduction in frequency of events assuming EL distribution

Figure 14.6

Hazard function derived from gamma distribution

Figure 14.7

Hazard function derived from Weibull distribution

Figure 14.8

Reduction in frequency of events assuming Weibull distribution

Figure 14.9

Fit of Weibull distribution to intervals between high reflux flow events

Figure 14.10

Bathtub curve for advanced control application

Figure 14.11

Hjorth hazard function: Effect of

δ

1

and

δ

2

Chapter 15

Figure 15.1

Error between inferential for C

3

in butane and the on‐stream analyser

Figure 15.2

Trend of cumulative sum of error

Figure 15.3

Fit of Weibull‐II distribution to interval between errors exceeding 0.5 vol%

Figure 15.4

Demonstrating that the process has memory

Figure 15.5

Comparison between speeds at which bias error is removed

Figure 15.6

Trend of cumulative sum of deviation of stock level from the mean

Chapter 16

Figure 16.1

Minimisation of the total sum of the squares in

y

direction

Figure 16.2

Linear regression analysis

Figure 16.3

Compensation of one independent variable for variation in others

Figure 16.4

Minimisation of the total sum of the squares in

x

direction

Figure 16.5

Minimisation of the total sum of the squares of the perpendicular distance

Figure 16.6

Minimisation of the total sum of the rectangles in

x

and

y

direction

Figure 16.7

Impact of choice of penalty function

Figure 16.8

Detection that a nonlinear correlation should be used

Figure 16.9

Single input inferentials

Figure 16.10

Two‐input inferential

Figure 16.11

Correlation between inputs

Figure 16.12

Probability that two‐input inferential is better than single input version

Figure 16.13

Structure of artificial neural network

Figure 16.14

Sigmoid curves

Figure 16.15

Artificial neural network outperforming linear regression

Figure 16.16

Validation of inferential based on artificial neural network

Figure 16.17

Advanced control vendor stock price

Figure 16.18

Predicting stock price

Figure 16.19

Inferential performance index

Chapter 17

Figure 17.1

Noisy measurement

Figure 17.2

Oscillation detected by autocorrelation

Figure 17.3

Comparison between on‐stream analyser and inferential

Figure 17.4

Effect of time delay on correlation

Figure 17.5

Autocorrelation of stock levels

Figure 17.6

Accuracy of predicted stock level

Chapter 18

Figure 18.1

Reconciliation of two measurements

Figure 18.2

Reconciliation of three measurements

Figure 18.3

Minimisation of data reconciliation penalty function

Chapter 19

Figure 19.1

Arctangent2 function

Figure 19.2

Apparently noisy measurement

Figure 19.3

Power (or frequency) spectrum

Figure 19.4

Period spectrum

Figure 19.5

Phase spectrum

Figure 19.6

Superimposition of dominant wave form on original measurement

Figure 19.7

Frequency spectrum derived with two additional data points

Figure 19.8

Addition of second noisy measurement

Figure 19.9

No apparent correlation between measurements

Figure 19.10

Correlation between frequency spectra

Chapter 20

Figure 20.1

Skew‐normal: Effect of

δ

on shape

Figure 20.2

Skew‐normal: Effect of

δ

on skewness and kurtosis

Figure 20.3

Skew‐normal: Impact

δ

has on fitting to C

4

in propane data

Figure 20.4

Skew‐normal: Feasible combinations of

γ

and

κ

Figure 20.5

Power lognormal: Effect of

p

on shape

Figure 20.6

Logit‐normal: Effect of

β

on shape

Figure 20.7

Logit‐normal: Effect of

α

on shape

Figure 20.8

Folded normal: Effect of

α

on shape

Figure 20.9

Levy: Effect of

β

on shape

Figure 20.10

Levy: Poor fit to absolute changes in NHV

Figure 20.11

Inverse Gaussian: Effect of

σ

on shape

Figure 20.12

Inverse Gaussian: Effect of

μ

and

σ

on skewness

Figure 20.13

Inverse Gaussian: Effect of

μ

and

σ

on kurtosis

Figure 20.14

Inverse Gaussian: Feasible combinations of

γ

and

κ

Figure 20.15

Inverse Gaussian: Fitted to the C

4

in propane data

Figure 20.16

Inverse Gaussian: P–P plot showing improved fit to C

4

data

Figure 20.17

Inverse Gaussian: Fit to histogram of C

4

in propane data

Figure 20.18

Generalised inverse Gaussian: Effect of

β

and

δ

on shape

Figure 20.19

Normal inverse Gaussian: Effect of

δ

on shape

Figure 20.20

Normal inverse Gaussian: Effect of

λ

on shape

Figure 20.21

Normal inverse Gaussian: Effect of

β

on shape

Figure 20.22

Reciprocal inverse Gaussian: Effect of

α

and

λ

on shape

Figure 20.23

Reciprocal inverse Gaussian: Fitted to the C

4

in propane data

Figure 20.24

Q‐Gaussian: Effect of

q

on shape

Figure 20.25

Q‐Gaussian: Effect of

q

on kurtosis, keeping

σ

fixed

Figure 20.26

Q‐Gaussian: Effect of

q

on kurtosis

Figure 20.27

Q‐Gaussian: Fitted to the NHV disturbance data

Figure 20.28

Q‐Gaussian: P–P plot showing improved fit to NHV data

Figure 20.29

Generalised error: Effect of

δ

on shape

Figure 20.30

Generalised error: Effect of

δ

on kurtosis

Figure 20.31

Generalised error: Fitted to the NHV disturbance data

Figure 20.32

Generalised error: Impact

δ

has on fitting to NHV data

Figure 20.33

Generalised error: Impact

δ

has on estimating

σ

Figure 20.34

Generalised normal (2): Effect of

β

on shape

Figure 20.35

Generalised normal (2): Effect of

δ

on shape

Figure 20.36

Generalised normal (2): Effect of

δ

on

γ

and

κ

Figure 20.37

Generalised normal (2): Feasible combinations of

γ

and

κ

Figure 20.38

Generalised normal (3): Effect of

δ

1

and

δ

2

on shape

Figure 20.39

Generalised normal (3): Feasible combinations of

γ

and

κ

Figure 20.40

Exponentially modified Gaussian: Effect of

λ

on shape

Figure 20.41

Exponentially modified Gaussian: Feasible combinations of

γ

and

κ

Figure 20.42

Moyal: Effect of

β

on shape

Chapter 21

Figure 21.1

Burr‐III: Effect of

δ

1

and

δ

2

on shape

Figure 21.2

Burr‐IV: Effect of

δ

1

and

δ

2

on shape

Figure 21.3

Burr‐V: Effect of

δ

1

and

δ

2

on shape

Figure 21.4

Burr‐VI: Effect of

δ

1

and

δ

2

on shape

Figure 21.5

Burr‐VII: Effect of

δ

on shape

Figure 21.6

Burr‐VIII: Effect of

δ

on shape

Figure 21.7

Burr‐IX: Effect of

δ

1

and

δ

2

on shape

Figure 21.8

Burr‐X: Effect of

δ

on shape

Figure 21.9

Burr‐XI: Effect of

δ

on shape

Figure 21.10

Dagum‐I: Effect of

δ

1

on shape

Figure 21.11

Dagum‐I: Effect of

δ

2

on shape

Figure 21.12

Dagum‐I: Feasible combinations of

γ

and

κ

Chapter 22

Figure 22.1

Logistic: Effect of

δ

on shape

Figure 22.2

Logistic: Approximation to normal distribution

Figure 22.3

Half‐logistic: Effect of

λ

on shape

Figure 22.4

Skew‐logistic (1): Effect of

δ

on shape

Figure 22.5

Skew‐logistic (2): Effect of

δ

on shape

Figure 22.6

Log‐logistic: Effect of

α

,

β

and

δ

on shape

Figure 22.7

Log‐logistic: Fitted to the C

4

in propane data

Figure 22.8

Log‐logistic: Feasible combinations of

γ

and

κ

Figure 22.9

Paralogistic: Effect of

δ

on shape

Figure 22.10

Paralogistic: Feasible combinations of

γ

and

κ

Figure 22.11

Paralogistic: Fitted to the C

4

in propane data

Figure 22.12

Generalised logistic‐I: Effect of

δ

on shape

Figure 22.13

Generalised logistic‐II: Effect of

δ

on shape

Figure 22.14

Generalised logistic‐III: Effect of

δ

on shape

Figure 22.15

Generalised logistic‐IV: Effect of

δ

1

on shape

Figure 22.16

Generalised logistic‐IV: Effect of

δ

2

on shape

Figure 22.17

Generalised log‐logistic: Effect of

δ

1

and

δ

2

on shape

Chapter 23

Figure 23.1

Pareto‐I: Effect of

β

and

δ

on shape

Figure 23.2

Observed distribution of absolute change in NHV

Figure 23.3

Pareto‐II: Effect of

β

and

δ

on shape

Figure 23.4

Inverse Pareto: Effect of

δ

on shape

Figure 23.5

Pareto‐III: Effect of

δ

on shape

Figure 23.6

Generalised Pareto: Effect of

δ

on shape

Figure 23.7

Generalised Pareto: Feasible combinations of

γ

and

κ

Figure 23.8

Lorenz curve

Figure 23.9

Pareto analysis

Chapter 24

Figure 24.1

Stoppa‐II: Effect of

δ

2

on shape

Figure 24.2

Stoppa‐II: Fitted to the NHV disturbance data

Figure 24.3

Stoppa‐IV: Effect of

δ

on shape

Chapter 25

Figure 25.1

Arcsine distributions

Figure 25.2

Wigner semicircle

Figure 25.3

Beta‐II: Comparison to the beta‐I distribution fitted to the C

4

data

Figure 25.4

Beta‐II: Effect of

δ

1

and

δ

2

on skewness

Figure 25.5

Beta‐II: Effect of

δ

1

and

δ

2

on kurtosis

Figure 25.6

Beta‐II: Feasible combinations of

γ

and

κ

Figure 25.7

Generalised beta prime: Effect of

δ

1

, δ

2

and

δ

3

on shape

Figure 25.8

PERT: Effect of

λ

on shape

Figure 25.9

Beta rectangular: Effect of

δ

on shape

Figure 25.10

Kumaraswamy: Effect of

δ

1

on shape

Figure 25.11

Kumaraswamy: Effect of

δ

2

on shape

Figure 25.12

Kumaraswamy: Feasible combinations of

γ

and

κ

Figure 25.13

Minimax odds: Effect of

δ

1

and

δ

2

on shape

Chapter 26

Figure 26.1

Johnson S

N

: Effect of

α

and

β

on shape

Figure 26.2

Johnson S

U

: Comparison with Johnson S

N

distribution

Figure 26.3

Johnson S

U

: Effect of

α

and

β

on shape

Figure 26.4

Johnson S

L

: Effect of

α

and

β

on shape

Figure 26.5

Johnson S

B

: Effect of

α

and

β

on shape

Chapter 27

Figure 27.1

Pearson: Range of

γ

and

κ

covered

Figure 27.2

Pearson‐III: Effect of

δ

on shape

Figure 27.3

Pearson‐III: Feasible combinations of

γ

and

κ

Figure 27.4

Pearson‐IV: Effect of

δ

2

on shape

Figure 27.5

Pearson‐IV: Feasible combinations of

γ

and

κ

Figure 27.6

Cauchy: Effect of

α

and

β

on shape

Figure 27.7

Cauchy: Fitted to NHV disturbances

Figure 27.8

Log‐Cauchy: Effect of

α

on shape

Figure 27.9

Log‐Cauchy: Effect of

β

on shape

Figure 27.10

Log‐Cauchy: P–P plot showing fit to absolute changes in NHV

Figure 27.11

Log‐Cauchy: Plot of PDF fitted to absolute changes in NHV

Figure 27.12

Pearson‐V: Effect of

δ

on shape

Figure 27.13

Pearson‐VI: Effect of

δ

1

and

δ

2

on shape

Figure 27.14

Pearson‐VI: Relationship between

RSS

and

σ

Figure 27.15

Pearson‐VI: Feasible combinations of

γ

and

κ

Figure 27.16

Log‐F: Effect of

f

1

and

f

2

on shape

Figure 27.17

Pearson‐VII: Effect of

δ

on shape

Figure 27.18

Log‐Student: Effect of

f

on shape

Figure 27.19

Noncentral Student: Effect of

δ

on shape

Figure 27.20

Noncentral Student: Fitted to the C

4

in propane data

Chapter 28

Figure 28.1

Hyperexponential: Cumulative probability of interval between events

Figure 28.2

Hypoexponential: Effect of

λ

1

and

λ

2

on shape

Figure 28.3

Exponential: Comparison between versions

Figure 28.4

Maxwell–Jüttner: Effect of

λ

on shape

Figure 28.5

Stretched exponential: Effect of

δ

on shape

Figure 28.6

Exponential logarithmic: Effect of

λ

and

δ

on shape

Figure 28.7

Logistic exponential: Effect of

λ

and

δ

on shape

Figure 28.8

Q‐exponential: Effect of

q

and

λ

on shape

Figure 28.9

Q‐exponential: Improved fit to absolute changes in NHV

Figure 28.10

Benktander‐I: Effect of

λ

and

δ

on shape

Figure 28.11

Benktander‐II: Effect of

λ

and

δ

on shape

Chapter 29

Figure 29.1

Nukiyama–Tanasawa: Effect of

δ

1

on shape

Figure 29.2

Q‐Weibull: Effect of

q

on shape with

δ

 = 1

Figure 29.3

Q‐Weibull: Effect of

q

on shape with

δ

 = 2

Figure 29.4

Q‐Weibull: Improved fit to stock level data

Chapter 30

Figure 30.1

Chi: Effect of

f

on shape

Figure 30.2

Rayleigh: Effect of

β

on shape

Figure 30.3

Inverse Rayleigh: Effect of

β

on shape

Figure 30.4

Maxwell: Effect of

β

on shape

Figure 30.5

Chi: Feasible combinations of

γ

and

κ

Figure 30.6

Chi: Fitted to changes in C

4

content of propane

Figure 30.7

Inverse chi: Effect of

f

on shape

Figure 30.8

Inverse chi‐squared: Effect of

f

on shape

Figure 30.9

Inverse chi‐squared: Feasible combinations of

γ

and

κ

Figure 30.10

Noncentral chi‐squared: Effect of

δ

and

β

on shape

Chapter 31

Figure 31.1

Log‐gamma (1): Effect of

δ

1

and

δ

2

on shape

Figure 31.2

Log‐gamma (2): Effect of

δ

1

and

δ

2

on shape

Figure 31.3

Log‐gamma (3): Effect of

δ

1

and

δ

2

on shape

Figure 31.4

Log‐gamma (4): Effect of

δ

1

and

δ

2

on shape

Figure 31.5

Log‐gamma (5): Effect of

δ

on shape

Figure 31.6

Generalised gamma: Problem fitting to C

4

in propane data

Figure 31.7

Q‐gamma: Effect of

q

on shape

Chapter 32

Figure 32.1

Anglit: Effect of

μ

and

β

on shape

Figure 32.2

Bates: Effect of

n

on shape

Figure 32.3

Irwin–Hall: Effect of

n

on shape

Figure 32.4

Hyperbolic secant: Effect of

μ

and

σ

on shape

Figure 32.5

Arctangent: Effect of

δ

and

β

on shape

Figure 32.6

Arctangent: Poor fit to NHV disturbance data

Figure 32.7

Kappa: Effect of

δ

on shape

Figure 32.8

Laplace: Effect of

μ

and

σ

on shape

Figure 32.9

Cosine: Effect of

μ

and

β

on shape

Figure 32.10

Raised cosine: Effect of

μ

and

β

on shape

Figure 32.11

Cardioid: Circular plot showing effect of

β

on shape

Figure 32.12

Cardioid: Conventional plot showing effect of

β

on shape

Figure 32.13

Slash: Effect of

μ

and

σ

on shape

Figure 32.14

Tukey lambda: Effect of

λ

on shape

Figure 32.15

Tukey lambda: Effect of

λ

on kurtosis

Figure 32.16

Von Mises: Effect of

β

on shape

Figure 32.17

Von Mises: Estimating

σ

from

β

Chapter 33

Figure 33.1

Benini: Effect of

α

and

β

on shape

Figure 33.2

Birnbaum–Saunders: Effect of

δ

on shape

Figure 33.3

Birnbaum–Saunders: Feasible combinations of

γ

and

κ

Figure 33.4

Bradford: Effect of

λ

on shape

Figure 33.5

Champernowne (1): Effect of

δ

1

and

δ

2

on shape

Figure 33.6

Champernowne (2): Effect of

δ

1

and

δ

2

on shape

Figure 33.7

Champernowne (2): Feasible combinations of

γ

and

κ

Figure 33.8

Davis: Effect of

δ

on shape

Figure 33.9

Fréchet: Effect of

δ

and

β

on shape

Figure 33.10

Fréchet: Feasible combinations of

γ

and

κ

Figure 33.11

Fréchet: Fitted to C

4

in propane data

Figure 33.12

Gompertz: Effect of

α

and

β

on shape

Figure 33.13

Shifted Gompertz: Effect of

α

on shape

Figure 33.14

Gompertz–Makeham: Effect of

α

,

β

and

λ

on shape

Figure 33.15

Gamma‐Gompertz: Effect of

α

,

β

and

δ

on shape

Figure 33.16

Gompertz: Comparison of fits to C

4

in propane data

Figure 33.17

Hyperbolic: Effect of

δ

on shape

Figure 33.18

Hyperbolic: Effect of

λ

on shape

Figure 33.19

Asymmetric Laplace: Effect of

δ

on shape

Figure 33.20

Asymmetric Laplace: Feasible combinations of

γ

and

κ

Figure 33.21

Log‐Laplace (1): Effect of

α

and

β

on shape

Figure 33.22

Log‐Laplace (2): Effect of

δ

on shape

Figure 33.23

indley: Effect of

λ

on shape

Figure 33.24

Lindley: Feasible combinations of

γ

and

κ

Figure 33.25

Lindley‐geometric: Effect of

δ

on shape

Figure 33.26

Generalised Lindley: Effect of

δ

1

and

δ

2

on shape

Figure 33.27

Lindley: Comparison of fits to C

4

in propane data

Figure 33.28

Mielke: Effect of

δ

1

and

δ

2

on shape

Figure 33.29

Muth: Effect of

δ

on shape

Figure 33.30

Nakagami: Effect of

δ

on shape

Figure 33.31

Nakagami: Data ignored when fitted to C

4

in propane data

Figure 33.32

Power: Effect of

δ

on shape

Figure 33.33

Power: Feasible combinations of

γ

and

κ

Figure 33.34

Two‐sided power: Effect of

δ

on shape

Figure 33.35

Exponential power: Effect of

λ

and

δ

on shape

Figure 33.36

Rician: Effect of

α

on shape

Figure 33.37

Topp–Leone: Effect of

δ

on shape

Figure 33.38

Generalised Tukey: Effect of

λ

3

and

λ

4

on shape

Figure 33.39

Generalised Tukey: One of the best fits to NHV disturbance data

Figure 33.40

Generalised Tukey: One of the best fits to the C

4

in propane data

Figure 33.41

Wakeby: Effect of

δ

1

on shape

Figure 33.42

Wakeby: Effect of

δ

2

on shape

Figure 33.43

Wakeby: Effect of

δ

3

on shape

Figure 33.44

Wakeby: Effect of

δ

4

on shape

Figure 33.45

Wakeby: Improving the fit to the C

4

in propane data

Chapter 34

Figure 34.1

Amoroso: Effect of

δ

1

and

δ

2

on shape

Figure 34.2

Amoroso: Fitted to the C

4

in propane data

Figure 34.3

Amoroso: Feasible combinations of

γ

and

κ

Chapter 35

Figure 35.1

Negative binomial: Fit to batch blending performance

Figure 35.2

Use of same percentage rule to quantify control improvement

Figure 35.3

Cumulative frequency showing intersection at same percentage

Figure 35.4

Geometric: Impact of improved control on distribution of days required per batch

Figure 35.5

Geometric: Reduction in probability of large number of trim blends

Figure 35.6

Beta‐geometric: Effect of

α

and

β

on shape

Figure 35.7

Beta‐geometric: Fit to interval between high reflux events

Figure 35.8

Beta‐geometric: 95% confidence that high reflux event occurs within 5 days

Figure 35.9

Beta‐binomial: Effect of

α

and

β

on shape

Figure 35.10

Beta‐binomial: Fitted to frequency of high reflux events

Figure 35.11

Beta‐binomial: Improvement on accuracy of fit of binomial distribution

Figure 35.12

Beta‐negative binomial: Effect of

α

and

β

on shape

Figure 35.13

Beta‐Pascal: Effect of

α

and

β

on shape

Figure 35.14

Gamma‐Poisson: Effect of

α

and

β

on shape

Figure 35.15

Gamma‐Poisson: Improved fit to frequency of reflux events

Figure 35.16

Gamma‐Poisson: Accurate representation of number of events per day

Figure 35.17

Conway–Maxwell–Poisson: Effect of

δ

on shape

Figure 35.18

Conway–Maxwell–Poisson: Alternative method of fitting to data

Figure 35.19

Skellam: Approximation to normal distribution

Figure 35.20

Skellam: Probability of reducing the number of low‐stock incidents

Chapter 36

Figure 36.1

Benford: Expected and actual distribution of leading digit in accounts

Figure 36.2

Benford: P–P plot showing exception from expected distribution

Figure 36.3

Benford: Expected distribution of two leading digits

Figure 36.4

Benford: Expected distribution of second digit

Figure 36.5

Benford: Expected and actual distribution of atomic weights

Figure 36.6

Borel–Tanner: Effect of

λ

on shape

Figure 36.7

Borel–Tanner: Effect of

n

on shape

Figure 36.8

Borel–Tanner: Impact of increased production on likelihood of completion

Figure 36.9

Borel–Tanner: Impact of restricted increase in laboratory capacity

Figure 36.10

Consul: Effect of

α

and

β

on shape

Figure 36.11

Delaporte: Effect of

λ

on shape

Figure 36.12

Delaporte: Effect of

α

and

β

on shape

Figure 36.13

Delaporte: Fit to frequency of high reflux events

Figure 36.14

Flory–Schulz: Effect of

p

on shape

Figure 36.15

Hypergeometric: Effect of

K

on shape

Figure 36.16

Negative hypergeometric: Effect of

n

1

on shape

Figure 36.17

Logarithmic: Effect of

p

on shape

Figure 36.18

Logarithmic: Fit to number of blends require per batch

Figure 36.19

Discrete Weibull: Effect of

β

on shape

Figure 36.20

Zipf: Actual distribution against that expected from ranking

Figure 36.21

Zipf: P–P plot showing close match for almost all words

Figure 36.22

Zipf: Demonstration of king effect

Guide

Cover

Table of Contents

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Statistics for Process Control Engineers

A Practical Approach

 

 

Myke King

Whitehouse Consulting, Isle of Wight, UK

 

 

 

 

 

 

 

 

 

 

 

 

 

 

This edition first published 2017© 2017 John Wiley & Sons Ltd

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Library of Congress Cataloging‐in‐Publication Data

Names: King, Myke, 1951–Title: Statistics for process control engineers : a practical approach / Myke King.Description: First edition. | Hoboken, NJ : Wiley, [2017] | Includes bibliographical references and index.Identifiers: LCCN 2017013231 (print) | LCCN 2017015732 (ebook) | ISBN 9781119383482 (pdf) ISBN 9781119383529 (epub) | ISBN 9781119383505 (cloth)Subjects: LCSH: Process control--Mathematical models. | Engineering–Statistical methods. | Engineering mathematics.Classification: LCC TS156.8 (ebook) | LCC TS156.8 .K487 2018 (print) | DDC 620.001/51--dc23LC record available at https://lccn.loc.gov/2017013231

Cover design by WileyCover Images: (Background) © kagankiris/Gettyimages;(Graph) Courtesy of Myke King

Preface

There are those that have a very cynical view of statistics. One only has to search the Internet to find quotations such as those from the author Mark Twain:

There are three kinds of lies: lies, damned lies, and statistics.Facts are stubborn, but statistics are more pliable.

From the American humourist Evan Esar:

Statistics is the science of producing unreliable facts from reliable figures.

From the UK’s shortest‐serving prime minister George Canning:

I can prove anything by statistics except the truth.

And my personal favourite, attributed to many – all quoting different percentages!

76.3% of statistics are made up.

However, in the hands of a skilled process control engineer, statistics are an invaluable tool. Despite advanced control technology being well established in the process industry, the majority of site managers still do not fully appreciate its potential to improve process profitability. An important part of the engineer’s job is to present strong evidence that such improvements are achievable or have been achieved. Perhaps one of the most insightful quotations is that from the physicist Ernest Rutherford.

If your experiment needs statistics, you ought to have done a better experiment.

Paraphrasing for the process control engineer:

If you need statistics to demonstrate that you have improved control of the process, you ought to have installed a better control scheme.

Statistics is certainly not an exact science. Like all the mathematical techniques that are applied to process control, or indeed to any branch of engineering, they need to be used alongside good engineering judgement. The process control engineer has a responsibility to ensure that statistical methods are properly applied. Misapplied they can make a sceptical manager even more sceptical about the economic value of improved control. Properly used they can turn a sceptic into a champion. The engineer needs to be well versed in their application. This book should help ensure so.

After writing the first edition of Process Control: A Practical Approach, it soon became apparent that not enough attention was given to the subject. Statistics are applied extensively at every stage of a process control project from estimation of potential benefits, throughout control design and finally to performance monitoring. In the second edition this was partially addressed by the inclusion of an additional chapter. However, in writing this, it quickly became apparent that the subject is huge. In much the same way that the quantity of published process control theory far outstrips more practical texts, the same applies to the subject of statistics – but to a much greater extent. For example, the publisher of this book currently offers over 2,000 titles on the subject but fewer than a dozen covering process control. Like process control theory, most published statistical theory has little application to the process industry, but within it are hidden a few very valuable techniques.

Of course, there are already many statistical methods routinely applied by control engineers – often as part of a software product. While many use these methods quite properly, there are numerous examples where the resulting conclusion later proves to be incorrect. This typically arises because the engineer is not fully aware of the underlying (incorrect) assumptions behind the method. There are also too many occasions where the methods are grossly misapplied or where licence fees are unnecessarily incurred for software that could easily be replicated by the control engineer using a spreadsheet package.

This book therefore has two objectives. The first is to ensure that the control engineer properly understands the techniques with which he or she might already be familiar. With the rapidly widening range of statistical software products (and the enthusiastic marketing of their developers), the risk of misapplication is growing proportionately. The user will reach the wrong conclusion about, for example, the economic value of a proposed control improvement or whether it is performing well after commissioning. The second objective is to extract, from the vast array of less well‐known statistical techniques, those that a control engineer should find of practical value. They offer the opportunity to greatly improve the benefits captured by improved control.

A key intent in writing this book was to avoid unnecessarily taking the reader into theoretical detail. However the reader is encouraged to brave the mathematics involved. A deeper understanding of the available techniques should at least be of interest and potentially of great value in better understanding services and products that might be offered to the control engineer. While perhaps daunting to start with, the reader will get the full value from the book by reading it from cover to cover. A first glance at some of the mathematics might appear complex. There are symbols with which the reader may not be familiar. The reader should not be discouraged. The mathematics involved should be within the capabilities of a high school student. Chapters 4 to 6 take the reader through a step‐by‐step approach introducing each term and explaining its use in context that should be familiar to even the least experienced engineer. Chapter 11 specifically introduces the commonly used mathematical functions and their symbology. Once the reader’s initial apprehension is overcome, all are shown to be quite simple. And, in any case, almost all exist as functions in the commonly used spreadsheet software products.

It is the nature of almost any engineering subject that the real gems of useful information get buried among the background detail. Listed here are the main items worthy of special attention by the engineer because of the impact they can have on the effectiveness of control design and performance.

Control engineers use the terms ‘accuracy’ and ‘precision’ synonymously when describing the confidence they might have in a process measurement or inferential property. As explained in

Chapter 4

, not understanding the difference between these terms is probably the most common cause of poorly performing quality control schemes.